Patents by Inventor Mathieu ZELLHUBER
Mathieu ZELLHUBER has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240294447Abstract: A method for producing a target compound includes distributing a feed mixture containing ethane to multiple reaction tubes of a shell-and-tube reactor arranged in parallel, and subjecting to an oxidative catalytic conversion of the ethane in the reaction tubes. The catalytic reaction is carried out by means of catalysis zones with different activity arranged in series in the reaction tubes. One or more catalytically active materials and one or more catalytically inactive materials are provided in each of the catalysis zones. The different activity of the catalysis zones is effected by providing the one or more catalytically active materials having identical or essentially identical basic formulation, wherein the one or more catalytically active materials is or are prepared using different calcination intensities.Type: ApplicationFiled: March 14, 2022Publication date: September 5, 2024Inventors: Mathieu Zellhuber, Martin Schubert, Andreas Meiswinkel, Wolfgang Muller, Gerhard Mestl, Klaus Wanninger, Peter Scheck
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Publication number: 20240207811Abstract: A method for carrying out a chemical reaction includes using a reactor arrangement in which reaction tubes arranged in a reactor vessel are heated to a reaction tube temperature level between 400° C. and 1,500° C. during a reaction period using radiant heat provided by means of one or more electric heating elements arranged in the reactor vessel. In at least a part of the reactor vessel in which the heating elements are provided, a gas atmosphere is provided during the reaction period, which gas atmosphere has a defined volume fraction of oxygen.Type: ApplicationFiled: April 7, 2022Publication date: June 27, 2024Inventors: Mathieu Zellhuber, Martin Hofstätter, Kiara Aenne Kochendoerfer, Andrey Shustov, Eric Jenne, Andrea Haunert, Scott A. Stevenson, Robert R. Broekhuis, Andrew M. Ward
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Patent number: 12012377Abstract: The invention relates to a method for producing one or more olefins and one or more carboxylic acids, in which one or more paraffins is or are subjected to an oxidative dehydrogenation. For the oxidative dehydrogenation, a reactor (10) having a plurality of reaction zones (11, 12, 13) is used, a gas mixture comprising the one or more paraffins is successively passed through the reaction zones (11, 12, 13), and at least two of the reaction zones (11, 12, 13) are subject to varying temperature influences. The invention also relates to a corresponding system (100).Type: GrantFiled: June 19, 2019Date of Patent: June 18, 2024Assignee: LINDE GmbHInventors: Mathieu Zellhuber, Martin Schubert, Andreas Meiswinkel, Florian Winkler, Desislava Tota, Hans-Jörg Zander
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Publication number: 20240166579Abstract: A process for producing ethylene by oxidative dehydrogenation of ethane using a shell-and-tube reactor having reaction tubes extending between a first end and a second end includes disposing one or more catalyst beds in each of the reaction tubes. In each of the reaction tubes, a ratio of a total length of the one or more catalyst beds between the first end and the second end to a diameter of each of the reaction tubes has a value between 150 and 400. The shell-and-tube reactor is operated at a linear velocity of 250 to 800 cm/s, and the one or more catalyst beds are configured such that a ratio of active catalyst mass to effective cooling area is in a range between 1.5 and 5 kg/m2.Type: ApplicationFiled: March 14, 2022Publication date: May 23, 2024Inventors: Mathieu Zellhuber, Martin Schubert, Andreas Meiswinkel
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Publication number: 20240158322Abstract: A method for producing a target compound includes distributing a feed mixture at a temperature in a first temperature range to a plurality of parallel reaction tubes of a shell-and-tube reactor, and subjecting the feed mixture in first tube sections of the reaction tubes to heating to a temperature in a second temperature range and in second tube sections of the reaction tubes arranged downstream of the first tube sections to oxidative catalytic conversion using one or more catalysts. A gas mixture flowing out of the second tube sections is brought into contact in third tube sections arranged downstream of the second tube sections with a catalyst which has a volumetric activity below the highest volumetric activity of the one or the plurality of catalysts arranged in the second tube sections. A gas mixture from the third tube sections is withdrawn from the shell-and-tube reactor without further catalytic conversion.Type: ApplicationFiled: March 14, 2022Publication date: May 16, 2024Inventors: Mathieu Zellhuber, Martin Schubert, Andreas Meiswinkel, Wolfgang Muller, Ernst Haidegger, Gerhard Mestl, Klaus Wanninger, Peter Scheck
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Publication number: 20240158700Abstract: A method of steam cracking using a steam cracking arrangement including an electric cracking furnace without a convection zone and a quench cooling train is proposed, wherein a process gas stream is passed through the cracking furnace and the cooling train. The cooling train is operated to comprise at least two distinct cooling steps arranged in either order, wherein in a first cooling step at least a part of the process gas stream withdrawn from the electric cracking furnace is cooled against vaporizing boiler feed water at an absolute pressure level between 30 and 175 bar and wherein in a second cooling step at least a part of the process gas stream withdrawn from the electric cracking furnace is cooled against a superheated mixture of feed hydrocarbons and process steam used in forming the process gas stream which is thereby heated to a temperature level between 350 and 750° C.Type: ApplicationFiled: March 8, 2022Publication date: May 16, 2024Inventors: Mathieu Zellhuber, Michael Horenz, David Bruder, Martin Hofstatter
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Publication number: 20240158701Abstract: A method of steam cracking includes using a steam cracking arrangement that has a fired cracking furnace, a quench cooling train, and rotating equipment at least partly driven by electric energy. A process gas stream is passed through the furnace and the cooling train. A steam generation arrangement, operated in thermal association with the cracking arrangement, results in superheated high pressure steam at a first pressure level of 30 and 175 bar absolute pressure and at a first temperature level. No steam at a higher temperature level than the first is generated. The superheated high pressure steam is partially adiabatically and isenthalpically expanded to a second lower pressure level. The first temperature level is selected such that each intermediate temperature level reached at intermediate pressure levels of more than 20 bar during the adiabatic and isenthalpic expansion process is between 5 and 120 K above the dew point of steam.Type: ApplicationFiled: March 8, 2022Publication date: May 16, 2024Inventors: Michael Horenz, Mathieu Zellhuber, Robert Stegemann, Gunther Schmidt
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Publication number: 20240158702Abstract: A method of steam cracking using a steam cracking system includes a first steam cracking furnace unit or a plurality of first steam cracking furnace units and a second steam cracking furnace unit or a plurality of second steam cracking furnace units. The first steam cracking furnace unit or each of the plurality of first steam cracking furnace units comprises one or more fired steam cracking furnaces. The second steam cracking furnace unit or each of the plurality of second steam cracking furnace units comprises one or more electric steam cracking furnaces. The first steam cracking furnace unit or each of the plurality of first steam cracking furnace units further includes means for preheating at least a part of combustion air provided to its fired steam cracking furnace or furnaces to a temperature level of at least 100° C.Type: ApplicationFiled: March 8, 2022Publication date: May 16, 2024Inventors: Mathieu Zellhuber, Michael Horenz, Tobias Sinn, Sebastian Mayer
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Publication number: 20240150262Abstract: Producing a product hydrocarbon includes subjecting a feed mixture containing a feed hydrocarbon and oxygen to selective oxidation to obtain a product mixture containing product hydrocarbon and water. A subsequent mixture is formed from a portion of the product mixture by separating a portion of the water. Oxygen in the feed mixture is partially converted during the selective oxidation, so that the product mixture has a first residual oxygen content and the subsequent mixture has a second residual oxygen content. Detection of the first and/or the second residual oxygen content is performed using a first measuring device. A second measuring device at the end of the catalyst bed detects temperature. Using a process control and/or evaluation unit, measurement data of the first and/or second measuring device(s) are detected and are evaluated and/or processed while obtaining follow-up data. Process control is carried out on the basis of the follow-up data.Type: ApplicationFiled: March 14, 2022Publication date: May 9, 2024Inventors: Mathieu Zellhuber, Martin Schubert, Andreas Meiswinkel, Anina Wohl
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Publication number: 20240150261Abstract: A method for producing a target compound, includes distributing feed mixture at a temperature in a first temperature range to a plurality of parallel reaction tubes of a shell-and-tube reactor. The method further includes subjecting the feed mixture in first tube sections of the reaction tubes to heating to a temperature in a second temperature range, and in second tube sections of the reaction tubes arranged downstream of the first tube sections to oxidative catalytic conversion using one or more catalysts arranged in the second tube sections. The heating is performed, at least in part, using a catalyst arranged in the first tube sections and having a light-off temperature in the first temperature range.Type: ApplicationFiled: March 14, 2022Publication date: May 9, 2024Inventors: Mathieu Zellhuber, Martin Schubert, Andreas Meiswinkel, Wolfgang Muller, Ernst Haidegger, Gerhard Mestl, Klaus Wanninger, Peter Scheck
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Publication number: 20240150263Abstract: A process for producing a target compound includes forming a feed mixture containing at least one reactant compound. The feed mixture is distributed to parallel reaction tubes of one or more shell-and-tube reactors and subjected to oxidative catalytic conversion in the reaction tubes. Steam is added to the feed mixture in an amount such that a steam fraction of the feed mixture is 5 to 95 vol %, oxygen is added to the feed mixture in the form of a fluid containing at least 95 vol % oxygen, and the oxidative catalytic conversion is carried out using one or more catalysts containing the metals molybdenum, vanadium, niobium and optionally tellurium.Type: ApplicationFiled: March 14, 2022Publication date: May 9, 2024Inventors: Mathieu Zellhuber, Martin Schubert, Andreas Meiswinkel, Gerhard Mestl, Klaus Wanninger, Peter Scheck, Anina Wohl
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Publication number: 20240123421Abstract: A reactor for carrying out a chemical reaction using multiphase alternating current, includes a reactor chamber surrounded by thermally insulating reactor walls and multiple substantially straight reaction tubes. The reaction tubes run between at least one tube inlet opening and at least one tube outlet opening in opposite reactor walls and consist of a material that permits electrical resistance heating. Two electrically conductive bridges spaced apart along the reaction tubes are provided, each of which electrically conductively connects the reaction tubes to one another. Electrically conductive power input arrangements are provided extending through one or more input openings in one of the reactor walls. Each reaction tube is electrically conductively connected to one of the power input arrangements. Each power input arrangement is electrically conductively connected between the bridges to one of the reaction tubes and is connected or connectable to one of the phases of the alternating current.Type: ApplicationFiled: February 7, 2022Publication date: April 18, 2024Inventors: Mathieu Zellhuber, Martin Hofstatter, Heinz Posselt, Clara Delhomme-Neudecker, Dieter Mihailowitsch
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Publication number: 20240100498Abstract: A reactor for carrying out a chemical reaction includes a reactor wall and at least one group of M reaction tubes, each of which has an electrically heatable heating section that extends between a first and a second removal region. Each heating section has a respective feed region in a region which extends over 20% to 80% of a heating length of the heating section and electrically conductive feed elements. Each group M is paired with the feed elements connected to the feed regions of the group, and different phases of the alternating current can be fed to different feed elements paired with a group. Each group is paired with M first and M second removal elements connected to the first or second removal regions of the group, respectively. Each group is paired with a first and a second star bridge.Type: ApplicationFiled: September 9, 2021Publication date: March 28, 2024Inventors: Martin Hofstatter, Clara Delhomme-Neudecker, Heinz Posselt, Mathieu Zellhuber
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Publication number: 20230356176Abstract: A method for regulatedly carrying out a chemical reaction in a reactor having reaction tubes which have a number of electrically heatable tube sections, wherein power connections are provided, which are each connected to at least one of the tube sections, wherein at least one connecting element is provided and each of the tube sections is connected to the connecting element. The method comprises conducting a process fluid through the one or more reaction tubes, providing several variable voltages at the several power connections, wherein the several voltages are provided as phases of a multiphase AC voltage so that the at least one connecting element forms a star point, setting the one or more voltages; detecting one or more measured values corresponding to one or more measured variables; changing the several set voltages so that the detected measured values correspond to predetermined values or value ranges of the measured variables.Type: ApplicationFiled: September 27, 2021Publication date: November 9, 2023Inventors: Christian Lang, Martin Hofstatter, Mathieu Zellhuber, Anton Wellenhofer, Robert Stegemann, Peter Reiser, Niklas Fleischmann, Christian Ziegler, Heinz Posselt, Clara Delhomme-Neudecker, Andrey Shustov, Eric Jenne, Heinz-Jurgen Kuhn, Kiara Aenne Kochendorfer, Heinrich Laib, Reiner Jacob
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Publication number: 20230302426Abstract: Disclosed is a reactor for carrying out a chemical reaction and a corresponding method. The reactor includes a vessel and one or more reaction tubes where a number of tube sections of the reaction tubes run between first second regions in the reactor vessel, and where the tube sections in the first region for the electrical heating of the tube sections can be electrically connected to the phase connections of a polyphase AC power source. Tube sections in the second region are electrically and conductively connected to one another as a whole by means of a single rigid connecting element, or in groups by means of a plurality of rigid connecting elements which are integrally connected to the reaction tubes and are arranged inside the reactor vessel. A corresponding method is also the subject-matter of the present invention.Type: ApplicationFiled: February 9, 2021Publication date: September 28, 2023Inventors: Mathieu Zellhuber, Martin Hofstatter, Heinz Posselt, Christian Lang, Clara Delhomme-Neudecker
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Publication number: 20230285929Abstract: A reactor has a reactor vessel and a reaction tube. Tube sections of the reaction tube run inside the reactor vessel. The tube sections are each electrically connectable to a current connection in a current feed region. Current feed arrangements are arranged in the current feed region to which in each case one or one group of the tube sections is electrically connected. Each current feed arrangement has a first and a second section, the first section extending along a longitudinal axis starting from the respective or group of tube section(s). The first section at least partially surrounds the second section or the second section surrounds the first section in a sleeve-like manner. The first and second sections each have contact surfaces arranged obliquely to the longitudinal axis. The current feed arrangements each extend through a wall of the reactor vessel.Type: ApplicationFiled: August 5, 2021Publication date: September 14, 2023Inventors: Heinz Posselt, Martin Hofstatter, Mathieu Zellhuber, Clara Delhomme-Neudecker, Eric Jenne, Kiara Aenne Kochendorfer, Andrey Shustov, Heinrich Laib, Heinz-Jurgen Kuhn, Reiner Jacob
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Publication number: 20230226511Abstract: A reactor has a reactor vessel and one or more reaction tubes. One or more power input elements are guided into the reactor vessel for the electrical heating of the reaction tube(s). The one or more power input elements each have a rod-shaped section, and the rod-shaped section(s) each run in a respective wall passage through a wall of the reactor vessel. A connection chamber into which the rod-shaped section(s) project is arranged outside the reactor vessel and adjacent to the wall of the reactor vessel through which the rod-shaped section(s) run in their wall passages. Gas feed means apply an inerting gas to the connection chamber, and the wall passages with the rod-shaped sections received therein in a longitudinally-movable manner are designed to be gas-permeable so that at least a portion of the inerting gas fed into the connection chamber flows out into the reactor vessel.Type: ApplicationFiled: April 22, 2021Publication date: July 20, 2023Inventors: Martin Hofstätter, Mathieu Zellhuber, Peter Reiser, Georg Kiese, Christian Ziegler, Robert Stegemann, Jens Aengenheister, Jürgen Feigl, Anton Wellenhofer, Clara Delhomme-Neudecker, Andrey Shustov, Eric Jenne, Kiara Aenne Kochendörfer, Heinrich Laib, Heinz-Jürgen Kühn, Reiner Jacob
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Publication number: 20230211305Abstract: A reactor for carrying out a chemical reaction has a reactor vessel, one or more reaction tubes and means for the electrical heating of the one or more reaction tubes. The reactor vessel has one or more discharge orifices which are permanently open or are set up to open above a preset pressure level, and gas feed means are provided, which are set up to feed an inerting gas into an interior of the reactor vessel.Type: ApplicationFiled: April 22, 2021Publication date: July 6, 2023Inventors: Martin Hofstätter, Mathieu Zellhuber, Peter Reiser, Georg Kiese, Christian Ziegler, Robert Stegemann, Jens Aengenheister, Jürgen Feigl, Anton Wellenhofer, Clara Delhomme-Neudecker, Andrey Shustov, Eric Jenne, Kiara Aenne Kochendörfer, Heinrich Laib, Heinz-Jürgen Kühn, Reiner Jacob
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Publication number: 20230116690Abstract: A reactor for carrying out a chemical reaction, which has a reactor vessel and one or more reaction tubes, wherein power input elements for electrical heating of the reaction tube(s) are guided into the reactor vessel. It is provided that the power input elements each have a rod-shaped section that, in each case, runs at a wall passage through a wall of the reactor vessel in such a way that a connection chamber into which the rod-shaped sections project is arranged outside the reactor vessel and adjacently to the wall of the reactor vessel through which the rod-shaped sections run at their wall passages, and that cooling panels through which a cooling fluid can flow are provided in the connection chamber and are arranged between at least two or between at least two groups of the rod-shaped sections that project into the connection chamber.Type: ApplicationFiled: March 11, 2021Publication date: April 13, 2023Inventors: Heinz Posselt, Mathieu Zellhuber, Martin Hofstätter, Clara Delhomme-Neudecker, Andrey Shustov, Eric Jenne, Kiara Aenne Kochendörfer, Heinrich Laib, Reiner Jacob, Heinz-Jürgen Kühn
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Publication number: 20230115461Abstract: A reactor includes a reactor vessel and one or more reaction tubes A number of tube sections of the one or more reaction tubes in each case run between a first region and a second region in the reactor vessel. For the electrical heating of the tube sections, the tube sections in the first region can be electrically connected to (a) current connection(s) of a current source. In the first region, current feed arrangements are provided; in each case one or in each case one group of the tube sections are electrically connected, and each comprise (a) contact passage(s) that in each case adjoin(s) at least one of the tube sections in the first region. A wall of the contact passages in each case is connected to a current feed element that has a rod-shaped section that runs at a wall passage through a wall of the reactor vessel.Type: ApplicationFiled: March 11, 2021Publication date: April 13, 2023Inventors: Mathieu Zellhuber, Martin Hofstätter, Heinz Posselt, Christian Lang, Robert Stegemann, Anton Wellenhofer, Volker Jeromin, Peter Reiser, Georg Kiese, Christian Ziegler, Andrey Shustov, Eric Jenne, Kiara Aenne Kochendörfer, Heinrich Laib, Heinz-Jürgen Kühn, Reiner Jacob, Clara Delhomme-Neudecker