Abstract: A lithium-ion battery including an electrodeposited anode material having a micron-scale, three-dimensional porous foam structure separated from interpenetrating cathode material that fills the void space of the porous foam structure by a thin solid-state electrolyte which has been reductively polymerized onto the anode material in a uniform and pinhole free manner, which will significantly reduce the distance which the Li-ions are required to traverse upon the charge/discharge of the battery cell over other types of Li-ion cell designs, and a procedure for fabricating the battery are described. The interpenetrating three-dimensional structure of the cell will also provide larger energy densities than conventional solid-state Li-ion cells based on thin-film technologies. The electrodeposited anode may include an intermetallic composition effective for reversibly intercalating Li-ions.

Abstract: Methods are described for forming insulating hybrid organic-inorganic solid electrolytes on conducting electrodes that are active materials in Li-ion batteries by electrochemical deposition, and for forming second conducting electrodes on the solid electrolytes using aqueous slurries, whereby Li-ion battery cells having solid electrolytes are generated. X-ray photoelectron spectroscopy is utilized for determining that the solid electrolytes are defect and pinhole free.

Abstract: Methods are described for forming insulating hybrid organic-inorganic solid electrolytes on conducting electrodes that are active materials in Li-ion batteries by electrochemical deposition, and for forming second conducting electrodes on the solid electrolytes using aqueous slurries, whereby Li-ion battery cells having solid electrolytes are generated. X-ray photoelectron spectroscopy is utilized for determining that the solid electrolytes are defect and pinhole free.

Abstract: A lithium-ion battery including an electrodeposited anode material having a micron-scale, three-dimensional porous foam structure separated from interpenetrating cathode material that fills the void space of the porous foam structure by a thin solid-state electrolyte which has been reductively polymerized onto the anode material in a uniform and pinhole free manner, which will significantly reduce the distance which the Li-ions are required to traverse upon the charge/discharge of the battery cell over other types of Li-ion cell designs, and a procedure for fabricating the battery are described. The interpenetrating three-dimensional structure of the cell will also provide larger energy densities than conventional solid-state Li-ion cells based on thin-film technologies. The electrodeposited anode may include an intermetallic composition effective for reversibly intercalating Li-ions.