Abstract: A method of operating a furnace having process tubes and multiple burners where it is desired to conform the temperatures of the process tubes to selected target temperature criterion. The present method provides a systematic and quantitative approach to determine how to adjust burner flow rates to result in desired tube wall temperatures, for example, using objective functions to decrease the probability that temperatures pertaining to the plurality of process tubes exceed their selected limit temperatures. An objective function can also be used to reduce the excess oxidant requirement for the furnace.

Abstract: A method of operating a furnace having process tubes and multiple burners where it is desired to conform the temperatures of the process tubes to selected target temperature criterion. The present method provides a systematic and quantitative approach to determine how to adjust burner flow rates to result in desired tube wall temperatures, for example, using objective functions to decrease the probability that temperatures pertaining to the plurality of process tubes exceed their selected limit temperatures. An objective function can also be used to reduce the excess oxidant requirement for the furnace.

Abstract: Pressure swing adsorption system comprising two or more vessels, each having a feed end, a product end, and adsorbent material adapted to adsorb one or more components from a multi-component feed gas mixture; piping adapted to (1) introduce the feed gas mixture into the feed ends, withdraw a product gas from the product ends, and withdraw a waste gas from the feed ends of the vessels, and (2) place the product ends of any pair of vessels in flow communication; a feed pipe adapted to supply the feed gas mixture to the system; a product pipe adapted to withdraw the product gas from the system; and a waste gas pipe adapted to withdraw the waste gas from the system. An indexed rotatable multi-port valve is adapted to place the product end of each vessel in sequential flow communication with the product end of each of the other vessels.

Abstract: Pressure swing adsorption system comprising two or more vessels, each having a feed end, a product end, and adsorbent material adapted to adsorb one or more components from a multi-component feed gas mixture; piping adapted to (1) introduce the feed gas mixture into the feed ends, withdraw a product gas from the product ends, and withdraw a waste gas from the feed ends of the vessels, and (2) place the product ends of any pair of vessels in flow communication; a feed pipe adapted to supply the feed gas mixture to the system; a product pipe adapted to withdraw the product gas from the system; and a waste gas pipe adapted to withdraw the waste gas from the system. An indexed rotatable multi-port valve is adapted to place the product end of each vessel in sequential flow communication with the product end of each of the other vessels.

Abstract: Pressure swing adsorption system comprising two or more vessels, each having a feed end, a product end, and adsorbent material adapted to adsorb one or more components from a multi-component feed gas mixture; piping adapted to (1) introduce the feed gas mixture into the feed ends, withdraw a product gas from the product ends, and withdraw a waste gas from the feed ends of the vessels, and (2) place the product ends of any pair of vessels in flow communication; a feed pipe adapted to supply the feed gas mixture to the system; a product pipe adapted to withdraw the product gas from the system; and a waste gas pipe adapted to withdraw the waste gas from the system. An indexed rotatable multi-port valve is adapted to place the product end of each vessel in sequential flow communication with the product end of each of the other vessels.

Abstract: Pressure swing adsorption process for producing oxygen comprising (a) providing at least one adsorber vessel having a first layer of adsorbent adjacent the feed end of the vessel and a second layer of adsorbent adjacent the first layer, wherein the surface area to volume ratio of the first layer is in the range of about 0.75 to about 1.8 cm?1; (b) introducing a pressurized feed gas comprising at least oxygen, nitrogen, and water into the feed end, adsorbing at least a portion of the water in the adsorbent in the first layer, and adsorbing at least a portion of the nitrogen in the adsorbent in the second layer, wherein the superficial contact time of the pressurized feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product gas enriched in oxygen from the product end of the adsorber vessel.

Abstract: Containerized gas separation system comprising (a) a container having an interior, an exterior, and an exterior volume defined by the exterior dimensions of the container and (b) a pressure swing adsorption system installed in the interior of the container and adapted to recover a product gas from a feed gas mixture, the pressure swing adsorption system being adapted to deliver the product gas at a product gas flow rate, wherein the ratio of the exterior volume of the container to the product gas flow rate is less than about 2000 ft3/(ton per day).

Abstract: Pressure swing adsorption system comprising two or more vessels, each having a feed end, a product end, and adsorbent material adapted to adsorb one or more components from a multi-component feed gas mixture; piping adapted to (1) introduce the feed gas mixture into the feed ends, withdraw a product gas from the product ends, and withdraw a waste gas from the feed ends of the vessels, and (2) place the product ends of any pair of vessels in flow communication; a feed pipe adapted to supply the feed gas mixture to the system; a product pipe adapted to withdraw the product gas from the system; and a waste gas pipe adapted to withdraw the waste gas from the system. An indexed rotatable multi-port valve is adapted to place the product end of each vessel in sequential flow communication with the product end of each of the other vessels.

Abstract: Pressure swing adsorption system comprising two or more vessels, each having a feed end, a product end, and adsorbent material adapted to adsorb one or more components from a multi-component feed gas mixture; piping adapted to (1) introduce the feed gas mixture into the feed ends, withdraw a product gas from the product ends, and withdraw a waste gas from the feed ends of the vessels, and (2) place the product ends of any pair of vessels in flow communication; a feed pipe adapted to supply the feed gas mixture to the system; a product pipe adapted to withdraw the product gas from the system; and a waste gas pipe adapted to withdraw the waste gas from the system. An indexed rotatable multi-port valve is adapted to place the product end of each vessel in sequential flow communication with the product end of each of the other vessels.

Abstract: PSA process for oxygen production comprising (a) providing an adsorber having a first layer of adsorbent selective for water and a second layer of adsorbent selective for nitrogen, wherein the heat of adsorption of water on the adsorbent in the first layer is ?about 14 kcal/mole at water loadings ?about 0.05 to about 3 mmol per gram; (b) passing a feed gas comprising at least oxygen, nitrogen, and water successively through the first and second layers, adsorbing water in the first layer of adsorbent, and adsorbing nitrogen in the second layer of adsorbent, wherein the mass transfer coefficient of water in the first layer is in the range of about 125 to about 400 sec?1 and the superficial contact time of the feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product enriched in oxygen from the adsorber.

Abstract: Portable medical oxygen concentrator comprising an air separation system adapted to recover oxygen from air; a bottom platform and a shell having an outer wall, wherein the shell is detachably connected to the bottom platform, wherein the shell and bottom platform define an enclosed volume when the shell is connected to the bottom platform, and wherein the air separation system is disposed in the enclosed volume; and one or more rechargeable batteries detachably connected to the outer wall of the shell and adapted to provide power to drive the air separation system. The air separation system may comprises a pressure swing adsorption system having two or more adsorbent columns and a rotary valve for directing gas flow sequentially to, from, and among the columns. A base assembly attached to the bottom platform may be adapted to support the two or more adsorbent columns and the rotary valve.

Abstract: PSA process for oxygen production comprising (a) providing an adsorber having a first layer of adsorbent selective for water and a second layer of adsorbent selective for nitrogen, wherein the heat of adsorption of water on the adsorbent in the first layer is equal to or less than about 14 kcal/mole at water loadings less than about 0.05 mmol per gram; (b) passing a feed gas comprising at least oxygen, nitrogen, and water successively through the first and second layers, adsorbing water in the first layer of adsorbent, and adsorbing nitrogen in the second layer of adsorbent, wherein the mass transfer coefficient of water in the first layer is in the range of about 125 to about 400 sec?1 and the superficial contact time of the feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product enriched in oxygen from the adsorber.

Abstract: System for producing an oxygen-rich gas comprising (a) a primary gas mover including a first and a second compressor, wherein the primary gas mover is characterized by a weight Wp; (b) a drive motor adapted to drive the first and second compressors; (c) a rechargeable power supply characterized by a weight, Wb; and (d) a pressure/vacuum swing adsorption unit adapted to separate the pressurized feed air into an oxygen-rich product at a product flow rate Fp and an oxygen-depleted waste gas, wherein the adsorption unit comprises a plurality of adsorber beds containing an adsorbent and characterized by a total adsorbent weight Wa; and wherein the combined weight, Wt, of the adsorbent, the primary gas mover, and the rechargeable power supply is characterized by the expression 0.75 Fp<Wt<2.02 Fp where Fp is in liters per min (at 23° C. and 1 atma pressure), and Wa, Wp, and Wb are in pounds.

Abstract: Containerized gas separation system comprising (a) a container having an interior, an exterior, and an exterior volume defined by the exterior dimensions of the container and (b) a pressure swing adsorption system installed in the interior of the container and adapted to recover a product gas from a feed gas mixture, the pressure swing adsorption system being adapted to deliver the product gas at a product gas flow rate, wherein the ratio of the exterior volume of the container to the product gas flow rate is less than about 2000 ft3/(ton per day).

Abstract: PSA process for oxygen production comprising (a) providing an adsorber having a first layer of adsorbent selective for water and a second layer of adsorbent selective for nitrogen, wherein the heat of adsorption of water on the adsorbent in the first layer is ? about 14 kcal/mole at water loadings? about 0.05 mmol per gram; (b) passing a feed gas comprising at least oxygen, nitrogen, and water successively through the first and second layers, adsorbing water in the first layer of adsorbent, and adsorbing nitrogen in the second layer of adsorbent, wherein the mass transfer coefficient of water in the first layer is in the range of about 125 to about 400 sec?1 and the superficial contact time of the feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product enriched in oxygen from the adsorber.

Abstract: Pressure swing adsorption process for producing oxygen comprising (a) providing at least one adsorber vessel having a first layer of adsorbent adjacent the feed end of the vessel and a second layer of adsorbent adjacent the first layer, wherein the surface area to volume ratio of the first layer is in the range of about 5 to about 11 cm?1; (b) introducing a pressurized feed gas comprising at least oxygen, nitrogen, and water into the feed end, adsorbing at least a portion of the water in the adsorbent in the first layer, and adsorbing at least a portion of the nitrogen in the adsorbent in the second layer, wherein the superficial contact time of the pressurized feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product gas enriched in oxygen from the product end of the adsorber vessel.

Abstract: Oxygen concentrator system having a portable oxygen generator unit adapted to generate a non-humidified oxygen-rich gas and a stationary base unit adapted to generate a humidified oxygen-rich gas, wherein the portable oxygen generator unit and the stationary base are adapted for operation in a coupled mode and an uncoupled mode. The portable oxygen generator unit includes a first flow coupling adapted to receive the humidified oxygen-rich gas when operating in the coupled mode, piping means adapted to combine the non-humidified oxygen-rich gas and the humidified oxygen-rich gas to form a humidified oxygen-rich gas product, and an oxygen-rich gas product delivery port. The stationary base unit is adapted to recharge a rechargeable power supply system in the portable oxygen generator unit when the units are coupled.

Abstract: Pressure swing adsorption system comprising two or more vessels, each having a feed end, a product end, and adsorbent material adapted to adsorb one or more components from a multi-component feed gas mixture; piping adapted to (1) introduce the feed gas mixture into the feed ends, withdraw a product gas from the product ends, and withdraw a waste gas from the feed ends of the vessels, and (2) place the product ends of any pair of vessels in flow communication; a feed pipe adapted to supply the feed gas mixture to the system; a product pipe adapted to withdraw the product gas from the system; and a waste gas pipe adapted to withdraw the waste gas from the system. An indexed rotatable multi-port valve is adapted to place the product end of each vessel in sequential flow communication with the product end of each of the other vessels.

Abstract: System for producing an oxygen-rich gas comprising (a) a primary gas mover including a first and a second compressor, wherein the primary gas mover is characterized by a weight Wp; (b) a drive motor adapted to drive the first and second compressors; (c) a rechargeable power supply characterized by a weight, Wb; and (d) a pressure/vacuum swing adsorption unit adapted to separate the pressurized feed air into an oxygen-rich product at a product flow rate Fp and an oxygen-depleted waste gas, wherein the adsorption unit comprises a plurality of adsorber beds containing an adsorbent and characterized by a total adsorbent weight Wa; and wherein the combined weight, Wt, of the adsorbent, the primary gas mover, and the rechargeable power supply is characterized by the expression 0.75 Fp<Wt<2.02 Fp where Fp is in liters per min (at 23° C. and 1 atma pressure), and Wa, Wp, and Wb are in pounds.

Abstract: Oxygen generation system having a portable oxygen generator unit including a portable air separation device for the generation of an oxygen-rich gas, a primary gas pump including means to supply air to the portable air separation device, a primary motor to drive the gas pump, a rechargeable power supply to drive the motor, connector means adapted to deliver power to the rechargeable power supply, flow coupling means to transfer the oxygen-rich gas from the portable oxygen generator unit, and a first oxygen-rich gas product discharge port. The system also includes a stationary base unit adapted to couple with the portable oxygen generator unit, wherein the stationary base unit has a stationary power supply system including connector means adapted to recharge the rechargeable power supply in the portable oxygen generator unit, flow coupling means to receive the oxygen-rich gas from the portable oxygen generator unit, and an optional second oxygen-rich gas product discharge port.