Abstract: Embodiments are directed to catalyst systems comprising: a procatalyst; and a co-catalyst dissolved in a non-halogenated aprotic hydrocarbon solvent, the co-catalyst comprising: a non-coordinating borate dianion having the formula: (III) and two cations, each cation being independently chosen from a cation according to formula (I) or formula (II).

Abstract: In an embodiment, an energy-absorbing device can comprise: a polymer reinforcement structure, wherein the polymer reinforcement structure comprises a polymer matrix and chopped fibers; and a shell comprising 2 walls extending from a back and forming a shell channel, wherein the shell comprises continuous fibers and a resin matrix; wherein the polymer reinforcement structure is located in the shell channel.

Abstract: In an embodiment, an energy-absorbing device can comprise: a polymer reinforcement structure, wherein the polymer reinforcement structure comprises a polymer matrix and chopped fibers; and a shell comprising 2 walls extending from a back and forming a shell channel, wherein the shell comprises continuous fibers and a resin matrix; wherein the polymer reinforcement structure is located in the shell channel.

Abstract: A vehicle energy absorbing system for a high-speed, small-overlap impact, comprising: lobes (12) spaced intermittently along a vehicle rail (1), wherein the lobes (12) include an impact arm (14), a reactionary arm (16), and a base (22), wherein a shape of the base (22) is complimentary to a shape of the vehicle rail (1) and wherein the impact arm (14) and the reactionary arm (16) protrude outwardly from the base (22) and the vehicle rail (1), wherein a channel (20) is formed in the space between the base (22), the impact arm (14), and the reactionary arm (16), wherein the channel (20) extends through the lobe (12) from end to end.

Abstract: In an embodiment, multi-stage energy absorbing system can comprise: a thermoplastic flanged frame and a crush lobe having a proximal base aligned with the flanged frame and a distal end protruding from the flanged frame. The crush lobe comprises a central slab and slab pairs such that the crush lobe comprises a total of 2i+1 slabs, wherein i is the number of slab pairs and is greater than or equal to 1. The slabs are disposed in a stepped arrangement and configured to absorb impact energy by collapsing in a telescopic manner with increasing energy level. The single energy-absorbing system is able to absorb low energy impact associated with vehicle-to-pedestrian impact; simultaneously with the ability to mitigate damageability associated with low-speed vehicle-to-barrier impact, as well as damageability associated with vehicle-to-vehicle moderate speed impact, head-on, as well as at an angle.

Abstract: A method of making a hybrid energy absorbing beam, comprises: forming a polymer member comprising a first portion, wherein the first portion includes a first ledge and a connecting ledge connected by a first portion wall; and a rib extending from the first portion wall, wherein a cross-section of the rib taken along a line, A-A, comprises a first channel formed from an opening between a channel wall and a first traverse wall of a lobe, wherein the lobe comprises the first traverse wall and a second traverse wall with a connecting wall disposed between the first traverse wall and the second traverse wall; wherein the first channel extends along a portion of a length, Lp, of the polymer member; and forming a metal/composite member; and attaching the polymer member to the metal/composite member on an opposite side of the polymer member as the connecting wall.

Abstract: A vehicle energy absorbing system for a high-speed, small-overlap impact, comprising: lobes (12) spaced intermittently along a vehicle rail (1), wherein the lobes (12) include an impact arm (14), a reactionary arm (16), and a base (22), wherein a shape of the base (22) is complimentary to a shape of the vehicle rail (1) and wherein the impact arm (14) and the reactionary arm (16) protrude outwardly from the base (22) and the vehicle rail (1), wherein a channel (20) is formed in the space between the base (22), the impact arm (14), and the reactionary arm (16), wherein the channel (20) extends through the lobe (12) from end to end.

Abstract: A structural body of a vehicle comprises: a hollow component comprising walls that define a channel, wherein the component has a component length, and wherein the component is selected from the group consisting of beam, rail (58), pillar (50,52,54,5), chassis, floor rocker (60), and cross-bar, or combinations comprising at least one of the foregoing; and a plastic-metal hybrid reinforcement (1) having cavities therethrough (14), and a support (6) having greater than or equal to 3 walls forming a support channel. The plastic element (4) is located in the support channel (6) wherein the reinforcement (1) is located in the component channel.

Abstract: A method of making a hybrid energy absorbing beam, comprises: forming a polymer member comprising a first portion, wherein the first portion includes a first ledge and a connecting ledge connected by a first portion wall; and a rib extending from the first portion wall, wherein a cross-section of the rib taken along a line, A-A, comprises a first channel formed from an opening between a channel wall and a first traverse wall of a lobe, wherein the lobe comprises the first traverse wall and a second traverse wall with a connecting wall disposed between the first traverse wall and the second traverse wall; wherein the first channel extends along a portion of a length, Lp, of the polymer member; and forming a metal/composite member; and attaching the polymer member to the metal/composite member on an opposite side of the polymer member as the connecting wall.

Abstract: In an embodiment, an energy-absorbing device can comprise: a polymer reinforcement structure, wherein the polymer reinforcement structure comprises a polymer matrix and chopped fibers; and a shell comprising 2 walls extending from a back and forming a shell channel, wherein the shell comprises continuous fibers and a resin matrix; wherein the polymer reinforcement structure is located in the shell channel.

Abstract: In one embodiment, a rail extension comprises: an energy absorber comprising a polymer body, wherein the energy absorber comprises cells formed by cell walls extending a length of the energy absorber and forming cavities therethrough; each side of the energy absorber comprises an open channel wherein the channel is defined by walls of adjacent cells; a vehicle attachment tab extending from at least one of the cell walls at one end of the energy absorber; and a first vehicle attachment tab gusset extending between the vehicle attachment tab and the cell wall on one side of an opening in the vehicle attachment; wherein the energy absorber and the vehicle attachment tab were formed as one-piece.

Abstract: A structural body of a vehicle comprises: a hollow component comprising walls that define a channel, wherein the component has a component length, and wherein the component is selected from the group consisting of beam, rail (58), pillar (50,52,54,5), chassis, floor rocker (60), and cross-bar, or combinations comprising at least one of the foregoing; and a plastic-metal hybrid reinforcement (1) having cavities therethrough (14), and a support (6) having greater than or equal to 3 walls forming a support channel. The plastic element (4) is located in the support channel (6) wherein the reinforcement (1) is located in the component channel.

Abstract: In one embodiment, a rail extension comprises: an energy absorber comprising a polymer body, wherein the energy absorber comprises cells formed by cell walls extending a length of the energy absorber and forming cavities therethrough; each side of the energy absorber comprises an open channel wherein the channel is defined by walls of adjacent cells; a vehicle attachment tab extending from at least one of the cell walls at one end of the energy absorber; and a first vehicle attachment tab gusset extending between the vehicle attachment tab and the cell wall on one side of an opening in the vehicle attachment; wherein the energy absorber and the vehicle attachment tab were formed as one-piece.

Abstract: In one embodiment, a rail extension comprises: an energy absorber comprising a polymer body, and vehicle attachment tabs extending from one end of the energy absorber and configured to attach to a vehicle rail, and an attachment tab extending from another end of the energy absorber and configured to attach to a bumper beam. The energy absorber can comprise cells formed by cell walls extending a length of the energy absorber and forming cavities therethrough; and open channels formed on each side of the energy absorber, wherein the channels are defined by walls of adjacent cells. A vehicle can comprise: a bumper beam; a vehicle rail; and the rail extensions.

Abstract: A thermoplastic energy absorber having a horizontal axis and a vertical axis, and comprise: an array of energy absorbing lobes protruding from a base, the lobes arranged in two or more rows. The energy absorbing lobes can have a vertical length (L) and a horizontal width (D), and wherein a ratio of L:D is greater than 1. The energy absorbing lobes in each row can be disposed in a staggered manner with respect to energy absorbing lobes in an adjacent row. The energy absorber can be configured to be installed on a vehicle for absorption of impact energy. An energy absorbing system can comprise the thermoplastic energy absorber disposed between a bumper beam and a fascia. The fascia can optionally be configured to envelope the thermoplastic energy absorber and the bumper beam. This system passes EuroNCAP lower-leg impact requirements, version 5.1, June 2011, for lower leg impact requirement.

Abstract: A structural body of a vehicle can comprises: a hollow metal component comprising walls that define a channel, wherein the metal component has a metal component length, and wherein the metal component is selected from the group consisting of beam, rail, pillar, chassis, floor rocker, and cross-bar, combinations comprising at least one of the foregoing; and a plastic-metal hybrid reinforcement having a cavities therethrough, and a metal support having greater than or equal to 3 walls forming a support channel. The plastic element is located in the support channel wherein the reinforcement is located in the component channel.

Abstract: In one embodiment, a rail extension comprises: an energy absorber comprising a polymer body, and vehicle attachment tabs extending from one end of the energy absorber and configured to attach to a vehicle rail, and an attachment tab extending from another end of the energy absorber and configured to attach to a bumper beam. The energy absorber can comprise cells formed by cell walls extending a length of the energy absorber and forming cavities therethrough; and open channels formed on each side of the energy absorber, wherein the channels are defined by walls of adjacent cells. A vehicle can comprise: a bumper beam; a vehicle rail; and the rail extensions.

Abstract: A structural body of a vehicle can comprises: a hollow metal component comprising walls that define a channel, wherein the metal component has a metal component length, and wherein the metal component is selected from the group consisting of beam, rail, pillar, chassis, floor rocker, and cross-bar, combinations comprising at least one of the foregoing; and a plastic-metal hybrid reinforcement having a cavities therethrough, and a metal support having greater than or equal to 3 walls forming a support channel. The plastic element is located in the support channel wherein the reinforcement is located in the component channel.

Abstract: A method for processing reinforcing filler-filled synthetic resins and applications made therefrom wherein the resulting articles have the ability to be plated to form a structurally aesthetic product substantially free of visual defects. The process utilizes an accelerated heat and cool process to form a resin-rich surface that is substantially free of any reinforcing fillers, such as fiber strands and/or bundles, on the external surface of the article. As such, the resulting article is capable of being plated to form an article that is substantially free of visual defects caused by these fillers on the surface of the article.