Abstract: Methods of making N-hydroxyalkylated polyamines are provided, in which the method includes reacting a polyamine comprising Formula (XXIV): with a cyclic oxide to produce the N-hydroxyalkylated polyamine, where R1 and R2 are independently a —C or —CH group; R3 is an aliphatic hydrocarbyl; and R4 and R5 are independently acyclic hydrocarbyls, or are covalently connected to form an unsaturated cyclic hydrocarbyl.

Abstract: N-hydroxyalkylated polyamines, methods of making N-hydroxyalkylated polyamines, and drilling fluids containing N-hydroxyalkylated polyamines are provided, in which the N-hydroxyalkylated polyamine includes Formula (I): where R1 and R2 are independently a —C or —CH group; R3 is an aliphatic hydrocarbyl; R4 and R5 are independently acyclic hydrocarbyls, or R1, R2, R4, and R5 are covalently connected to form a cyclic hydrocarbyl; and R6, R7, R8, and R9 are independently acyclic hydrocarbyls or acyclic heterohydrocarbyls.

Abstract: Treating a subterranean formation with a composition including a maleic anhydride copolymer, an amine crosslinker, and a gelling agent. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: where each R1 is independently-H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R2 is independently-H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R3 is independently —OH or —O?M1, each M1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R4 is independently-NH2 or —OM1. The gelling agent includes at least one of: a calcium chelating agent, a calcium precipitating agent, a pH buffer, an agent reactive with hydroxide, and an acid generating agent, and promotes formation of a gel from the maleic anhydride copolymer and the amine crosslinker in contact with set cement.

Abstract: Methods of making N-hydroxyalkylated polyamines are provided, in which the method includes reacting a polyamine comprising Formula (XXIV): with a cyclic oxide to produce the N-hydroxyalkylated polyamine, where R1 and R2 are independently a —C or —CH group; R3 is an aliphatic hydrocarbyl; and R4 and R5 are independently acyclic hydrocarbyls, or are covalently connected to form an unsaturated cyclic hydrocarbyl.

Abstract: In a method to degrade filtercake in a hydrocarbon reservoir using downhole in-situ heat generation, a filtercake breaker, configured to degrade filtercake at a temperature, is mixed with a drilling fluid. The drilling fluid mixed with the filtercake breaker is flowed through a hydrocarbon reservoir in which a wellbore is being drilled. A filtercake forms in a portion of the hydrocarbon reservoir responsive to flowing the drilling fluid. A temperature of the portion of the hydrocarbon reservoir is less than the temperature at which the filtercake breaker is configured to degrade filtercake. Multiple filtercake chemicals are flowed to the portion of the hydrocarbon reservoir. The multiple filtercake chemicals, when mixed, are configured to react in an exothermic reaction to release heat to increase the temperature of the portion of the hydrocarbon reservoir to at least the temperature at which the filtercake breaker is configured to degrade filtercake.

Abstract: In a method to degrade filtercake in a hydrocarbon reservoir using downhole in-situ heat generation, a filtercake breaker, configured to degrade filtercake at a temperature, is mixed with a drilling fluid. The drilling fluid mixed with the filtercake breaker is flowed through a hydrocarbon reservoir in which a wellbore is being drilled. A filtercake forms in a portion of the hydrocarbon reservoir responsive to flowing the drilling fluid. A temperature of the portion of the hydrocarbon reservoir is less than the temperature at which the filtercake breaker is configured to degrade filtercake. Multiple filtercake chemicals are flowed to the portion of the hydrocarbon reservoir. The multiple filtercake chemicals, when mixed, are configured to react in an exothermic reaction to release heat to increase the temperature of the portion of the hydrocarbon reservoir to at least the temperature at which the filtercake breaker is configured to degrade filtercake.

Abstract: Treating a subterranean formation with a composition including a maleic anhydride copolymer, an amine crosslinker, and a gelling agent. The maleic anhydride copolymer includes first repeat units I and II and at least one of second repeat units III and IV: where each R1 is independently-H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R2 is independently-H, —O(C1-C5) alkyl, or —(C1-C5) alkyl; each R3 is independently —OH or —O?M1, each M1 is independently an alkali metal, an alkaline earth metal, an ammonium ion, or a quaternary ammonium ion; and each R4 is independently-NH2 or —OM1. The gelling agent includes at least one of: a calcium chelating agent, a calcium precipitating agent, a pH buffer, an agent reactive with hydroxide, and an acid generating agent, and promotes formation of a gel from the maleic anhydride copolymer and the amine crosslinker in contact with set cement.

Abstract: In a method to degrade filtercake in a hydrocarbon reservoir using downhole in-situ heat generation, a filtercake breaker, configured to degrade filtercake at a temperature, is mixed with a drilling fluid. The drilling fluid mixed with the filtercake breaker is flowed through a hydrocarbon reservoir in which a wellbore is being drilled. A filtercake forms in a portion of the hydrocarbon reservoir responsive to flowing the drilling fluid. A temperature of the portion of the hydrocarbon reservoir is less than the temperature at which the filtercake breaker is configured to degrade filtercake. Multiple filtercake chemicals are flowed to the portion of the hydrocarbon reservoir. The multiple filtercake chemicals, when mixed, are configured to react in an exothermic reaction to release heat to increase the temperature of the portion of the hydrocarbon reservoir to at least the temperature at which the filtercake breaker is configured to degrade filtercake.

Abstract: In a method to degrade filtercake in a hydrocarbon reservoir using downhole in-situ heat generation, a filtercake breaker, configured to degrade filtercake at a temperature, is mixed with a drilling fluid. The drilling fluid mixed with the filtercake breaker is flowed through a hydrocarbon reservoir in which a wellbore is being drilled. A filtercake forms in a portion of the hydrocarbon reservoir responsive to flowing the drilling fluid. A temperature of the portion of the hydrocarbon reservoir is less than the temperature at which the filtercake breaker is configured to degrade filtercake. Multiple filtercake chemicals are flowed to the portion of the hydrocarbon reservoir. The multiple filtercake chemicals, when mixed, are configured to react in an exothermic reaction to release heat to increase the temperature of the portion of the hydrocarbon reservoir to at least the temperature at which the filtercake breaker is configured to degrade filtercake.

Abstract: In a method to degrade filtercake in a hydrocarbon reservoir using downhole in-situ heat generation, a filtercake breaker, configured to degrade filtercake at a temperature, is mixed with a drilling fluid. The drilling fluid mixed with the filtercake breaker is flowed through a hydrocarbon reservoir in which a wellbore is being drilled. A filtercake forms in a portion of the hydrocarbon reservoir responsive to flowing the drilling fluid. A temperature of the portion of the hydrocarbon reservoir is less than the temperature at which the filtercake breaker is configured to degrade filtercake. Multiple filtercake chemicals are flowed to the portion of the hydrocarbon reservoir. The multiple filtercake chemicals, when mixed, are configured to react in an exothermic reaction to release heat to increase the temperature of the portion of the hydrocarbon reservoir to at least the temperature at which the filtercake breaker is configured to degrade filtercake.

Abstract: N-hydroxyalkylated polyamines, methods of making N-hydroxyalkylated polyamines, and drilling fluids containing N-hydroxyalkylated polyamines are provided, in which the N-hydroxyalkylated polyamine includes Formula (I): where R1 and R2 are independently a —C or —CH group; R3 is an aliphatic hydrocarbyl; R4 and R5 are independently acyclic hydrocarbyls, or R1, R2, R4, and R5 are covalently connected to form a cyclic hydrocarbyl; and R6, R7, R8, and R9 are independently acyclic hydrocarbyls or acyclic heterohydrocarbyls.

Abstract: N-hydroxyalkylated polyamines, methods of making N-hydroxyalkylated polyamines, and drilling fluids containing N-hydroxyalkylated polyamines are provided, in which the N-hydroxyalkylated polyamine includes Formula (I): where R1 and R2 are independently a —C or —CH group; R3 is an aliphatic hydrocarbyl; R4 and R5 are independently acyclic hydrocarbyls, or R1, R2, R4, and R5 are covalently connected to form a cyclic hydrocarbyl; and R6, R7, R8, and R9 are independently acyclic hydrocarbyls or acyclic heterohydrocarbyls.

Abstract: N-hydroxyalkylated polyamines, methods of making N-hydroxyalkylated polyamines, and drilling fluids containing N-hydroxyalkylated polyamines are provided, in which the N-hydroxyalkylated polyamine includes Formula (I): where R1 and R2 are independently a —C or —CH group; R3 is an aliphatic hydrocarbyl; R4 and R5 are independently acyclic hydrocarbyls, or R1, R2, R4, and R5 are covalently connected to form a cyclic hydrocarbyl; and R6, R7, R8, and R9 are independently acyclic hydrocarbyls or acyclic heterohydrocarbyls.

Abstract: An oil-swellable gel lost circulation material (LCM) formed from an elastomeric polymer and a crosslinker amine is provided. The LCM may include gel pieces cut from gel strands formed from an elastomeric polymer and a crosslinker amine. The oil-swellable gel LCM composition may be formed by mixing an elastomeric polymer solution with a crosslinker amine and heating the mixture to form a crosslinked gel. The gel may be extruded through a die having orifices into a non-solvent and allowed to desolvate in the presence of the non-solvent. The gel strands may be dried and cut into gel pieces to form an LCM. The resulting LCM may swell when introduced to a loss circulation zone in the presence of a non-aqueous fluid such as a drilling mud or component of a drilling mud.

Abstract: An oil-swellable gel lost circulation material (LCM) formed from an elastomeric polymer and a crosslinker amine is provided. The LCM may include gel pieces cut from gel strands formed from an elastomeric polymer and a crosslinker amine. The oil-swellable gel LCM composition may be formed by mixing an elastomeric polymer solution with a crosslinker amine and heating the mixture to form a crosslinked gel. The gel may be extruded through a die having orifices into a non-solvent and allowed to desolvate in the presence of the non-solvent. The gel strands may be dried and cut into gel pieces to form an LCM. The resulting LCM may swell when introduced to a loss circulation zone in the presence of a non-aqueous fluid such as a drilling mud or component of a drilling mud.

Abstract: An oil-swellable gel lost circulation material (LCM) formed from an elastomeric polymer and a crosslinker amine is provided. The LCM may include gel pieces cut from gel strands formed from an elastomeric polymer and a crosslinker amine. The oil-swellable gel LCM composition may be formed by mixing an elastomeric polymer solution with a crosslinker amine and heating the mixture to form a crosslinked gel. The gel may be extruded through a die having orifices into a non-solvent and allowed to desolvate in the presence of the non-solvent. The gel strands may be dried and cut into gel pieces to form an LCM. The resulting LCM may swell when introduced to a loss circulation zone in the presence of a non-aqueous fluid such as a drilling mud or component of a drilling mud.

Abstract: An oil-swellable gel lost circulation material (LCM) formed from an elastomeric polymer and a crosslinker amine is provided. The LCM may include gel pieces cut from gel strands formed from an elastomeric polymer and a crosslinker amine. The oil-swellable gel LCM composition may be formed by mixing an elastomeric polymer solution with a crosslinker amine and heating the mixture to form a crosslinked gel. The gel may be extruded through a die having orifices into a non-solvent and allowed to desolvate in the presence of the non-solvent. The gel strands may be dried and cut into gel pieces to form an LCM. The resulting LCM may swell when introduced to a loss circulation zone in the presence of a non-aqueous fluid such as a drilling mud or component of a drilling mud.

Abstract: N-hydroxyalkylated polyamines, methods of making N-hydroxyalkylated polyamines, and drilling fluids containing N-hydroxyalkylated polyamines are provided, in which the N-hydroxyalkylated polyamine includes Formula (I): where R1 and R2 are independently a —C or —CH group; R3 is an aliphatic hydrocarbyl; R4 and R5 are independently acyclic hydrocarbyls, or R1, R2, R4, and R5 are covalently connected to form a cyclic hydrocarbyl; and R6, R7, R8, and R9 are independently acyclic hydrocarbyls or acyclic heterohydrocarbyls.

Abstract: An oil-swellable gel lost circulation material (LCM) formed from an elastomeric polymer and a crosslinker amine is provided. The LCM may include gel pieces cut from gel strands formed from an elastomeric polymer and a crosslinker amine. The oil-swellable gel LCM composition may be formed by mixing an elastomeric polymer solution with a crosslinker amine and heating the mixture to form a crosslinked gel. The gel may be extruded through a die having orifices into a non-solvent and allowed to desolvate in the presence of the non-solvent. The gel strands may be dried and cut into gel pieces to form an LCM. The resulting LCM may swell when introduced to a loss circulation zone in the presence of a non-aqueous fluid such as a drilling mud or component of a drilling mud.

Abstract: In a method to degrade filtercake in a hydrocarbon reservoir using downhole in-situ heat generation, a filtercake breaker, configured to degrade filtercake at a temperature, is mixed with a drilling fluid. The drilling fluid mixed with the filtercake breaker is flowed through a hydrocarbon reservoir in which a wellbore is being drilled. A filtercake forms in a portion of the hydrocarbon reservoir responsive to flowing the drilling fluid. A temperature of the portion of the hydrocarbon reservoir is less than the temperature at which the filtercake breaker is configured to degrade filtercake. Multiple filtercake chemicals are flowed to the portion of the hydrocarbon reservoir. The multiple filtercake chemicals, when mixed, are configured to react in an exothermic reaction to release heat to increase the temperature of the portion of the hydrocarbon reservoir to at least the temperature at which the filtercake breaker is configured to degrade filtercake.