Abstract: This invention is directed to a golf ball core that has hardness gradients created in its outer skin by the application of high temperatures from infrared radiation. The outer 0.001 to 0.040 inches of the core has a different hardness than the rest of the core. The skin can either be harder or softer than the rest of the core.

Abstract: This invention is directed to a method for creating cure gradients in golf balls and golf ball cores by the application of high temperatures from infrared radiation. The hardness gradients are created in the outer skin wherein the outer 0.001 to 0.040 inches of the core has a different hardness than the rest of the core. The same hardness gradients can be applied to the outer skin of any intermediate or cover layers. The skin can either be harder or softer than the rest of the component. The skins can be compounded by materials that will be reactive at temperatures produced by infrared radiation.

Abstract: A golf ball comprising a core, an intermediate layer and a cover, wherein the intermediate layer has a moisture vapor transmission rate that is lower than that of the cover and, additionally, a primary ingredient of the intermediate layer is made from a material including polybutadiene, natural rubber, butyl-based rubber, acrylics, trans-polyisoprene, neoprene, chlorinated polyethylene, balata, multi-layer thermoplastic films, blends of ionomers, polyvinyl alcohol copolymer and polyamides, and dispersions of acid salts of polyetheramines.

Abstract: A golf ball comprising a core, a cover, and at least one water vapor barrier layer, wherein the water vapor barrier layer comprises at least one layer formed from poly-para-xylylene and its derivatives.

Abstract: Golf equipment, or a portion thereof, with improved abrasion resistance is obtained by applying a coating comprising hard filler particles, a coupling agent and a polymer precursor preferably comprising a plurality of reactive monomers and/or oligomers. Colloidal silica may be used as the filler, silanes of the form Y—(CH2)nSiX3, wherein Y is an organofunctional group providing the bonding with the polymer matrix attached to the central silicon atom via the stable (CH2)n carbon chain and X represents the silicon-functional or alkoxy group that hydrolyzes and subsequently reacts with the active sites on inorganic surfaces. The coating may be hardened by curing with ultraviolet radiation or solvent evaporation and crosslinking.

Abstract: A golf ball with at least one moisture vapor barrier layer is disclosed. In accordance to one aspect of the invention, the moisture vapor barrier layer may comprise nano particles, flaked glass, flaked metals or ceramic particles to increase the layer's resistance to the transmission of moisture through the layer. In accordance to another aspect of the invention, the moisture vapor barrier layer may comprise a soft, high specific gravity layer to increase the moment of inertia of the golf ball. In accordance to another aspect of the invention, the moisture vapor barrier layer may comprise a multi-layer thermoplastic film. In accordance to another aspect of the invention, the moisture vapor barrier layer may be positioned adjacent to a wound layer such that the moisture vapor barrier layer penetrates into the interstitial spaces in the wound layer to minimize the transmission of moisture vapor through the wound layer.

Abstract: A golf ball with at least one moisture vapor barrier layer is disclosed. In accordance to one aspect of the invention, the moisture vapor barrier layer may comprise butyl rubber. The butyl rubber may also be a halogenated butyl rubber such as bromobutyl rubber or chlorobutyl rubber. The butyl rubber may also be a sulfonated butyl rubber. The butyl rubber may be blended with other polymers. In accordance to another aspect of the invention, the moisture vapor barrier layer is placed on to a core subassembly and cured by infrared radiation (IR). IR-curable moisture vapor barrier materials include, but not limited to, butyl rubber, polysulfide rubber and single-pack castable polymers, among others. In accordance to another aspect of the invention, an outer layer of the golf ball may comprise a polymer that has a cured temperature greater than the softening temperature or melting temperature of the encased subassembly. Such outer layer may be cured by IR.

Abstract: A method for increasing adhesion between golf ball layers comprising the steps of providing a golf ball layer having a first surface; preparing the first surface for treatment; exposing the first layer to a silane; providing a second golf ball layer; and adhering the second layer to the first via the silane. Additionally, a golf ball including an inner component, a molecular monolayer, and at least one cover layer, wherein the inner component and the at least one cover layer have differing surface energies and the cover layer is adhered to inner component with the molecular monolayer.

Abstract: Golf equipment, or a portion thereof, with improved abrasion resistance is obtained by applying a coating comprising hard filler particles, a coupling agent and a polymer precursor preferably comprising a plurality of reactive monomers and/or oligomers. Colloidal silica may be used as the filler, silanes of the form Y—(CH2)nSiX3, wherein Y is an organofunctional group providing the bonding with the polymer matrix attached to the central silicon atom via the stable (CH2)n, carbon chain and X represents the silicon-functional or alkoxy group that hydrolyzes and subsequently reacts with the active sites on inorganic surfaces. The coating may be hardened by curing with ultraviolet radiation or solvent evaporation and crosslinking.

Abstract: Film-forming compositions which are substantially free of organic solvent and capable of forming a generally continuous film at ambient temperature are provided. The film-forming composition includes at least one thermosettable aqueous dispersion of polymeric microparticles having functionality adapted to react with a crosslinking agent. The polymeric microparticles are prepared by mixing under high shear conditions (1) at least one hydrophobic polymer having reactive functional groups; and (2) at least one hydrophobic crosslinking agent containing functional groups which are reactive with the functional groups of the polymer. Further provided is a multi-component composite coating composition which includes a pigmented base coat and a transparent topcoat of the substantially organic solvent-free film-forming composition described above. Substrates coated with the same are also provided. Additionally, a method for preparing the aqueous dispersion of polymeric microparticles is provided.

Abstract: The present invention is directed to a method of making a golf ball comprising the steps of cooling a golf ball subassembly such that the golf ball subassembly undergoes a volumetric reduction, and applying a cover layer over the volumetrically reduced golf ball subassembly. The method can further include a three-step curing process after applying the cover layer. The three-steps include maintaining mold halves containing the covered subassembly at a first temperature, heating the mold halves to a second temperature, then maintaining the mold halves at a third temperature. Also, the method can include cooling the cover materials in a mixer so that higher levels of catalyst can be used.