Patents by Inventor Mathieu Leclerc

Mathieu Leclerc has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240310117
    Abstract: An apparatus for separation of a flow containing at least 95 mol % of carbon dioxide and also at least one impurity lighter than carbon dioxide by distillation comprises a heat exchanger (20), a distillation column (30), expansion means (V3), means for sending the flow to be cooled in the heat exchanger, means for sending the cooled flow to be separated in the distillation column, means for withdrawing at the bottom of the column a liquid flow containing at least 99 mol % of carbon dioxide, means for sending at least a portion (12) of the liquid flow to be cooled in the heat exchanger to form a subcooled liquid (3), means for sending at least a portion of the subcooled liquid to the expansion means to produce a two-phase flow, a phase separator (40) for separating the two-phase flow to form a gas and a liquid, means for sending at least a portion (14) of the liquid from the phase separator to be vaporized in the heat exchanger and means for taking a portion (4) of the liquid from the phase separator.
    Type: Application
    Filed: February 28, 2022
    Publication date: September 19, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Michael TRAN, Ludovic GRANADOS, Mathieu LECLERC, Guillaume RODRIGUES, Aurore TROPTARD
  • Publication number: 20240240856
    Abstract: In a process for separating a mixture containing hydrogen and carbon dioxide, the following steps are present: a) cooling of the mixture in a heat exchanger by sending the mixture to the heat exchanger, resulting in the partial condensation of the mixture into a liquid phase enriched in carbon dioxide and a gas phase depleted in carbon dioxide, a gaseous fluid which is heated in the heat exchanger by indirect heat exchange, b) separating the liquid phase from the gas phase in a separator vessel, c) heating of the gas phase originating from at least one of the separator vessels in the heat exchanger, d) sending of the at least one heated part from step c) to a membrane separation unit, generating a residue depleted in hydrogen and carbon dioxide and e) expansion of the at least one residue in a turbine producing an expanded fluid, f) the expanded fluid constituting the gaseous fluid of step a) which is heated in the heat exchanger by indirect heat exchange.
    Type: Application
    Filed: January 12, 2024
    Publication date: July 18, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Felix PERE, Mathieu LECLERC
  • Publication number: 20240226803
    Abstract: In a process for separating a mixture containing hydrogen and carbon dioxide, the mixture is compressed to form a compressed mixture, the compressed mixture is separated by partial condensation and/or distillation generating a first CO2-depleted stream, the first CO2-depleted stream is separated by permeation through a membrane system to form a residue of the membrane system which is depleted in hydrogen and carbon dioxide and a portion of the residue is recycled, after expansion, to the compressor to be compressed therein.
    Type: Application
    Filed: October 9, 2023
    Publication date: July 11, 2024
    Inventors: Felix PERE, Mathieu LECLERC
  • Publication number: 20240210106
    Abstract: In a method for separating a flow containing at least 95 mol % of carbon dioxide and at least one impurity lighter than carbon dioxide by distillation, the flow is cooled to a first intermediate temperature between those of the cold end and the hot end of a heat exchange means in order to form a liquid flow at a first temperature and a first pressure and it is split into at least two to form a first fraction and a second fraction, the first fraction is expanded to the pressure of a distillation column, referred to as second pressure, which is lower than the first pressure, and it is sent to an intermediate level of the distillation column, the second fraction is cooled in the heat exchange means to the cold end thereof, it is expanded to the pressure of the distillation column and is sent to a level of the distillation column above the point of arrival of the first fraction, a liquid flow containing at least 99 mol % of carbon dioxide is withdrawn from the bottom of the column, and a fraction of the liquid fl
    Type: Application
    Filed: March 10, 2022
    Publication date: June 27, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Michael TRAN, Mathieu LECLERC
  • Publication number: 20240157268
    Abstract: In a process for distilling a gas mixture of CO2 and at least one component lighter than CO2, a partially purified liquid CO2 stream is withdrawn at an intermediate level of the distillation column at least one theoretical plate below the top of the distillation column and at least one theoretical plate above the bottom of the distillation column and the stream extracted at the intermediate level of the distillation column is vaporized by heat exchange with the gas mixture, with which it is then compressed.
    Type: Application
    Filed: November 9, 2023
    Publication date: May 16, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Mathieu LECLERC, Laurette MADELAINE
  • Publication number: 20240131470
    Abstract: In a process for separating a mixture containing hydrogen and carbon dioxide, the mixture is compressed to form a compressed mixture, the compressed mixture is separated by partial condensation and/or distillation generating a first CO2-depleted stream, the first CO2-depleted stream is separated by permeation through a membrane system to form a residue of the membrane system which is depleted in hydrogen and carbon dioxide and a portion of the residue is recycled, after expansion, to the compressor to be compressed therein.
    Type: Application
    Filed: October 8, 2023
    Publication date: April 25, 2024
    Inventors: Felix PERE, Mathieu LECLERC
  • Publication number: 20240101430
    Abstract: An apparatus for the separation of a flow containing carbon dioxide by distillation comprising a heat exchange means, a distillation column, means for sending the flow to be cooled in the heat exchange means down to a first intermediate temperature in order to form a liquid flow at a first temperature and at a first pressure, means for dividing the liquid flow in order to form a first fraction and a second fraction, means for expanding the first fraction to the pressure of a distillation column, means for sending the expanded first fraction to an intermediate level of the distillation column, means for exiting the second fraction from the cold end of the heat exchange means after cooling, means for expanding the cooled second fraction to the pressure of the distillation column, means for sending the second fraction to the distillation column and means for the withdrawal, from the bottom of the column, of a liquid flow.
    Type: Application
    Filed: January 27, 2022
    Publication date: March 28, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Michael TRAN, Mathieu LECLERC
  • Publication number: 20240068744
    Abstract: In a method for liquefying a gas rich in carbon dioxide, the gas is compressed to a first pressure greater than its critical pressure in a compressor to form a compressed gas, the compressed gas is cooled through heat exchange with a refrigerant to a variable temperature to form a cooled compressed gas with a density between 370 and 900 kg/m3, the cooled compressed gas is cooled at supercritical pressure in a first heat exchanger to a temperature below the critical temperature, the gas cooled below the critical temperature is expanded to a second pressure between 45 and 60 bara to form a diphasic fluid which is separated in a phase separator to form a liquid and a gas, and a liquid portion originating from the phase separator provides cold to the first heat exchanger.
    Type: Application
    Filed: March 2, 2022
    Publication date: February 29, 2024
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Michael TRAN, Mathieu LECLERC
  • Publication number: 20240066462
    Abstract: In a method for drying a first wet gas stream containing at least 90 mol % CO2, the first CO2 stream is dried in a water adsorption unit, at least a portion of the regeneration gas from the adsorbers being a gas containing at least 90 mol % carbon dioxide produced in a separation apparatus (33) that separates a gas (31) containing carbon dioxide and at least one impurity by partial condensation and/or distillation at a temperature below 0° C.
    Type: Application
    Filed: January 7, 2022
    Publication date: February 29, 2024
    Inventors: Mathieu LECLERC, Félix PERE
  • Publication number: 20230375266
    Abstract: In a process for the recovery of cold from a methane-rich fluid for the cooling of a flow rich in carbon dioxide, cold is provided to a first heat exchanger for the cooling of the flow by the evaporation of an intermediate fluid by exchange of heat with the methane-rich fluid in order to form at least one condensed intermediate fluid flow at at least one pressure level; at least a part of the intermediate fluid evaporated in a second heat exchanger is condensed at at least one pressure into at least one flow.
    Type: Application
    Filed: May 18, 2023
    Publication date: November 23, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges Claude
    Inventors: Martin RAVENTOS, Richard DUBETTIER-GRENIER, Mathieu LECLERC, Thomas MOREL
  • Patent number: 11585738
    Abstract: An apparatus for analyzing the content of at least one contaminant in a liquid cryogen comprising a cylindrical enclosure, an annular enclosure arranged around the cylindrical enclosure, means for dividing a flow of liquid cryogen in two, means for delivering a first part of the liquid cryogen to the cylindrical enclosure, means for delivering a second part of the liquid cryogen to the annular enclosure, a pipe connected to the cylindrical enclosure to allow vaporized liquid to pass through, a pipe connected to the annular enclosure to allow vaporized liquid to pass through, a heater for heating the cylindrical enclosure vessel and means for stopping the delivery of liquid cryogen to the cylindrical enclosure.
    Type: Grant
    Filed: May 18, 2018
    Date of Patent: February 21, 2023
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Patrick Le Bot, Frederic Crayssac, Benoit Davidian, Mathieu Leclerc
  • Publication number: 20230027743
    Abstract: A process for membrane separation of a mixture containing as main, or even major, components hydrogen and carbon dioxide and also at least one other component, for example chosen from the following group: carbon monoxide, methane and nitrogen, including: heating of the mixture in the heat exchanger, permeation of the reheated mixture in a first membrane separation unit making it possible to obtain a first permeate which is a hydrogen and carbon dioxide enriched relative to the mixture, and a first residue which is hydrogen and carbon dioxide lean, permeation of the first residue in a second membrane separation unit making it possible to obtain a second residue, at least one portion of the first permeate is compressed in a booster compressor and the second residue is expanded in a turbine, the booster compressor being driven by the turbine.
    Type: Application
    Filed: July 26, 2022
    Publication date: January 26, 2023
    Inventors: Mathieu LECLERC, Felix Pere
  • Patent number: 11359027
    Abstract: The present disclosure relates to the in vivo prevention or treatment of hematologic malignancy relapse using a TNFR2 antagonist (an anti TNFR2 antagonist antibody) (i) for use in the prevention or treatment of hematologic malignancy relapse after allogeneic hematopoietic stem cell transplantation (AHCT) or after a treatment with lymphocytes and (ii) for use in enhancing the graft-versus-leukemia-activity (GVL activity) of a hematopoietic stem cell transplantation (HCT) or a treatment with lymphocytes.
    Type: Grant
    Filed: June 22, 2017
    Date of Patent: June 14, 2022
    Assignees: UNIVERSITE PARIS EST CRETEIL VAL DE MARNE, INSTITUT NATIONAL DE LA SANTE ET DE LA RECHERCHE MEDICALE (INSERM), ASSISTANCE PUBLIQUE—HOPITAUX DE PARIS, SORBONNE UNIVERSITE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Sébastien Maury, José Cohen, Benoît Salomon, Sina Naserian, Mathieu Leclerc
  • Patent number: 11344842
    Abstract: In a method for separating a mixture containing carbon dioxide, the mixture is cooled in a heat exchanger and partially condensed and a first liquid is separated from the mixture in a first system operating at low temperature comprising at least one first phase separator and a gas from the first system is treated in a membrane system to produce a permeate and a non-permeate, the gas from the first system being divided into two portions, a first portion being sent to the membrane system without being heated and a second portion being heated to at least an intermediate temperature of the heat exchanger and then sent to the membrane system without being cooled.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: May 31, 2022
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Ludovic Granados, Mathieu Leclerc, Frederick Lockwood, Paul Terrien
  • Patent number: 10746463
    Abstract: In a method for compressing a gas that is to be separated in a low-temperature CO2 separation unit using at least one partial condensation step and/or at least one distillation step, the gas that is to be separated has a variable composition and/or variable flow rate, the gas that is to be separated is compressed in a compressor to produce a compressed gas and the inlet pressure of the gas that is to be separated, entering the compressor, is modified according to the CO2 content and/or the flow rate of the gas that is to be separated so as to reduce the variations in volumetric flow rate of the gas that is to be separated entering the compressor.
    Type: Grant
    Filed: May 25, 2017
    Date of Patent: August 18, 2020
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Mathieu Leclerc, Ludovic Granados, Frederick Lockwood, Cyril Defaye
  • Publication number: 20200209113
    Abstract: An apparatus for analyzing the content of at least one contaminant in a liquid cryogen comprising a cylindrical enclosure, an annular enclosure arranged around the cylindrical enclosure, means for dividing a flow of liquid cryogen in two, means for delivering a first part of the liquid cryogen to the cylindrical enclosure, means for delivering a second part of the liquid cryogen to the annular enclosure, a pipe connected to the cylindrical enclosure to allow vaporized liquid to pass through, a pipe connected to the annular enclosure to allow vaporized liquid to pass through, a heater for heating the cylindrical enclosure vessel and means for stopping the delivery of liquid cryogen to the cylindrical enclosure.
    Type: Application
    Filed: May 18, 2018
    Publication date: July 2, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Patrick LE BOT, Frederic CRAYSSAC, Benoit DAVIDIAN, Mathieu LECLERC
  • Publication number: 20200191689
    Abstract: The invention relates to a method for analyzing the content of at least one contaminant in a cryogenic liquid, wherein a known amount of liquid L constituting the initial liquid is injected at the pressure P into an enclosure; a predetermined fraction of the liquid present in the enclosure is vaporized by heating same; the vapor thus generated is discharged from the vaporizing enclosure to maintain a pressure no higher than the pressure P during the vaporization phase; the amount of liquid thus vaporized, less than L, is precisely controlled so that the amount of contaminant in the residual liquid present in the enclosure is substantially equal to that of the initial liquid, which implies that the concentration thereof is multiplied by a previously determined factor; a sample of residual liquid is collected; the contaminant content is measured after total vaporization of the residual liquid sample; and the contaminant content in the initial liquid is deduced from the measurement of contaminant in the residual
    Type: Application
    Filed: May 18, 2018
    Publication date: June 18, 2020
    Applicant: l'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Patrick LE BOT, Frédéric CRAYSSAC, Benoit DAVIDIAN, Mathieu LECLERC
  • Publication number: 20190330359
    Abstract: The present disclosure relates to the in vivo prevention or treatment of hematologic malignancy relapse using a TNFR2 antagonist (an anti TNFR2 antagonist antibody) (i) for use in the prevention or treatment of hematologic malignancy relapse after allogeneic hematopoietic stem cell transplantation (AHCT) or after a treatment with lymphocytes and (ii) for use in enhancing the graft-versus-leukemia-activity (GVL activity) of a hematopoietic stem cell transplantation (HCT) or a treatment with lymphocytes.
    Type: Application
    Filed: June 22, 2017
    Publication date: October 31, 2019
    Applicants: Universite Paris EST Creteil Val de Marne, Institut National de la Recherche Medicale (Inserm), Assistance Publique Hopitaux de Paris, Universite Paris 6 Pierre et Marie Curie, Centre National de la Recherche Scientifique
    Inventors: Sébastien MAURY, José COHEN, Benoît SALOMON, Sina NASERIAN, Mathieu LECLERC
  • Patent number: 10392251
    Abstract: The invention relates to a method for treating a mixture in order to separate carbon dioxide and hydrogen from said mixture, in which: i) the mixture is cooled and partially condensed and a first liquid is separated from the rest of the mixture in a first phase separator; ii) a gas from or derived from a gas from the first phase separator is treated in a hydrogen pressure swing adsorption module in order to produce a hydrogen-rich gas and a hydrogen-depleted residual gas; and iii) said hydrogen-depleted residual gas or a gas derived from said depleted gas is cooled and partially condensed and a second liquid is separated from the remaining gas in a second phase separator, separate from the first phase separator, wherein the first and/or second liquid being rich in carbon dioxide. The invention also relates to an installation for implementing such a method.
    Type: Grant
    Filed: May 11, 2015
    Date of Patent: August 27, 2019
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Nicolas Chambron, Richard Dubettier-Grenier, Mathieu Leclerc, Pascal Marty
  • Patent number: 10317135
    Abstract: A device for separating a gas mixture containing at least 35 mol % carbon dioxide and also at least one gas lighter than carbon dioxide, comprising a first phase separator configured to receive a first partially condensed flow from an exchange line; a first phase separator configured to separate the gas phase from the liquid phase; a cooling means configured to receive the gas phase from the first phase separator and cool said gas phase to form a second partially condensed flow. The resulting liquid phase is then sent to a first valve and is expanded to a lower pressure that is at most 300 mbar lower in order to form a first expanded liquid, which is then mixed with a second liquid originating from the second phase separator in a mixing means that is located upstream of a third valve.
    Type: Grant
    Filed: February 20, 2014
    Date of Patent: June 11, 2019
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Alain Briglia, Mathieu Leclerc