Abstract: A pre-fractured glass laminate that includes: a glass substrate comprising a thickness, a pair of opposed primary surfaces, a compressive stress region, a central tension (CT) region and a plurality of cracks; a second phase comprising a polymer or a cured resin within the plurality of cracks; a backing layer; and an interlayer disposed between one of the primary surfaces of the substrate and the backing layer. The compressive stress region extends from each of the primary surfaces to a first selected depth in the substrate. Further, the plurality of cracks is located in the CT region.

Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than about 0.7·t up to t, comprise a tangent with a slope having an absolute value greater than about 0.1 MPa/micrometer, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t) and a maximum central tension in the range from about 80 MPa to about 100 MPa. In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a value at a point between the first surface and the second surface and increases from the value to the second surface. The concentration of the metal oxide may be about 0.

Abstract: A glass-ceramic includes a silicate-containing glass and crystals within the silicate-containing glass. The crystals include non-stoichiometric tungsten and/or molybdenum sub-oxides, and the crystals are intercalated with dopant cations.

Abstract: Chemically durable glass compositions are disclosed. In embodiments, the glass composition includes: 48 mol. % to 61 mol. % SiO2; 0 mol. % to 1 mol. % Al2O3; 7 mol. % to 20 mol. % B2O3; 9 mol. % to 16 mol. % R2O, where R2O is a sum of alkali oxides present in the glass composition; 9 mol. % to 15 mol. % Na2O; and 8 mol. % to 21 mol. % ZnO. The glass composition may be substantially free of Li2O. RO (mol. %)<0.5×ZnO (mol. %), where RO is a sum of the alkaline earth oxides in the glass composition. An average coefficient of thermal expansion of the glass composition is 75×10?7/° C. to 88×10?7/° C. over a temperature range from about 20° C. to about 300° C. The glass composition comprises a softening point less than or equal to 660° C. The glass composition comprises a hydrolytic resistance of class HGA1 or class HGA2 according to ISO 720:1985.

Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.

Abstract: A glass-ceramic, includes a silicate-containing glass comprising a first portion and a second portion. A plurality of crystalline precipitates comprising at least one of W and Mo. The crystalline precipitates are distributed within at least one of the first and second portions of the silicate-containing glass. The glass-ceramic comprises a difference in absorbance between the first and second portions of 0.04 optical density (OD)/mm or greater over a wavelength range of from 400 nm to 1500 nm.

Abstract: Ion exchangeable glasses containing SiO2, Al2O3, Na2O, MgO, B2O3, and P2O5 are provided. The compressive stresses of these ion exchanged glasses are greater than 900 megapascals (MPa) at a depth of 45 or 50 microns (?m) with some glasses exhibiting a compressive stress of at least 1 gigaPascals (GPa). The ion exchange rates of these glasses are much faster than those of other alkali aluminosilicate glasses and the ion exchanged glass is resistant damage to impact damage. A method of ion exchanging the glass is also provided.

Abstract: A laminate glass-ceramic article is provided that includes: a core glass layer having a first coefficient of thermal expansion (CTE); and a plurality of clad glass-ceramic layers, each having a CTE that is lower than or equal to the first CTE of the core glass layer. A first of the clad glass-ceramic layers is laminated to a first surface of core glass layer and a second of the clad glass-ceramic layers is laminated to a second surface of the core glass layer. Further, a total thickness of the plurality of clad glass-ceramic layers is from about 0.05 mm to about 0.5 mm. In addition, each of the glass-ceramic layers includes: an alumino-boro-silicate glass, 0 mol %?MoO3?15 mol %, and 0 mol %?WO3?15 mol %, the WO3 (mol %) plus the MoO3 (mol %) is from 0.7 mol % to 19 mol %.

Abstract: A glass having from greater than or equal to about 0.1 mol. % to less than or equal to about 20 mol. % Ho2O3, and one or more chromophores selected from V, Cr, Mn, Fe, Co, Ni, Se, Pr, Nd, Er, Yb, and combinations thereof. The amount of Ho2O3 (mol. %) is greater than or equal to 0.7(CeO2 (mol. %)+Pr2O3 (mol. %)+Er2O3 (mol. %)). The glass can include one or more fluorescent ions selected from Cu, Sn, Ce, Eu, Tb, Tm, and combinations thereof in addition to, or in place of the chromophores. The glass can also include multiple fluorescent ions.

Abstract: A glass-ceramic that includes: SiO2 from 40 mol % to 80 mol %; Al2O3 from 3 mol % to 20 mol %; B2O3 from 3 mol % to 50 mol %; WO3 plus MoO3 from 1 mol % to 18 mol %; Fe2O3 plus MnO2 from 0.1 mol % to 2 mol %; and R2O from 0 mol % to 15 mol %. The R2O is one or more of Li2O, Na2O, K2O, Rb2O and Cs2O. Further, R2O—Al2O3 ranges from ?12 mol % to +4 mol %.

Abstract: An example glass composition comprises rare earth content (e.g., rare earth oxides, elements, and/or ions) of from about 0.5 mol % to about 20 mol %. The glass composition may have a liquidus temperature that is within a specified range, a softening point that is within a specified range, a working point that is within a specified range, and/or a coefficient of thermal expansion (CTE) that is within a specified range.

Abstract: A glass-ceramic includes a silicate-containing glass and crystals within the silicate-containing glass. The crystals include non-stoichiometric tungsten and/or molybdenum sub-oxides, and the crystals are intercalated with dopant cations.

Abstract: A glass having from greater than or equal to about 0.1 mol. % to less than or equal to about 20 mol. % Ho2O3, and one or more chromophores selected from V, Cr, Mn, Fe, Co, Ni, Se, Pr, Nd, Er, Yb, and combinations thereof. The amount of Ho2O3 (mol. %) is greater than or equal to 0.7 (CeO2 (mol. %)+Pr2O3 (mol. %)+Er2O3 (mol. %)). The glass can include one or more fluorescent ions selected from Cu, Sn, Ce, Eu, Tb, Tm, and combinations thereof in addition to, or in place of the chromophores. The glass can also include multiple fluorescent ions.

Abstract: Glass compositions having from 50 to 80 mol % SiO2, less than or equal to 25 mol % Al2O3, from 6.5 to 10.0 mol % Li2O and, optionally, other components, such as alkali metal oxides, alkaline earth metal oxides, zinc oxide, phosphorus oxides, rare earth metal oxides, boron oxide, and small amounts of other species, such as titania, zirconia, and tin oxide. The glass compositions are characterized by zero or positive values of the ratios, in terms of mol %: Al2O3??R2O?0, or Al2O3??R2O??RO?0, or Al2O3??R2O??RO—P2O5?0, where R2O means alkali metal oxides and RO means divalent metal oxides. The glass compositions may have a liquidus viscosity greater than or equal to 1000 Poises to less than or equal to 300,000 Poises.

Abstract: Optically transparent glass ceramic materials comprising a glass phase containing and a crystalline tungsten bronze phase comprising nanoparticles and having the formula MxWO3, where M includes at least one H, Li, Na, K, Rb, Cs, Ca, Sr, Ba, Zn, Cu, Ag, Sn, Cd, In, Tl, Pb, Bi, Th, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, and U, and where 0<x<1. Aluminosilicate and zinc-bismuth-borate glasses comprising at least one of Sm2O3, Pr2O3, and Er2O3 are also provided.

Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than about 0.7·t up to t, comprise a tangent with a slope having an absolute value greater than about 0.1 MPa/micrometer, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t) and a maximum central tension in the range from about 80 MPa to about 100 MPa. In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a value at a point between the first surface and the second surface and increases from the value to the second surface. The concentration of the metal oxide may be about 0.

Abstract: A glass that includes Pr2O3 and Nd2O3 such that the sum of Pr2O3 and Nd2O3 is greater than 0.2 mole % and the ratio of Nd2O3 to Pr2O3 is greater than 0.5 and less than 3. Further, the sum of any chromophores in the glass from the group V2O5, Cr2O3, MnO, Mn2O3, Fe2O3, CoO, Co3O4, CuO, NiO, Nb2O5, CeO2, Ho2O3 and Er2O3 is less than 0.1 mole %. The glass can be characterized by a substantially pink color upon exposure to an incandescent light source and a substantially green color upon exposure to a fluorescent light source. The glass can optionally include one or more fluorescent ions selected from oxides of Cu, Sn, Mn, Ag, Sb, Ce, Sm, Eu, Tb, Dy, Tm, and combinations thereof, such that a total concentration of fluorescent ions is from greater than or equal to about 0.01 mole % to less than or equal to about 5.0 mole %.

Abstract: A group of glass compositions in the Li2O—Al2O3—SiO2—B2O3 family that can be chemically strengthened in single or multiple ion exchange baths containing at least one of NaNO3 and KNO3 for a short time (2-4 hours) to develop a deep depth of layer (DOL). In some instances, the DOL is at least 70 ?m; in others, at least about 100 ?m. The ion exchanged glasses have a high damage resistance (indentation fracture toughness ranging form greater than 10 kgf to greater than 50 kgf) that is better than or at least comparable to that of sodium aluminosilicate glasses.

Abstract: A glass-ceramic, includes a silicate-containing glass comprising a first portion and a second portion. A plurality of crystalline precipitates comprising at least one of W and Mo. The crystalline precipitates are distributed within at least one of the first and second portions of the silicate-containing glass. The glass-ceramic comprises a difference in absorbance between the first and second portions of 0.04 optical density (OD)/mm or greater over a wavelength range of from 400 nm to 1500 nm.

Abstract: Glass articles and methods for modifying a composition of a surface portion of the glass article are disclosed. The method includes heating the surface portion of the glass article with a laser beam to a temperature within a range of about 1100?C to about 2200?C such that the heating evaporates one or more metalloids and/or one or more alkali metals present at the surface portion, and modifies the composition of the surface portion such that the surface portion has a lower alkali metals concentration and/or a lower metalloids concentration as compared to a portion of the glass article that is not heated by the laser beam.