Patents by Inventor Matthias Horteis

Matthias Horteis has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10636540
    Abstract: In general, the present invention relates to an electro-conductive paste comprising an oxide additive and solar cells obtainable therefrom. More specifically, the present invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The present invention relates to a conductive paste composition comprising the following paste constituents: a. at least about 70 wt. % Ag particles, based on the paste; b. a vehicle; c. a glass; d. an oxide additive comprising MI, MII, and O; wherein MI and MII are different; wherein MI is selected from the group consisting of: V, Nb, Ta, Cr, Mo, W, Ge, As, Sb, Se, Te, Pb and Bi; wherein MII is selected from the group consisting of: V, Nb, Ta, Cr, Mo, W, Ge, As, Sb, Se, Te, Pb, Bi, Mn, Ce, Zn, Li, Na, K, Rb, Cs, Mg, Ca, Sr and Ba; wherein the oxide additive is crystalline according to electron back scattering diffraction (EBSD) measurement.
    Type: Grant
    Filed: March 23, 2016
    Date of Patent: April 28, 2020
    Assignee: HERAEUS DEUTSCHLAND GMBH & CO. KG
    Inventors: Markus König, Gerd Schulz, Daniel W. Holzmann, Matthias Hörteis
  • Patent number: 10403769
    Abstract: The invention relates to an electro-conductive paste comprising Ag nano-particles and spherical Ag micro-particles in the preparation of electrodes, particularly in electrical devices, particularly in temperature sensitive electrical devices or solar cells, particularly in HIT (Heterojunction with Intrinsic Thin-layer) solar cells. In particular, the invention relates to a paste, a process for preparing a paste, a precursor, a process for preparing an electrical device and a module comprising electrical devices. The invention relates to a paste comprising the following paste constituents: a. Ag particles, b. a polymer system; wherein the Ag particles have a multi-modal distribution of particle diameter with at least a first maximum in the range from about 1 nm to about less than 1 ?m and at least a further maximum in the range from about 1 ?m to about less than 1 mm; wherein the difference between the first and the further maximum is at least about 0.3 ?m; wherein at least 50 wt.
    Type: Grant
    Filed: August 30, 2013
    Date of Patent: September 3, 2019
    Assignee: HERAEUS DEUTSCHLAND GMBH & CO. KG
    Inventors: Christian Muschelknautz, Matthias Horteis, Isao Tanaka, Klaus Kunze, Roupen Keusseyan, Toshinori Wada, Aziz S. Shaikh
  • Patent number: 10158032
    Abstract: In general, the present invention relates to electro-conductive pastes with halogen containing compounds as additives and solar cells with high Ohmic sheet resistance, preferably photovoltaic solar cells. More specifically, the present invention relates to solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The present invention relates to a solar cell precursor at least comprising as precursor parts: i) a wafer with sheet resistance of at least 80 Ohm/sq.; ii) an electro-conductive paste at least comprising: a) metallic particles; b) a glass frit; c) an organic vehicle; and d) a halogen containing compound applied to the wafer.
    Type: Grant
    Filed: October 10, 2013
    Date of Patent: December 18, 2018
    Assignee: HERAEUS DEUTSCHLAND GMBH & CO. KG
    Inventors: Gerd Schulz, Daniel Winfried Holzmann, Sebastian Unkelbach, Matthias Hörteis
  • Patent number: 10141459
    Abstract: In general, the invention relates to electro-conductive pastes containing binary glass frits and photovoltaic solar cells, preferably n-type photovoltaic solar cells. More specifically, the invention relates to solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The invention relates to a solar cell precursor comprising as precursor parts i. a wafer with a back face and a front face, wherein the front face comprises a p-doped layer ii. a first paste comprising Ag particles; Al particles in a range from about 0.01 to about 5 wt. %, based on the total weight of the paste; a vehicle; a glass frit in a range from about 0.1 to about 5 wt. %, based on the total weight of the paste, wherein the glass frit comprises a first glass frit with a glass transition temperature Tgl and a further glass frit with a glass transition temperature Tgf, wherein Tgf differs from Tgl by at least about 10° C.; an additive; superimposed on a first area on said p-doped layer.
    Type: Grant
    Filed: December 23, 2013
    Date of Patent: November 27, 2018
    Assignee: HERAEUS DEUTSCHLAND GMBH & CO. KG
    Inventors: Markus König, Matthias Hörteis, Weiming Zhang
  • Patent number: 10056508
    Abstract: In general, the present invention relates to an electro-conductive paste comprising a metal additive and solar cells obtainable therefrom by application of the paste to a p-type doped face. More specifically, the present invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The present invention relates to a precursor comprising the following paste constituents: a. A Si wafer with at least one p-type doped face and at least one n-type doped face; b. A conductive paste comprising the following paste constituents: i. at least about 70 wt. % Ag particles, based on the paste, ii. a vehicle, iii. a glass, iv. a metal compound comprising a metal M and which is one or more selected from the group consisting of: an organic metal oxide, a metal oxide, an organic metal compound and a silver metal oxide; wherein the conductive paste b. is superimposed on a p-type doped face.
    Type: Grant
    Filed: March 24, 2016
    Date of Patent: August 21, 2018
    Assignee: HERAEUS DEUTSCHLAND GMBH & CO. KG
    Inventors: Markus König, Gerd Schulz, Daniel Winfried Holzmann, Matthias Hörteis, Nicole Georg, Christin Behl
  • Patent number: 10014418
    Abstract: The present invention relates to an inorganic reaction system used in the manufacture of electroconductive pastes. The inorganic reaction system comprises a lead containing matrix forming composition and a tellurium oxide additive. Preferably the lead containing matrix forming composition is between 5-95 wt. % of the inorganic reaction system, and the tellurium oxide additive is between 5-95 wt. % of the inorganic reaction system. The lead containing matrix forming composition may be a glass frit, and may comprise lead oxide. Another aspect of the present invention relates to an electroconductive paste composition that comprises metallic particles, an inorganic reaction system as previously disclosed, and an organic vehicle. Another aspect of the present invention relates to an organic vehicle that comprises one or more of a binder, a surfactant, a solvent, and a thixatropic agent.
    Type: Grant
    Filed: September 7, 2016
    Date of Patent: July 3, 2018
    Assignee: Heraeus Precious Metals North America Conshohocken LLC
    Inventors: Lei Wang, Matthias Hörteis, Weiming Zhang
  • Patent number: 10002977
    Abstract: The invention relates to an electro-conductive paste comprising coarse SiO2 particles in the preparation of electrodes in solar cells, particularly in the preparation of electrodes in MWT solar cells, particularly in the preparation of the metal wrap through, or plug, electrode in such solar cells. In particular, the invention relates to a solar cell precursor, a process for preparing a solar cells, a solar cell and a module comprising solar cells. The invention relates to a solar cell precursor at least comprising as precursor parts: i) a wafer (101) with at least one hole (315) with a Si surface (113); ii) an electro-conductive paste (105) at least comprising as paste constituents: a) metallic particles; b) an inorganic reaction system; c) an organic vehicle; and d) inorganic oxide particles having no glass transition temperature below about 750° C. or a glass transition temperature which is at least about 50° C.
    Type: Grant
    Filed: December 23, 2013
    Date of Patent: June 19, 2018
    Assignee: HERAEUS DEUTSCHLAND GMBH & CO. KG
    Inventors: Lei Wang, Crystal J. Han, Matthias Hörteis
  • Publication number: 20180076343
    Abstract: In general, the present invention relates to electro-conductive pastes comprising organic metal oxide and solar cells obtainable therefrom, preferably photovoltaic solar cells. More specifically, the present invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The present invention relates to a conductive paste composition comprising the following paste constituents: a. at least 70 wt. % Ag particles, based on the paste; b. a vehicle; c. an inorganic reaction system; d. an organic metal oxide comprising a metal M; wherein the metal M is one or more selected from the group consisting of the following: Se, Ge, Pb, As, Sb, Bi, Te, Nb, Ta, Cr, Mo, W.
    Type: Application
    Filed: March 24, 2016
    Publication date: March 15, 2018
    Inventors: Gerd Schulz, Daniel W. Holzmann, Markus König, Matthias Hörteis, Michael Neidert, Sebastian Unkelbach, Li Yan
  • Publication number: 20180053577
    Abstract: In general, the present invention relates to an electro-conductive paste comprising an oxide additive and solar cells obtainable therefrom. More specifically, the present invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The present invention relates to a conductive paste composition comprising the following paste constituents: a. at least about 70 wt. % Ag particles, based on the paste; b. a vehicle; c. a glass; d. an oxide additive comprising MI, MII, and O; wherein MI and MII are different; wherein MI is selected from the group consisting of: V, Nb, Ta, Cr, Mo, W, Ge, As, Sb, Se, Te, Pb and Bi; wherein MII is selected from the group consisting of: V, Nb, Ta, Cr, Mo, W, Ge, As, Sb, Se, Te, Pb, Bi, Mn, Ce, Zn, Li, Na, K, Rb, Cs, Mg, Ca, Sr and Ba; wherein the oxide additive is crystalline according to electron back scattering diffraction (EBSD) measurement.
    Type: Application
    Filed: March 23, 2016
    Publication date: February 22, 2018
    Inventors: Markus König, Gerd Schulz, Daniel W. Holzmann, Matthias Hörteis
  • Publication number: 20180040748
    Abstract: The present invention relates to a solar cell (1) comprising a substrate (2) of p-type silicon or n-type silicon, wherein the substrate (2) comprises a front side (2a) the surface of which is at least partially covered with at least one passivation layer (3) and a back side (2b), wherein the back side (2b) of the substrate (2) is at least partially covered with a conductive polymer layer (4) and wherein at least one of the following conditions a) and b) is fulfilled: a) the conductive polymer layer (4) is at least partially in direct contact with the surface of the p-type or n-type silicon; b) the conductive polymer layer (4) comprises a cationic conductive polymer and a polymeric anion in a weight ratio cationic conductive polymer:polymeric anion of greater than 0.4. The present invention also relates to a process for the preparation of a solar cell, to a solar cell obtainable by this process and to a solar module.
    Type: Application
    Filed: March 9, 2016
    Publication date: February 8, 2018
    Inventors: Jan Schmidt, Dimitri Zielke, Andreas Elschner, Wilfried Lövenich, Matthias Hörteis, Arnulf Scheel
  • Publication number: 20180033517
    Abstract: In general, the present invention relates to electro-conductive pastes comprising metals compounds and solar cells obtainable therefrom, preferably photovoltaic solar cells. More specifically, the present invention relates to solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The present invention relates to a precursor comprising the following precursor constituents: a. An Si wafer having a surface with a dopant concentration in the range from about 2*1018 to about 2*1021 cm?3; b. An electro-conductive paste superimposed over the surface, wherein the electroconductive paste comprises the following paste constituents: i. Silver particles at least about 70 wt. % based on the total weight of the paste; ii. Inorganic reaction system; iii. A metal compound comprising a metal M; iv. Organic vehicle.
    Type: Application
    Filed: March 23, 2016
    Publication date: February 1, 2018
    Inventors: Gerd Schulz, Daniel Winfried Holzman, Markus König, Matthias Hörteis, Paul Gundel
  • Publication number: 20170301803
    Abstract: The present invention relates to an inorganic reaction system used in the manufacture of electroconductive pastes. The inorganic reaction system comprises a lead containing matrix forming composition and a tellurium oxide additive. Preferably the lead containing matrix forming composition is between 5-95 wt. % of the inorganic reaction system, and the tellurium oxide additive is between 5-95 wt. % of the inorganic reaction system. The lead containing matrix forming composition may be a glass frit, and may comprise lead oxide. Another aspect of the present invention relates to an electroconductive paste composition that comprises metallic particles, an inorganic reaction system as previously disclosed, and an organic vehicle. Another aspect of the present invention relates to an organic vehicle that comprises one or more of a binder, a surfactant, a solvent, and a thixatropic agent.
    Type: Application
    Filed: September 7, 2016
    Publication date: October 19, 2017
    Inventors: LEI WANG, Matthias HÖRTEIS, Weiming ZHANG
  • Publication number: 20170291846
    Abstract: In general, the invention relates to a paste comprising: i) silver particles; ii) a particulate lead-silicate glass comprising iia) at least one oxide of silicon; iib) at least one oxide of lead; iic) at least one chloride; iid) optionally at least one further oxide being different from components iia) and iib); iii) an organic vehicle. The invention also relates to a solar cell precursor, to a process for the preparation of a solar cell, to a solar cell obtainable by this process, to a module comprising such a solar cell and to the use of a particulate lead-silicate glass as a component in a silver paste that can be used for the formation of an electrode.
    Type: Application
    Filed: April 7, 2016
    Publication date: October 12, 2017
    Inventors: Gerd SCHULZ, Ryan MAYBERRY, Daniel Winfried HOLZMANN, Christian JUNG, Matthias HORTEIS, Gregory BERUBE
  • Publication number: 20160380129
    Abstract: The present invention relates to an inorganic reaction system used in the manufacture of electroconductive pastes. The inorganic reaction system comprises a lead containing matrix forming composition and a tellurium oxide additive. Preferably the lead containing matrix forming composition is between 5-95 wt. % of the inorganic reaction system, and the tellurium oxide additive is between 5-95 wt. % of the inorganic reaction system. The lead containing matrix forming composition may be a glass frit, and may comprise lead oxide. Another aspect of the present invention relates to an electroconductive paste composition that comprises metallic particles, an inorganic reaction system as previously disclosed, and an organic vehicle. Another aspect of the present invention relates to an organic vehicle that comprises one or more of a binder, a surfactant, a solvent, and a thixatropic agent.
    Type: Application
    Filed: September 7, 2016
    Publication date: December 29, 2016
    Inventors: LEI WANG, Matthias HÖRTEIS, Weiming ZHANG
  • Publication number: 20160284900
    Abstract: In general, the present invention relates to an electro-conductive paste comprising a metal additive and solar cells obtainable therefrom by application of the paste to a p-type doped face. More specifically, the present invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The present invention relates to a precursor comprising the following paste constituents: a. A Si wafer with at least one p-type doped face and at least one n-type doped face; b. A conductive paste comprising the following paste constituents: i. at least about 70 wt. % Ag particles, based on the paste, ii. a vehicle, iii. a glass, iv. a metal compound comprising a metal M and which is one or more selected from the group consisting of: an organic metal oxide, a metal oxide, an organic metal compound and a silver metal oxide; wherein the conductive paste b. is superimposed on a p-type doped face.
    Type: Application
    Filed: March 24, 2016
    Publication date: September 29, 2016
    Inventors: Markus KÖNIG, Gerd SCHULZ, Daniel ZINDEL, Matthias HÖRTEIS, Nicole GEORG, Christin BEHL
  • Publication number: 20160190358
    Abstract: The invention relates to an electro-conductive paste comprising Ag particles with a multimodal diameter distribution in the preparation of electrodes in solar cells, particularly in the preparation of electrodes in MWT solar cells, particularly in the preparation of the metal wrap through, or plug, electrode in such solar cells. In particular, the invention relates to a solar cell precursor, a process for preparing a solar cell, a solar cell and a module comprising solar cells. The invention relates to a solar cell precursor at least comprising as precursor parts: i) a wafer with at least one hole with a Si surface; ii) an electro-conductive paste at least comprising as paste constituents: a) metallic particles; b) an inorganic reaction system; c) an organic vehicle; and d) an additive; comprised by the hole, wherein the metallic particles have a multimodal distribution of particle diameter.
    Type: Application
    Filed: July 9, 2014
    Publication date: June 30, 2016
    Inventors: Michael NEIDERT, Jing HAN, Matthias HÖRTEIS
  • Publication number: 20160049531
    Abstract: In general, the invention relates to electro-conductive pastes comprising particles with comprise Al and Ag and their use in the preparation of photovoltaic solar cells, preferably n-type photovoltaic solar cells. More specifically, the invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The invention relates to a paste comprising as paste constituents: a. At least 80 wt. % silver powder, based on the total weight of the paste; b. An inorganic reaction system; c. An organic vehicle; d. Additive particles comprising Al and Ag as particle constituents, wherein Al and Ag are present in the additive particles as elements or in one or more single phase mixtures of elements comprising one or both of Al and Ag, or a combination of one or both of Al and Ag as elements with one or more mixtures of elements, a combination of one or more elements with one or more mixtures of elements.
    Type: Application
    Filed: March 26, 2014
    Publication date: February 18, 2016
    Inventors: Markus KÖNIG, Alexander RUDL, Matthias HÖRTEIS
  • Publication number: 20160049530
    Abstract: In general, the invention relates to electro-conductive pastes comprising particles with comprise Al, Si and Mg and their use in the preparation of photovoltaic solar cells, preferably n-type photovoltaic solar cells. More specifically, the invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The invention relates to a paste comprising as paste constituents: a. At least 80 wt. % silver powder, based on the total weight of the paste; b. An inorganic reaction system; c. An organic vehicle; d. Additive particles comprising Al, Mg and Si as particle constituents, wherein Al, Mg and Si are present in the additive particles as elements or in one or more single phase mixtures of elements comprising one or more of the particle constituents, or a combination of one or more elements with one or more single phase mixtures of elements.
    Type: Application
    Filed: March 26, 2014
    Publication date: February 18, 2016
    Inventors: Markus KÖNIG, Nicole GEORG, Matthias HÖRTEIS
  • Publication number: 20160013333
    Abstract: In general, the invention relates to electro-conductive pastes with characteristic weight loss and their use in the preparation of photovoltaic solar cells. More specifically, the invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The invention relates to a paste comprising the following paste constituents: i. Metal particles; ii. An inorganic reaction system; iii. An organic vehicle; wherein the first weight loss ?30 is in the range from about 0.05 to about 0.3 wt. %.
    Type: Application
    Filed: July 8, 2015
    Publication date: January 14, 2016
    Inventors: Christian Muschelknautz, Matthias Horteis
  • Publication number: 20160013332
    Abstract: In general, the invention relates to electro-conductive pastes with characteristic weight loss and their use in the preparation of photovoltaic solar cells. More specifically, the invention relates to electro-conductive pastes, solar cell precursors, processes for preparation of solar cells, solar cells and solar modules. The invention relates to a paste comprising the following paste constituents: i. Metal particles; ii. An inorganic reaction system; iii. An organic vehicle; wherein the first weight loss ?30 is in the range from about 0.05 to about 0.3 wt. %.
    Type: Application
    Filed: July 8, 2015
    Publication date: January 14, 2016
    Inventors: Christian Muschelknautz, Matthias HORTEIS