Abstract: Gel polymer electrolyte compositions including a cross-linked three-dimensional polymer network and an electrolyte composition comprising an electrolyte and water are disclosed. The gel polymer electrolyte compositions can be included in an aqueous electrochemical cell, in which a gel polymer electrolyte can be positioned between an anode and a cathode. Methods of forming a gel polymer electrolyte in the form of a film, and methods of forming an aqueous electrochemical cell including a gel polymer electrolyte, are also disclosed.

Abstract: Aspects of the disclosure describe an energy storage device comprising a cathode, an anode, a separator, and an electrolyte. The anode comprises a support structure and an electrode layer disposed on the support structure. The electrode layer comprises 40-80% silicon, 15-40% graphite, 5-15% carbon black, 0-15% carboxymethyl cellulose (CMC), 0-5% styrene-butadiene rubber (SBR), and 5-20% poly(acrylic acid). The separator is disposed between the anode and cathode to prevent internal shorting of the energy storage device. The electrolyte allows movement of ions between the anode and cathode.

Abstract: Disclosed herein is a battery anode compound including a metal oxide and a metal. Also disclosed herein is a method of providing a battery anode compound comprising synthesizing AlNb11O29 and combining AlNb11O29 and a metal. A Li-ion battery anode compound is also disclosed that includes a slurry comprising up to 70% AlNb11O29, up to 70% Li4Ti5O12, and up to 70% of a metal, wherein the metal is any one of Sb or Sn.

Abstract: A gel polymer electrolyte (GPE) composition and a method of forming the same are provided. The GPE includes a polymer network and an electrolyte composition comprising a deep eutectic solvent (DES) having a eutectic point of less than or equal to 25° C. An electrochemical cell including a GPE and a method of forming the same are also provided.

Abstract: Flexible lithium-ion batteries include patterned electrode assemblies configured to partition bending stresses when the lithium-ion battery is flexed by localizing high bending stresses. The patterned electrode assemblies can include a patterned current collector and active material or patterned active material formed on a current collector that is not patterned.

Abstract: Disclosed herein are metal-organic frameworks and methods of making and use thereof.

Abstract: Processes for preparing a niobate material are provided, in which the processes include the following steps: (i) providing a niobium-containing source; (ii) providing a transitional metal source (TMS), a post-transitional metal source (PTMS), or both; (iii) dissolving (a) the niobium-containing source, and (b) the TMS, the PTMS, or both in an aqueous medium to form an intermediate solution; (iv) forming an intermediate paste by admixing an inert support material with the intermediate solution; (v) optionally coating the intermediate paste on a support substrate; and (vi) removing the inert support material by subjecting the intermediate paste to a calcination process and providing a transition-metal-niobate (TMN) and/or a post-transition-metal-niobate (PTMN). Anodes including a TMN and/or PTMN are also provided.

Abstract: Processes for preparing a niobate material are provided, in which the processes include the following steps: (i) providing a niobium-containing source; (ii) providing a transitional metal source (TMS), a post-transitional metal source (PTMS), or both; (iii) dissolving (a) the niobium-containing source, and (b) the TMS, the PTMS, or both in an aqueous medium to form an intermediate solution; (iv) forming an intermediate paste by admixing an inert support material with the intermediate solution; (v) optionally coating the intermediate paste on a support substrate; and (vi) removing the inert support material by subjecting the intermediate paste to a calcination process and providing a transition-metal-niobate (TMN) and/or a post-transition-metal-niobate (PTMN). Anodes including a TMN and/or PTMN are also provided.

Abstract: Processes for preparing a niobate material include the following steps: (i) providing a niobium-containing source; (ii) providing a transitional metal source (TMS), a post-transitional metal source (PTMS), or both; (iii) dissolving (a) the niobium-containing source, and (b) the TMS, the PTMS, or both in an aqueous medium to form an intermediate solution; (iv) forming an intermediate paste by admixing an inert support material with the intermediate solution; (v) optionally coating the intermediate paste on a support substrate; and (vi) removing the inert support material by subjecting the intermediate paste to a calcination process and providing a transition-metal-niobate (TMN) and/or a post-transition-metal-niobate (PTMN). Anodes including a TMN and/or PTMN are also provided.

Abstract: A water harvesting device includes at least a first adsorption column including a first inlet, a first outlet, and a first interior region. A sorbent material is located within the first interior region of the first adsorption column. The sorbent material includes a metal organic framework (MOF) material including a plurality of metal ions or clusters of metal ions coordinated to one or more organic linkers, a plurality of nanofabrics comprising a hydrogel material, or a combination thereof.

Abstract: Sorbent materials comprising a nanofiber composite including a polymeric material defining a continuous phase and at least one metal organic framework (MOF) material defining a discontinuous phase are provided. The at least one MOF material is dispersed throughout the continuous phase of the polymeric material. Fibrous mats comprising the sorbent materials are also provided. Water harvesting devices utilizing the sorbent materials are also provided.

Abstract: A method of manufacturing a three-dimensional electrochemical lithium battery includes forming a first electrode on an underlying layer comprising aerosolizing a first ink formulation comprising a slurry including nanoparticles or microparticles of a first active material and a binder, and depositing the slurry onto the underlying layer to form a first electrode layer. A permeable separator layer is formed on the first electrode by aerosolizing a polymer precursor solution, exposing the aerosolized polymer precursor solution to a first activating radiation source to form partially cured polymer spheres in the aerosolized stream, focusing and directing the aerosolized stream onto a substrate to form the permeable separator layer of the partially cured polymer spheres, and exposing the partially cured polymer spheres on the substrate to a second activating radiation source to fully cure the partially cured polymer spheres.

Abstract: Processes for preparing a niobate material include the following steps: (i) providing a niobium-containing source; (ii) providing a transitional metal source (TMS), a post-transitional metal source (PTMS), or both; (iii) dissolving (a) the niobium-containing source, and (b) the TMS, the PTMS, or both in an aqueous medium to form an intermediate solution; (iv) forming an intermediate paste by admixing an inert support material with the intermediate solution; (v) optionally coating the intermediate paste on a support substrate; and (vi) removing the inert support material by subjecting the intermediate paste to a calcination process and providing a transition-metal-niobate (TMN) and/or a post-transition-metal-niobate (PTMN). Anodes including a TMN and/or PTMN are also provided.

Abstract: A water harvesting device includes at least a first adsorption column including a first inlet, a first outlet, and a first interior region. A sorbent material is located within the first interior region of the first adsorption column. The sorbent material includes a metal organic framework (MOF) material including a plurality of metal ions or clusters of metal ions coordinated to one or more organic linkers, a plurality of nanofabrics comprising a hydrogel material, or a combination thereof.

Abstract: Gel polymer electrolyte compositions including a cross-linked three-dimensional polymer network and an electrolyte composition comprising an electrolyte and water are disclosed. The gel polymer electrolyte compositions can be included in an aqueous electrochemical cell, in which a gel polymer electrolyte can be positioned between an anode and a cathode. Methods of forming a gel polymer electrolyte in the form of a film, and methods of forming an aqueous electrochemical cell including a gel polymer electrolyte, are also disclosed.

Abstract: A gel polymer electrolyte (GPE) composition and a method of forming the same are provided. The GPE includes a polymer network and an electrolyte composition comprising a deep eutectic solvent (DES) having a eutectic point of less than or equal to 25° C. An electrochemical cell including a GPE and a method of forming the same are also provided.

Abstract: Disclosed herein are metal-organic frameworks and methods of making and use thereof.

Abstract: A pipeline debris shearing device includes a forwardly positioned, self sharpening, wear compensating, diameter conforming elastomeric member that forms a peeling edge having a negative rake angle to peel away debris from the internal wall of a pipeline. The peeling edge is formed at the point of meeting between a concave-shaped, curved forward face surface and a substantially straight outer peripheral surface. Radial slots may be provided to lessen the force being exerted on the peeling edge and provide for bypass flow to carry away debris removed by the peeling edge. Spaced-apart narrow stripper teeth may be added to help in removing harder deposits of debris. The peeling edge may be arranged substantially perpendicular the central longitudinal axis of the pipeline pig or arranged oblique to it. Further, the peeling edge may spiral about at least a portion of the pipeline pig.

Abstract: A pipeline debris shearing device includes a forwardly positioned, self sharpening, wear compensating, diameter conforming elastomeric member that forms a peeling edge having a negative rake angle to peel away debris from the internal wall of a pipeline. The peeling edge is formed at the point of meeting between a concave-shaped, curved forward face surface and a substantially straight outer peripheral surface. Radial slots may be provided to lessen the force being exerted on the peeling edge and provide for bypass flow to carry away debris removed by the peeling edge. Spaced-apart narrow stripper teeth may be added to help in removing harder deposits of debris. The peeling edge may be arranged substantially perpendicular the central longitudinal axis of the pipeline pig or arranged oblique to it. Further, the peeling edge may spiral about at least a portion of the pipeline pig.

Abstract: A pipeline debris shearing device includes a forwardly positioned, self sharpening, wear compensating, diameter conforming elastomeric member that forms a peeling edge having a negative rake angle to peel away debris from the internal wall of a pipeline. The peeling edge is formed at the point of meeting between a concave-shaped, curved forward face surface and a substantially straight outer peripheral surface. Radial slots may be provided to lessen the force being exerted on the peeling edge and provide for bypass flow to carry away debris removed by the peeling edge. Spaced-apart narrow stripper teeth may be added to help in removing harder deposits of debris. The peeling edge may be arranged substantially perpendicular the central longitudinal axis of the pipeline pig or arranged oblique to it. Further, the peeling edge may spiral about at least a portion of the pipeline pig.