Abstract: Herein discussed is a method of producing carbon monoxide or hydrogen or both simultaneously comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a mixed-conducting membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises a hydrocarbon; and (c) introducing a second stream to the cathode, wherein the second stream comprises carbon dioxide or water or both, wherein carbon monoxide is generated from carbon dioxide electrochemically and hydrogen is generated from water electrochemically.

Abstract: Herein discussed is a method of producing carbon monoxide comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises a fuel; and (c) introducing a second stream to the cathode, wherein the second stream comprises carbon dioxide, and wherein carbon monoxide is generated from carbon dioxide electrochemically; wherein the reactor comprises no interconnect and no current collector; wherein the reactor generates no electricity and receives no electricity; and wherein the reactor is operated at a temperature no higher than 750° C. In an embodiment, the reactor is operated at a temperature no higher than 700° C. or no higher than 650° C.

Abstract: A reactor assembly includes a multiplicity of electrochemical reactors, wherein each of the electrochemical reactors comprises an anode, a cathode, and a membrane between and in contact with the anode and the cathode, wherein the anode or the cathode forms a fluid passage having an inlet and an outlet, wherein the surface area of the fluid passage in contact with the anode or cathode is at least 25 times of the combined cross-sectional area of the inlet and the outlet; wherein the minimum distance between the reactors is no greater than 2 cm; and wherein the reactors have no interconnects and no direct contact with one another.

Abstract: An electrochemical reactor includes an anode, a cathode, and a membrane between and in contact with the anode and the cathode, wherein the anode or the cathode forms a fluid passage having an inlet and an outlet, wherein the surface area of the fluid passage in contact with the anode or cathode is at least 25 times of the combined cross-sectional area of the inlet and the outlet. Further discussed herein is an electrochemical reactor comprising an anode, a cathode, and a membrane between and in contact with the anode and the cathode, wherein the anode or the cathode forms a fluid passage having an inlet and an outlet, wherein a tortuosity of the fluid passage is no less than 10, wherein tortuosity is the ratio of fluid flow path length to the straight distance between the inlet and the outlet.

Abstract: Herein discussed is a method of producing hydrogen comprising introducing a metal smelter effluent gas or a basic oxygen furnace (BOF) effluent gas or a mixture thereof into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane. In an embodiment, the method comprises introducing steam into the EC reactor on one side of the membrane, wherein the effluent gas is on the opposite side of the membrane, wherein the effluent gas and the steam are separated by the membrane and do not come in contact with each other.

Abstract: Herein discussed is a device comprising a metal chamber having a first internal space; a plate and a connector in the first internal space; and a ceramic chamber having a second internal space, wherein the ceramic chamber is inside the metal chamber and the second internal space penetrates the plate; wherein the plate is configured to expand or contract and remain in contact with the connector such that the first and second internal spaces are not in fluid communication with one another. In an embodiment, the ceramic chamber wall is in contact with the plate but does not penetrate the plate. In an embodiment, the device produces no electricity and receives no electricity.

Abstract: A device including a metal chamber having a first internal space defined by at least one metal chamber wall; a plate in the first internal space; and a ceramic chamber having a second internal space defined by at least one ceramic chamber wall, a closed bend, and two openings, wherein the ceramic chamber is inside the metal chamber and the second internal space penetrates the plate such that the two openings and the closed bend are on opposite sides of the plate; wherein the first and second internal spaces are not in fluid communication with one another.

Abstract: Herein discussed is a method of producing hydrogen comprising: providing a tubular reactor having an open end and a closed end, wherein the reactor comprises an anode on the inside and a cathode on the outside separated by and in contact with a mixed conducting electrolyte, wherein the electrolyte comprises an electronically conducting phase and an ionically conducting phase, wherein the reactor comprises no current collector or interconnect; introducing a hydrocarbon and an oxidant into a feed tube, wherein the feed tube contains a catalyst that promotes catalytic partial oxidation (CPOX) reactions, wherein the feed tube extends into the open end of the reactor and toward the closed end of the reactor; introducing steam to the outside of the tubular reactor; and converting steam to hydrogen electrochemically without electricity input.

Abstract: Herein discussed is a device comprising an anode, a cathode, an electrolyte in contact with the anode and the cathode, and an interconnect, wherein the anode and the cathode are short circuited via electronic communication through the interconnect. In an embodiment, the anode and the cathode are separated by the electrolyte and the interconnect.

Abstract: Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, wherein the membrane conducts both electrons and protons, wherein the anode and cathode are porous; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia or a cracked ammonia product; and (c) extracting a second stream from the cathode, wherein the second stream comprises hydrogen, wherein the first stream and the second stream are separated by the membrane.

Abstract: Herein discussed is a method of co-producing carbon monoxide and hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a mixed-conducting membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises a fuel; (c) introducing a second stream to the cathode, wherein the second stream comprises carbon dioxide and water, wherein carbon monoxide is generated from carbon dioxide electrochemically and hydrogen is generated from water electrochemically. In an embodiment, the anode and the cathode are separated by the membrane and are both exposed to reducing environments during the entire time of operation.

Abstract: Herein discussed is a method of making an electrochemical device comprising (a) infiltrating an anode precursor, a cathode precursor, and an electrolyte precursor with a dispersion to produce an infiltrated anode precursor, an infiltrated cathode precursor, and an infiltrated electrolyte precursor, wherein the dispersion comprises metal ions and nanoparticles selected from the group consisting of metallic nanoparticles, metal-oxide nanoparticles, ceramic nanoparticles, and combinations thereof; wherein the metal ions percolate each precursor, wherein the anode precursor, the cathode precursor, and the electrolyte precursor are porous, the electrolyte precursor having an average pore size that is 50% or less of an average pore size of the anode precursor and that is 50% or less of an average pore size of the cathode precursor; and (b) co-sintering the infiltrated anode precursor, the infiltrated cathode precursor, and the infiltrated electrolyte precursor such that the infiltrated anode precursor becomes a por

Abstract: Herein discussed is a method of producing hydrogen comprising: providing a tubular reactor having an open end and a closed end, wherein the reactor comprises an anode on the inside and a cathode on the outside separated by and in contact with a mixed conducting electrolyte, wherein the electrolyte comprises an electronically conducting phase and an ionically conducting phase, wherein the reactor comprises no current collector or interconnect; introducing a hydrocarbon and an oxidant into a feed tube, wherein the feed tube contains a catalyst that promotes catalytic partial oxidation (CPOX) reactions, wherein the feed tube extends into the open end of the reactor and toward the closed end of the reactor; introducing steam to the outside of the tubular reactor; and converting steam to hydrogen electrochemically without electricity input.

Abstract: Herein discussed is a hydrogen production system comprising: a catalytic partial oxidation (CPOX) reactor; a steam generator; and an electrochemical (EC) reactor; wherein the CPOX reactor product stream is introduced into the EC reactor and the steam generator provides steam to the EC reactor; and wherein the product stream and the steam do not come in contact with each other in the EC reactor. In an embodiment, the EC reactor generates a first product stream comprising CO and CO2 and a second product stream comprising H2 and H2O, wherein the two product streams do not come in contact with each other.

Abstract: Herein discussed is a method of producing hydrogen comprising introducing a first stream comprising a fuel to an electrochemical (EC) reactor having a mixed-conducting membrane, introducing a second stream comprising water to the reactor, reducing the water in the second stream to produce hydrogen, and recycling at least portion of the produced hydrogen to the first stream, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase; and wherein the first stream and the second stream do not come in contact with each other in the reactor.

Abstract: Herein discussed is a method of producing hydrogen or carbon monoxide comprising introducing a waste gas having a total combustible species (TCS) content of no greater than 60 vol % into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase. Also disclosed herein is an integrated hydrogen production system comprising a waste gas source and an electrochemical (EC) reactor comprising a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase, wherein the waste gas source is configured to send its exhaust to the EC reactor, wherein the exhaust has a total combustible species (TCS) content of no greater than 60 vol %.

Abstract: Herein discussed is a method of using an oxide ion conducting membrane comprising exposing the oxide ion conducting membrane to a reducing environment on both sides of the membrane. In an embodiment, the oxide ion conducting membrane also conducts electrons. In various embodiments, the membrane is impermeable to fluid flow (e.g., having a permeability of less than 1 micro darcy). In an embodiment, the oxide ion conducting membrane comprises lanthanum chromite and a material selected from the group consisting of doped ceria, yttria-stabilized zirconia (YSZ), lanthanum strontium gallate magnesite (LSGM), scandia-stabilized zirconia (SSZ), Sc and Ce doped zirconia, and combinations thereof. In an embodiment, the lanthanum chromite comprises undoped lanthanum chromite, strontium doped lanthanum chromite, iron doped lanthanum chromite, strontium and iron doped lanthanum chromite, lanthanum calcium chromite, or combinations thereof. In an embodiment, the membrane is mixed conducting.

Abstract: A hydrogen production system comprising: a fuel source; a water source; and a hydrogen producer; where the fuel source and the water source are in fluid communication with the hydrogen producer; and where fuel enters the hydrogen producer from the fuel source and water enters the hydrogen producer from the water source and the fuel and the water do not come in contact with each other in the hydrogen producer.

Abstract: A device includes a first electrode, a second electrode, and an electrolyte between the electrodes. The first electrode and the second electrode may comprise a metallic phase that does not contain a platinum group metal when the device is in use, and where the electrolyte is solid state and is oxide ion conducting.

Abstract: A method of producing hydrogen includes providing a device, introducing a first stream including a fuel to the device, introducing a second stream comprising water to the device, reducing the water in the second stream to hydrogen, and extracting hydrogen from the device. The first stream and the second stream do not come in contact with each other in the device.