Abstract: Provided is a negative electrode active material that contains silicon clathrate II and that is suitable for a negative electrode of a lithium ion secondary battery. The negative electrode active material includes a silicon material in which silicon clathrate II represented by composition formula NaxSi136 (0?x?10) is contained and a volume of a pore having a diameter of not greater than 100 nm is not less than 0.025 cm3/g.

Abstract: The present invention provides a sample plate for laser desorption/ionization mass spectrometry, comprising: a hydrophilic thin film capable of absorbing a laser ray; and a water-repellent thin film comprising surface-hydrophobized nanoparticles and being stacked in a region other than a region to be a sample spot on a surface of the hydrophilic thin film, wherein a water contact angle of the water-repellent thin film is 120° or more.

Abstract: Provided is a negative electrode active material that contains silicon clathrate II and that is suitable for a negative electrode of a lithium ion secondary battery. The negative electrode active material includes a silicon material in which silicon clathrate II represented by composition formula NaxSi136 (0?x?10) is contained and a volume of a pore having a diameter of not greater than 100 nm is not less than 0.025 cm3/g.

Abstract: The present invention provides a sample plate for laser desorption/ionization mass spectrometry, comprising: a hydrophilic thin film capable of absorbing a laser ray; and a water-repellent thin film comprising surface-hydrophobized nanoparticles and being stacked in a region other than a region to be a sample spot on a surface of the hydrophilic thin film, wherein a water contact angle of the water-repellent thin film is 120° or more.

Abstract: A polymer compound, which is used as a binder for a negative electrode of an electricity storage device, is obtained by condensation of a vinyl polymer that contains a carboxyl group and a third compound that is selected from among an aromatic multifunctional amine, phosphorous acid, phosphorous acid ester, trialkoxysilane, and phosphoric acid.

Abstract: An object is to provide a composite plating film excellent in the water-repellent property and oil-repellent property using a material that is less likely to accumulate in the environment, as substitute for a fluorine resin. A composite plating film is provided which includes an alloy matrix phase and a silicone dispersed in the alloy matrix phase. In the composite plating film, the silicone preferably has Hansen solubility parameters comprising a dispersion term ?D of 15 MPa1/2 or less, a polar term ?P of 3 MPa1/2 or less, and a hydrogen bonding term ?H of 3 MPa1/2 or less. The silicone preferably has an interaction radius of a Hansen solubility sphere of 5.0 MPa1/2 or less.

Abstract: A forming method of a thermal insulation film includes a first step of forming an anode oxidation coating film on an aluminum-based wall surface, the anode oxidation coating film including micro-pores each having a diameter of micrometer-scale and nano-pores each having a diameter of nanometer-scale; and a second step of coating a surface of the anode oxidation coating film with a sealant containing filler to seal at least part of the micro-pores and the nano-pores by the sealant so as to form the thermal insulation film.

Abstract: A negative-electrode active material is used for a negative electrode, the negative-electrode active material including: agglomerated particles including nanometer-size silicon produced by heat treating a lamellar polysilane having a structure in which multiple six-membered rings constituted of a silicon atom are disposed one after another, and expressed by a compositional formula, (SiH)n; and a carbon layer including amorphous carbon, and covering at least some of the agglomerated particles to be composited therewith. An electric storage apparatus including the same is not only able to reduce the irreversible capacity, but also able to inhibit the generation of “SEI.

Abstract: Providing a negative-electrode material for nonaqueous-electrolyte secondary battery, the negative-electrode material including lithium silicate particles coated by a carbonaceous substance, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. A negative-electrode material for nonaqueous-electrolyte secondary battery includes lithium silicate particles having a surface at least some of which is coated by a carbonaceous substance formed by heating a carbon-containing compound at a thermal decomposition temperature of the carbon-containing compound or more and 1,100±° C. or less, the carbon-containing compound being a solid at ordinary temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP).

Abstract: A polymer compound for use as a binder for a negative electrode of an electrical storage device is formed by condensing polyacrylic acid and a multifunctional amine represented by the following formula (1), in which Y represents a straight chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom, and R1 and R2 each independently represent one or more hydrogen atoms, methyl groups, ethyl groups, trifluoromethyl groups, or methoxy groups.

Abstract: An object is to provide a composite plating film excellent in the water-repellent property and oil-repellent property using a material that is less likely to accumulate in the environment, as substitute for a fluorine resin. A composite plating film is provided which includes an alloy matrix phase and a silicone dispersed in the alloy matrix phase. In the composite plating film, the silicone preferably has Hansen solubility parameters comprising a dispersion term ?D of 15 MPa1/2 or less, a polar term ?P of 3 MPa1/2 or less, and a hydrogen bonding term ?H of 3 MPa1/2 or less. The silicone preferably has an interaction radius of a Hansen solubility sphere of 5.0 MPa1/2 or less.

Abstract: A negative-electrode active material is provided, the negative-electrode active material including: a lamellar polysilane having a structure in which multiple six-membered rings constituted of a silicon atom are disposed one after another, and expressed by a compositional formula, (SiH)n, as a basic skeleton; and the negative-electrode active material containing copper in an amount of from 0.01 to 50% by mass. To contain copper results in upgrading electron conductivity. Consequently, an electric storage apparatus using the negative-electrode active material for one of the negative electrodes has upgraded rate characteristic, and also has augmented charged and discharged capacities.

Abstract: A polymer compound, which is used as a binder for a negative electrode of an electricity storage device, is obtained by condensation of a vinyl polymer that contains a carboxyl group and a third compound that is selected from among an aromatic multifunctional amine, phosphorous acid, phosphorous acid ester, trialkoxysilane, and phosphoric acid.

Abstract: A polymer compound for use as a binder for a negative electrode of an electrical storage device is formed by condensing polyacrylic acid and a multifunctional amine represented by the following formula (1), in which Y represents a straight chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom, and R1 and R2 each independently represent one or more hydrogen atoms, methyl groups, ethyl groups, trifluoromethyl groups, or methoxy groups.

Abstract: A nanometer-size silicon material produced by heat treating a lamellar polysilane exhibits Raman-shift peaks existing at 341±10 cm?1, 360±10 cm?1, 498±10 cm?1, 638±10 cm?1, and 734±10 cm?1 in a Raman spectrum, has a large specific surface area, and has a reduced SiO content.

Abstract: In a secondary battery, a negative electrode, an electrolytic solution for negative electrode, a diaphragm, an electrolytic solution for positive electrode, and a positive electrode are disposed in order. The negative electrode includes a negative-electrode active material that has an element whose oxidation-reduction potential is more “base” by 1.5 V or more than an oxidation-reduction potential of hydrogen, and whose volume density is larger than that of lithium metal. The diaphragm includes a solid electrolyte transmitting ions of said element alone. A secondary battery with high volumetric density is provided.

Abstract: A negative-electrode active material includes a mixed power of a first active-material powder composed of a granular graphite particle, and a second active-material powder composed of a plate-shaped graphite particle having a thickness of from 0.3 nm to 100 nm and a major-axis-direction length of from 0.1 ?m to 500 ?m. Since the plate-shaped graphite particle has a lam liar structure, the plate-shaped graphite particle excels in the strength and flexibility, and function as a negative-electrode active material because lithium ions come in and out between the layers. Therefore, while securing the flexibility of negative-electrode active-material layer, the contradictory event between the capacity and the conductive property is solved.

Abstract: A forming method of a thermal insulation film includes a first step of forming an anode oxidation coating film on an aluminum-based wall surface, the anode oxidation coating film including micro-pores each having a diameter of micrometer-scale and nano-pores each having a diameter of nanometer-scale; and a second step of coating a surface of the anode oxidation coating film with a sealant containing filler to seal at least part of the micro-pores and the nano-pores by the sealant so as to form the thermal insulation film.

Abstract: Provided is a novel lithium silicate-based material useful as a positive electrode material for lithium ion secondary battery. The lithium silicate-based compound is represented by Li1.5FeSiO4.25. The lithium silicate-based compound is a compound including: lithium (Li); iron (Fe); silicon (Si); and oxygen (O), and expressed by a composition formula, Li1+2?FeSiO4+??c (?0.25???0.25, 0?c?0.5). The lithium silicate-based compound, of which iron (Fe) is trivalent, exerts a remarkable chemical stability as compared to Li2FeSiO4.

Abstract: A negative-electrode active material is used for a negative electrode, the negative-electrode active material including: agglomerated particles including nanometer-size silicon produced by heat treating a lamellar polysilane having a structure in which multiple six-membered rings constituted of a silicon atom are disposed one after another, and expressed by a compositional formula, (SiH)n; and a carbon layer including amorphous carbon, and covering at least some of the agglomerated particles to be composited therewith. An electric storage apparatus including the same is not only able to reduce the irreversible capacity, but also able to inhibit the generation of “SEI.