Patents by Inventor Masashi Uzawa

Masashi Uzawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11952509
    Abstract: The conductive composition of the present invention includes a conductive polymer (A) having an acidic group, and a basic compound (B) having a cyclic amide and an amino group in its molecule. The conductive film of the present invention is formed from the conductive composition. The laminate of the present invention includes a substrate; an electron beam resist layer, formed on at least one surface of the substrate; and a conductive film formed on the electron beam resist layer.
    Type: Grant
    Filed: September 21, 2020
    Date of Patent: April 9, 2024
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masashi Uzawa, Shinji Saiki, Akira Yamazaki
  • Publication number: 20230135022
    Abstract: A conductive composition comprising a conductive polymer (A), a water-soluble polymer (B), and a solvent (C1), wherein: the water-soluble polymer (B) comprises a water-soluble polymer (B11) represented by formula (11), and an amount of a water-soluble polymer (B2) represented by formula (2) as the water-soluble polymer (B) is 0.15% by mass or less, based on a total mass of the conductive composition: wherein R1 denotes a linear or branched alkyl group with 6 to 20 carbon atoms, each of R4 and R5 independently denotes a methyl or ethyl group, R6 denotes a hydrophilic group, R7 denotes a hydrogen atom or a methyl group, Y1 denotes a single bond, —S—, —S(?O)—, —C(?O)—O— or —O—, Z denotes a cyano group or a hydroxy group, each of p1 and q denotes an average number of repetitions, and is a number of from 1 to 50, and m denotes a number of from 1 to 5.
    Type: Application
    Filed: December 28, 2022
    Publication date: May 4, 2023
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Saki MAKIGAWA, Shinji SAIKI, Yoshiko IRIE, Masashi UZAWA, Akira YAMAZAKI
  • Publication number: 20230107107
    Abstract: A conductive composition including a conductive polymer (A), a water-soluble polymer (B) other than the conductive polymer (A), and a solvent (C), wherein a peak area ratio is 0.44 or less, which is determined based on results of analysis performed using a high performance liquid chromatograph mass spectrometer with respect to a test solution obtained by extracting the water-soluble polymer (B) from the conductive composition with n-butanol, and calculated by formula (I): Area ratio=Y/(X+Y) wherein X is a total peak area of an extracted ion chromatogram prepared with respect to ions derived from compounds having a molecular weight (M) of 600 or more from a total ion current chromatogram, Y is a total peak area of an extracted ion chromatogram prepared with respect to ions derived from compounds having a molecular weight (M) of less than 600 from the total ion current chromatogram.
    Type: Application
    Filed: December 9, 2022
    Publication date: April 6, 2023
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Akira YAMAZAKI, Shinji SAIKI, Yoshiko IRIE, Masashi UZAWA
  • Patent number: 11572479
    Abstract: A conductive composition comprising a conductive polymer (A), a water-soluble polymer (B), and a solvent (C1), wherein: the water-soluble polymer (B) comprises a water-soluble polymer (B11) represented by formula (11), and an amount of a water-soluble polymer (B2) represented by formula (2) as the water-soluble polymer (B) is 0.15% by mass or less, based on a total mass of the conductive composition: wherein R1 denotes a linear or branched alkyl group with 6 to 20 carbon atoms, each of R4 and R5 independently denotes a methyl or ethyl group, R6 denotes a hydrophilic group, R7 denotes a hydrogen atom or a methyl group, Y1 denotes a single bond, —S—, —S(?O)—, —C(?O)—O— or —O—, Z denotes a cyano group or a hydroxy group, each of p1 and q denotes an average number of repetitions, and is a number of from 1 to 50, and m denotes a number of from 1 to 5.
    Type: Grant
    Filed: July 17, 2020
    Date of Patent: February 7, 2023
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Saki Makigawa, Shinji Saiki, Yoshiko Irie, Masashi Uzawa, Akira Yamazaki
  • Publication number: 20210319927
    Abstract: The present invention relates to a conductor having a substrate and a conductive coating film laminated on the substrate, wherein, the surface resistance value of the conductive coating film is 5×1010?/? or less, the Ra1 of the conductive coating film is 0.7 nm or less, the Ra2 value of the conductive coating film scanning probe microscopies 0.35 nm or less, and the conductive coating film is formed with a conductive composition containing a conductive polymer (A). In addition, the present invention relates to a conductive composition which contains a conductive polymer (A) and a surfactant (B), wherein the surfactant (B) contains a specific water-soluble polymer (C), and the content of a compound (D1) with an octanol-water partition coefficient (Log Pow) of 4 or more in the conductive composition is 0.001 mass % or less, relative to the total mass of the conductive composition.
    Type: Application
    Filed: June 23, 2021
    Publication date: October 14, 2021
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hiroya FUKUDA, Osamu Numata, Hironobu Ikeda, Toshio Nagasaka, Shinji Saiki, Hiroaki Iriyama, Masashi Uzawa, Asako Kaneko
  • Patent number: 11145432
    Abstract: The present invention relates to a conductor having a substrate and a conductive coating film laminated on the substrate, wherein, the surface resistance value of the conductive coating film is 5×1010?/? or less, the Ra1 of the conductive coating film is 0.7 nm or less, the Ra2 value of the conductive coating film scanning probe microscopies 0.35 nm or less, and the conductive coating film is formed with a conductive composition containing a conductive polymer (A). In addition, the present invention relates to a conductive composition which contains a conductive polymer (A) and a surfactant (B), wherein the surfactant (B) contains a specific water-soluble polymer (C), and the content of a compound (D1) with an octanol-water partition coefficient (Log Pow) of 4 or more in the conductive composition is 0.001 mass % or less, relative to the total mass of the conductive composition.
    Type: Grant
    Filed: February 20, 2018
    Date of Patent: October 12, 2021
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hiroya Fukuda, Osamu Numata, Hironobu Ikeda, Toshio Nagasaka, Shinji Saiki, Hiroaki Iriyama, Masashi Uzawa, Asako Kaneko
  • Publication number: 20210261765
    Abstract: A conductive composition comprising a conductive polymer (A) having an acidic group, and a basic compound (B), wherein: an area ratio (X/Y) is 0.046 or less as calculated by an specific method, which is a ratio an area (X) of a region corresponding to molecular weight (M) ranging from 300 to 3300, relative to an area (Y) of an entire region ascribed to the conductive polymer (A); or a ratio, ZS/ZR, is 20 or less, wherein the ZS is a maximum value of fluorescence intensity in a wavelength region of 320 to 420 nm when a fluorescence spectrum is measured using a spectrofluorometer at an excitation wavelength of 230 nm with respect to a measurement solution obtained by diluting the conductive composition with water so as to adjust solids content of the conductive polymer (A) to 0.6% by mass, and the ZR is a maximum value of Raman scattering intensity in a wavelength region of 380 to 420 nm when a fluorescence spectrum of water is measured using a spectrofluorometer at an excitation wavelength of 350 nm.
    Type: Application
    Filed: April 29, 2021
    Publication date: August 26, 2021
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Saki Nakano, Yoshiko Irie, Masashi Uzawa, Akira Yamazaki
  • Publication number: 20210009818
    Abstract: The conductive composition of the present invention includes a conductive polymer (A) having an acidic group, and a basic compound (B) having a cyclic amide and an amino group in its molecule. The conductive film of the present invention is formed from the conductive composition. The laminate of the present invention includes a substrate; an electron beam resist layer, formed on at least one surface of the substrate; and a conductive film formed on the electron beam resist layer.
    Type: Application
    Filed: September 21, 2020
    Publication date: January 14, 2021
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Masashi UZAWA, Shinji SAIKI, Akira YAMAZAKI
  • Publication number: 20210005343
    Abstract: The conductive film of the present invention includes a conductive polymer (A) and has a film thickness of 35 nm or less, wherein: a surface resistance of the conductive film is 1×1011 ?/sq. or less, and a standard deviation of current that flows through the conductive film upon application of voltage to the conductive film is 5 or less. The conductor of the present invention has a substrate, and the conductive film provided on at least a part of the surface of the substrate. The resist pattern forming method of the present invention includes a lamination step of forming the conductive film on a surface of a resist layer including a chemically amplified resist, said resist layer formed on one surface of a substrate, and an exposure step of irradiating the substrate with an electron beam according to a pattern on its side on which the conductive film is formed.
    Type: Application
    Filed: September 2, 2020
    Publication date: January 7, 2021
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Saki MAKIGAWA, Akira YAMAZAKI, Naoko YAMADA, Yoshiko IRIE, Shinji SAIKI, Masashi UZAWA
  • Publication number: 20200347244
    Abstract: A conductive composition comprising a conductive polymer (A), a water-soluble polymer (B), and a solvent (C1), wherein: the water-soluble polymer (B) comprises a water-soluble polymer (B11) represented by formula (11), and an amount of a water-soluble polymer (B2) represented by formula (2) as the water-soluble polymer (B) is 0.15% by mass or less, based on a total mass of the conductive composition: wherein R1 denotes a linear or branched alkyl group with 6 to 20 carbon atoms, each of R4 and R5 independently denotes a methyl or ethyl group, R6 denotes a hydrophilic group, R7 denotes a hydrogen atom or a methyl group, Y1 denotes a single bond, —S—, —S(?O)—, —C(?O)—O— or —O—, Z denotes a cyano group or a hydroxy group, each of p1 and q denotes an average number of repetitions, and is a number of from 1 to 50, and m denotes a number of from 1 to 5.
    Type: Application
    Filed: July 17, 2020
    Publication date: November 5, 2020
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Saki MAKIGAWA, Shinji SAIKI, Yoshiko IRIE, Masashi UZAWA, Akira YAMAZAKI
  • Publication number: 20190359833
    Abstract: A conductive composition including a conductive polymer (A), a water-soluble polymer (B) other than the conductive polymer (A), and a solvent (C), wherein a peak area ratio is 0.44 or less, which is determined based on results of analysis performed using a high performance liquid chromatograph mass spectrometer with respect to a test solution obtained by extracting the water-soluble polymer (B) from the conductive composition with n-butanol, and calculated by formula (I): Area ratio=Y/(X+Y) wherein X is a total peak area of an extracted ion chromatogram prepared with respect to ions derived from compounds having a molecular weight (M) of 600 or more from a total ion current chromatogram, Y is a total peak area of an extracted ion chromatogram prepared with respect to ions derived from compounds having a molecular weight (M) of less than 600 from the total ion current chromatogram.
    Type: Application
    Filed: August 8, 2019
    Publication date: November 28, 2019
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Akira YAMAZAKI, Shinji SAIKI, Yoshiko IRIE, Masashi UZAWA
  • Patent number: 10488757
    Abstract: This conductive composition includes: a conductive polymer (a) having a sulfonic acid group and/or a carboxy group; a basic compound (b) having at least one nitrogen-containing heterocyclic ring and an amino group; an aqueous polymer (c) having a hydroxyl group (excluding the conductive polymer (a)); a hydrophilic organic solvent (d); and water (e).
    Type: Grant
    Filed: May 13, 2015
    Date of Patent: November 26, 2019
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Akira Yamazaki, Masashi Uzawa, Hiroya Fukuda
  • Patent number: 10096395
    Abstract: The present invention relates to a conductor having a substrate and a conductive coating film laminated on the substrate, wherein, the surface resistance value of the conductive coating film is 5×1010?/? or less, the Ra1 of the conductive coating film is 0.7 nm or less, the Ra2 value of the conductive coating film scanning probe microscopies 0.35 nm or less, and the conductive coating film is formed with a conductive composition containing a conductive polymer (A). In addition, the present invention relates to a conductive composition which contains a conductive polymer (A) and a surfactant (B), wherein the surfactant (B) contains a specific water-soluble polymer (C), and the content of a compound (D1) with an octanol-water partition coefficient (Log Pow) of 4 or more in the conductive composition is 0.001 mass % or less, relative to the total mass of the conductive composition.
    Type: Grant
    Filed: July 24, 2013
    Date of Patent: October 9, 2018
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hiroya Fukuda, Osamu Numata, Hironobu Ikeda, Toshio Nagasaka, Shinji Saiki, Hiroaki Iriyama, Masashi Uzawa, Asako Kaneko
  • Patent number: 10049780
    Abstract: The electroconductive composition of the present invention contains an electroconductive polymer (A) having a sulfonic acid group and/or carboxylic acid group, and a basic compound (B) having two or more nitrogen atoms. The electrical conductor of the present invention consists of the electroconductive composition. In the laminate of the present invention, the electrical conductor is laminated on at least one surface of a substrate. The method for producing a laminate of the present invention includes applying the electroconductive composition to at least one surface of a substrate, heating and drying the composition, and forming an electrical conductor. The electroconductive film of the present invention is provided with the electrical conductor.
    Type: Grant
    Filed: May 16, 2014
    Date of Patent: August 14, 2018
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masashi Uzawa, Akira Yamazaki, Hiroya Fukuda
  • Publication number: 20180174698
    Abstract: The present invention relates to a conductor having a substrate and a conductive coating film laminated on the substrate, wherein, the surface resistance value of the conductive coating film is 5×1010?/? or less, the Ra1 of the conductive coating film is 0.7 nm or less, the Ra2 value of the conductive coating film scanning probe microscopies 0.35 nm or less, and the conductive coating film is formed with a conductive composition containing a conductive polymer (A). In addition, the present invention relates to a conductive composition which contains a conductive polymer (A) and a surfactant (B), wherein the surfactant (B) contains a specific water-soluble polymer (C), and the content of a compound (D1) with an octanol-water partition coefficient (Log Pow) of 4 or more in the conductive composition is 0.001 mass % or less, relative to the total mass of the conductive composition.
    Type: Application
    Filed: February 20, 2018
    Publication date: June 21, 2018
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Hiroya FUKUDA, Osamu NUMATA, Hironobu IKEDA, Toshio NAGASAKA, Shinji SAIKI, Hiroaki IRIYAMA, Masashi UZAWA, Asako KANEKO
  • Patent number: 9799420
    Abstract: When measuring the molecular mass distribution of conductive aniline polymer of formula (1) by GPC and converting its retention time into molecular mass (M) in terms of sodium polystyrene sulfonate, for the molecular mass (M), the area ratio (X/Y) of the area (X) of a region of 15,000 Da or more to the area (Y) of a region of less than 15,000 Da is 1.20 or more. A method for producing such a polymer includes: polymerization step (Z1) where specific aniline derivative (A) is polymerized in a solution containing basic compound (B), solvent (C), and oxidizing agent (D) at a liquid temperature lower than 25° C.; or polymerization step (Z2) where specific aniline derivative (A) and oxidizing agent (D) are added to and polymerized in a solution of a conductive aniline polymer (P-1) with a unit of formula (1) dissolved or dispersed in a solvent (C).
    Type: Grant
    Filed: March 4, 2015
    Date of Patent: October 24, 2017
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kohei Yamada, Yasushi Horiuchi, Yukiko Hachiya, Masashi Uzawa, Takahiro Sakai, Tamae Takagi
  • Publication number: 20170261854
    Abstract: This conductive composition includes: a conductive polymer (a) having a sulfonic acid group and/or a carboxy group; a basic compound (b) having at least one nitrogen-containing heterocyclic ring and an amino group; an aqueous polymer (c) having a hydroxyl group (excluding the conductive polymer (a)); a hydrophilic organic solvent (d); and water (e).
    Type: Application
    Filed: May 13, 2015
    Publication date: September 14, 2017
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Akira YAMAZAKI, Masashi UZAWA, Hiroya FUKUDA
  • Patent number: 9679673
    Abstract: A conductive composition according to the present invention contains a conductive polymer (A) having a sulfonic acid group and/or a carboxyl group; and an alkali metal hydroxide and/or an alkaline earth metal hydroxide (B). In such a conductive composition, the amount of the hydroxide (B) is set at 0.2˜0.65 mol per 1 mol of a repeating unit that contains a sulfonic acid group and/or a carboxyl group in the conductive polymer (A).
    Type: Grant
    Filed: November 16, 2015
    Date of Patent: June 13, 2017
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kohei Yamada, Takahiro Sakai, Masashi Uzawa, Youko Sasata, Akira Yamazaki
  • Patent number: 9627144
    Abstract: A solid electrolytic capacitor, including: a solid electrolytic layer; and a dielectric layer on which the solid electrolytic layer is formed. The solid electrolytic layer is formed by applying and drying a conductive-polymer solution including a conductive polymer on the dielectric layer, and the dielectric layer is formed by oxidizing a surface of an anode metal. The conductive polymer has a volume average particle size of smaller than 26 nm. A stacked aluminum electrolytic capacitor including a test solid electrolytic layer and a test dielectric layer, the test solid electrolytic layer being formed by applying and drying the conductive-polymer solution on the test dielectric layer, the test dielectric layer being formed by oxidizing a surface of aluminum having an electrical capacitance of 95 ?F/cm2, has a rate of exhibited capacitance of no less than 70%.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: April 18, 2017
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Akira Yamazaki, Takeo Sando, Masashi Uzawa, Hiroaki Iriyama
  • Publication number: 20160223910
    Abstract: Provided is an electrically conductive composition that includes: an electrically conductive substance (A); and a water-soluble polymer (b) having a hydrophilic group, and a C13 or greater terminating hydrophobic group.
    Type: Application
    Filed: October 20, 2014
    Publication date: August 4, 2016
    Applicant: Mitsubishi Rayon Co., Ltd.
    Inventors: Hiroya FUKUDA, Masashi UZAWA