Patents by Inventor Matthias Krull
Matthias Krull has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Publication number: 20250122418Abstract: A gas hydrate inhibitor composition is disclosed including two main components: (1) 5-95% of an amphiphilic compound with a hydrophobic tail linked to a hydrophilic head group through various linking structures, and (2) 5-95% of a cationic surfactant based on di(C8-C18 alkyl)dimethyl ammonium salts. The linking structures include amide-based linkers and more complex structures containing hydroxyl groups, carboxylic acid groups, and various combinations. The composition features specific requirements for substituent groups ranging from small alkyl chains to larger hydrocarbyl groups.Type: ApplicationFiled: September 25, 2024Publication date: April 17, 2025Inventors: Dirk LEINWEBER, Zachary Thomas WARD, Felix Hoevelmann, Jonathan James Wylde, Matthias KRULL
-
Patent number: 12129427Abstract: The present disclosure relates to a gas hydrate inhibitor composition comprising from an amphiphile having a hydrophobic tail linked to a hydrophilic head group by a linking moiety, the amphiphile having the general formula (1) [R5-L-N(R1)(R2)(R3)]+X???(1) wherein each of R1 and R2 is independently an alkyl group having from 1 to 5 carbon atoms; or wherein the nitrogen atom and the R1 and R2 groups together form a substituted or unsubstituted heterocyclic group; R3 is present or not as hydrogen or an alkyl group having from 1 to 8 carbon atoms which optionally bears a hydroxy group or a carboxy group in the 2-position; L is a linking moiety comprising an optionally substituted hydrocarbyl group having at least 2 adjacent carbon atoms, at least one heteroatom selected from nitrogen and oxygen, and optionally one or more further heteroatoms; R5 is a hydrocarbyl group having from 6 to 22 carbon atoms; and X? is present as an anion when R3 is present; and from a cationic surfactant which is selected fromType: GrantFiled: November 16, 2020Date of Patent: October 29, 2024Assignee: Clariant International LtdInventors: Dirk Leinweber, Zachary Thomas Ward, Felix Hoevelmann, Jonathan James Wylde, Matthias Krull
-
Patent number: 12060480Abstract: The invention relates to polymer compositions with improved manageability. The invention also relates to a polymer composition obtainable by radical polymerisation of A) 95-40 wt. % of a monomer mixture comprising Ai) 65-98 wt. % of at least alkyl (meth)acrylate having a linear C16-C40 alkyl radical and Aii) 2-35 wt. % of at least one comonomer selected from (meth)acrylates and (meth)acrylamides, which supports an optionally substituted aromatic radical bonded via an alkylene, alkenylene, oxyalkylene or polyoxyalkylene group to the ester group of the (meth)acrylate or to the amide group of the (meth)acrylamide, in the presence of B) 5-60% by weight % of at least one ethylene copolymer. The invention further relates to a method for the preparation and use thereof as flow improvers for paraffin-containing hydrocarbon oils.Type: GrantFiled: August 31, 2020Date of Patent: August 13, 2024Assignee: Clariant International LtdInventors: Michael Feustel, Mike Saul, Matthias Krull
-
Publication number: 20240218276Abstract: The present invention relates to a fuel oil having a sulfur content of less than 50 ppm, comprising i. at least one oil-soluble amide-ammonium salt of a polycarboxylic acid with a mono- and/or dialkylamine (A) and ii. 5-100% by weight, based on the amount of amide-ammonium salt (A), of an oil-soluble amine (B), and iii. a lubricity additive (C) selected from fatty acids, fatty acid partial esters of polyols and fatty acid amides of alkanolamides, and wherein the fuel oil consists of fuel oil of mineral origin, synthetic fuel or a mixture thereof.Type: ApplicationFiled: January 15, 2021Publication date: July 4, 2024Applicant: Clariant International Ltd.Inventors: Matthias KRULL, Kerstin MÜLLER, Simone HACKLÄNDER, Oliver HUBERT, Sergey BURMISTROV, Lydmila ABRAMOVA, Alexander UTKIN
-
Patent number: 11993550Abstract: The present invention provides for the use of at least one oil soluble polymer comprising linear polymethylene sequences with an average of 10 to 40 consecutive methylene groups to improve the water resistance of an explosive composition comprising particulate ammonium nitrate and a fuel oil, said linear polymethylene sequences with in average 10 to 40 consecutive methylene groups may be either in the main chain or in the side chains of the oil soluble polymer.Type: GrantFiled: March 13, 2017Date of Patent: May 28, 2024Assignee: CLARIANT INTERNATIONAL LTDInventors: Michael Feustel, Matthias Krull, Ian James Tolliday, Christopher Robin Collins, Maja Franjic, Thomas Roy
-
Patent number: 11993756Abstract: The present invention relates to a low-temperature additive for fuel oils having a sulfur content of less than 50 ppm, comprising i) at least one oil-soluble amide-ammonium salt of a polycarboxylic acid with a mono- and/or dialkylamine (A) and ii) 5-100% by weight, based on the amount of amide-ammonium salt (A), of an oil-soluble amine (B), and iii) 0.1 to 10 parts by weight, based on the amount of amide-ammonium salt (A), of a resin formed from at least one aromatic compound bearing an alkyl radical and an aldehyde and/or ketone (D).Type: GrantFiled: January 15, 2021Date of Patent: May 28, 2024Assignee: Clariant International LtdInventors: Matthias Krull, Kerstin Müller, Simone Hackländer, Oliver Hubert, Sergey Burmistrov, Lydmila Abramova, Alexander Utkin
-
Patent number: 11981876Abstract: This invention provides a wax inhibitor composition comprising A) the reaction product obtainable by reaction of i) a carboxylic acid containing an optionally substituted cycloaliphatic hydrocarbyl residue with ii) an alkylene polyamine, B) a polymeric wax inhibitor, and C) an organic solvent.Type: GrantFiled: June 18, 2020Date of Patent: May 14, 2024Assignee: Clariant International LtdInventors: Michael Feustel, Matthias Krull
-
Patent number: 11976248Abstract: The invention provides dispersions comprising I) at least one oil-soluble polymer effective as a cold flow improver for mineral oils, II) at least one organic, water-immiscible solvent, III) a dispersant comprising, based on the total amount of dispersant, a) 10-90% by weight of a salt of an ethercarboxylic acid and b) 90-10% by weight of a nonionic surfactant, IV) water and V) at least one organic, water-miscible solvent.Type: GrantFiled: August 13, 2018Date of Patent: May 7, 2024Assignee: Dorf Ketal Energy Services LLCInventors: Michael Feustel, Matthias Krull, Victor Goncharov
-
Patent number: 11898091Abstract: Disclosed is a gas hydrate inhibitor composition comprising an amphiphile by a linking moiety, the amphiphile having of the general formula (1) [R5-L-N(R1)(R2)(R3)]+X???(1) wherein each of R1 and R2 is an alkyl group having from 1 to 5 carbon atoms; or wherein the nitrogen atom and the R1 and R2 groups together form a heterocyclic group; R3 is present or not as hydrogen or an alkyl group having from 1 to 8 carbon atoms L is a linking moiety comprising a hydrocarbyl group having at least 2 adjacent carbon atoms, at least one heteroatom selected from nitrogen and oxygen, R5 is a hydrocarbyl group having from 6 to 22 carbon atoms; and X? is present as an anion when R3 is present; and a cationic surfactant which is selected from quaternary benzyl ammonium salts and a method of using the gas hydrate inhibitor composition.Type: GrantFiled: November 16, 2020Date of Patent: February 13, 2024Assignee: CLARIANT INTERNATIONAL LTDInventors: Dirk Leinweber, Zachary Thomas Ward, Felix Hoevelmann, Jonathan James Wylde, Matthias Krull
-
Patent number: 11845892Abstract: Use of complex polyester amines and polyester quaternary ammonium compounds as corrosion inhibitors for metal surfaces, and a method for protecting a metal surface from corrosion by contacting the metal surface with said corrosion inhibitor.Type: GrantFiled: August 5, 2021Date of Patent: December 19, 2023Assignee: CLARIANT INTERNATIONAL LTDInventors: Dirk Leinweber, Tobias Platen, Nihal N. Obeyesekere, Matthias Krull
-
Publication number: 20230340351Abstract: The present invention relates to a low-temperature additive for fuel oils having a sulfur content of less than 50 ppm, comprising i) at least one oil-soluble amide-ammonium salt of a polycarboxylic acid with a mono- and/or dialkylamine (A) and ii) 5-100% by weight, based on the amount of amide-ammonium salt (A), of an oil-soluble amine (B), and iii) 0.1 to 10 parts by weight, based on the amount of amide-ammonium salt (A), of a resin formed from at least one aromatic compound bearing an alkyl radical and an aldehyde and/or ketone (D).Type: ApplicationFiled: January 15, 2021Publication date: October 26, 2023Applicant: Clariant International Ltd.Inventors: Matthias KRULL, Kerstin MÜLLER, Simone HACKLÄNDER, Oliver HUBERT, Sergey BURMISTROV, Lydmila ABRAMOVA, Alexander UTKIN
-
Patent number: 11753576Abstract: This invention relates to a method for inhibiting the agglomeration of gas hydrates, comprising the injection of an anti-agglomerant comprising a N,N-dialkyl-ammoniumalkyl fatty acid amide represented by the formula (I) wherein R1 is an alkyl or alkenyl group having from 7 to 21 carbon atoms, R2 and R3 are each independently an alkyl group containing 1 to 10 carbon atoms, or together form an optionally substituted ring having 5 to 10 ring atoms, wherein the ring may carry up to 3 substituents, R4 is hydrogen or an alkyl group having 1 to 6 carbon atoms, R5 is hydrogen or an optionally substituted hydrocarbyl group having 1 to 17 carbon atoms and A is an alkylene group having two or three carbon atoms, into a fluid comprising gas, water and oil under conditions prone to the formation of gas hydrates, wherein the N,N-dialkyl-ammoniumalkyl fatty acid amide represented by the formula (I) is produced by the condensation reaction of a fatty acid with an N,N-dialkylamino alkyl amine and subsequent neutralizationType: GrantFiled: May 28, 2019Date of Patent: September 12, 2023Assignee: Clariant International Ltd.Inventors: Scot Bodnar, Dan Smith, Felix Hoevelmann, Corinna Krüger, Matthias Krull, Jonathan James Wylde, Lisa Greaney Tejada
-
Patent number: 11753577Abstract: This invention relates to a method for inhibiting the agglomeration of gas hydrates, comprising the injection of an anti-agglomerant comprising a N,N-dialkyl-ammoniumalkyl fatty acid amide represented by the formula (I) wherein R1 is an alkyl or alkenyl group having from 7 to 21 carbon atoms, R2 and R3 are each independently an alkyl group containing 1 to 10 carbon atoms, or together form an optionally substituted ring having 5 to 10 ring atoms, wherein the ring may carry up to 3 substituents, R4 is hydrogen or an alkyl group having 1 to 6 carbon atoms, R5 is hydrogen or an optionally substituted hydrocarbyl group having 1 to 22 carbon atoms and A is an alkylene group having two or three carbon atoms, into a fluid comprising gas, water and oil under conditions prone to the formation of gas hydrates, wherein the N,N-dialkyl-ammoniumalkyl fatty acid amide represented by formula (I) is produced by the aminolysis of an ester of a fatty acid and a C1- to C4-alcohol with an N,N-dialkylamino alkyl amine and sType: GrantFiled: May 28, 2019Date of Patent: September 12, 2023Assignee: Clariant International Ltd.Inventors: Scot Bodnar, Dan Smith, Felix Hoevelmann, Corinna Krüger, Matthias Krull, Jonathan James Wylde, Lisa Greaney Tejada
-
Patent number: 11692053Abstract: This invention relates a wax inhibitor for hydrocarbon oils comprising an esterified copolymer having repeating structural units derived from an esterified ethylenically unsaturated dicarboxylic acid and ?-olefins having at least 18 carbon atoms, whereof at least 3 mol-% of the ?-olefins have 30 or more carbon atoms, and wherein the ethylenically unsaturated dicarboxylic acid has been esterified with a mixture of alcohols comprising i) 70 to 97 mol-% of a saturated fatty alcohol having 18 to 24 carbon atoms and ii) 3 to 30 mol-% of an unsaturated alcohol having 16 to 24 carbon atoms.Type: GrantFiled: April 21, 2021Date of Patent: July 4, 2023Assignee: CLARIANT INTERNATIONAL LTDInventors: Anton Kaiser, Michael Feustel, Christoph Kayser, Matthias Krull, Michael Schaefer, Rashod Smith
-
Publication number: 20230159812Abstract: This invention provides a composition comprising I. at least one reaction product between a nitrogen-free monohydric alcohol and an aldehyde or ketone, and II. at least one reaction product between a nitrogen-free polyhydric alcohol and an aldehyde or ketone, and optionally III. at least one reaction product from III.a) formaldehyde, and III.b) an amine, selected from the group consisting of primary alkyl amines having 1 to 4 carbon atoms, and primary hydroxy alkyl amines having 2 to 4 carbon atoms, and optionally IV. at least one solid suppression agent selected from the group consisting of IV(a). alkali or alkaline earth metal hydroxides IV(b). mono-, di- or tri-hydroxy alkyl, aryl or alkylaryl amines, IV(c). mono-, di- or tri-alkyl, aryl or alkylaryl primary, secondary and tertiary amines or IV(d). multifunctional amines and IV(e). mixtures of compounds of groups IV(a) to IV(c). wherein alkyl is C1 to C15, aryl is C6 to C15 and alkylaryl is C7 to C15.Type: ApplicationFiled: November 7, 2022Publication date: May 25, 2023Applicant: Clariant International Ltd.Inventors: Antonio Pedro DE OLIVEIRA FILHO, Aline KINA, Grahame TAYLOR, Jonathan WYLDE, James BEGEAL, Ali YOUSEF, Matthias KRULL, Mike SAHL
-
Publication number: 20230102819Abstract: Use of complex polyester amines and polyester quaternary ammonium compounds as corrosion inhibitors for metal surfaces, and a method for protecting a metal surface from corrosion by contacting the metal surface with said corrosion inhibitor.Type: ApplicationFiled: August 5, 2021Publication date: March 30, 2023Applicant: Clariant International, Ltd.Inventors: Dirk LEINWEBER, Tobias PLATEN, Nihal N. OBEYESEKERE, Matthias KRULL
-
Patent number: 11603497Abstract: This invention provides a composition comprising I. at least one reaction product between a nitrogen-free monohydric alcohol and an aldehyde or ketone, and II. at least one reaction product between a monosaccharide having 3 to 6 carbon atoms and/or an oligosaccharide being formed by oligomerization of monosaccharides having 3 to 6 carbon atoms and an aldehyde or ketone, and optionally III. at least one reaction product from III.a) formaldehyde, and III.b) an amine, selected from the group consisting of primary alkyl amines having 1 to 4 carbon atoms, and primary hydroxy alkyl amines having 2 to 4 carbon atoms, and optionally IV. at least one solid suppression agent selected from the group consisting of IV(a). alkali or alkaline earth metal hydroxides IV(b). mono-, di- or tri-hydroxy alkyl, aryl or alkylaryl amines, IV(c). mono-, di- or tri-alkyl, aryl or alkylaryl primary, secondary and tertiary amines or IV(d). multifunctional amines and IV(e). mixtures of compounds of groups IV(a) to IV(c).Type: GrantFiled: January 23, 2020Date of Patent: March 14, 2023Assignee: CLARIANT INTERNATIONAL LTDInventors: Antonio Pedro de Oliveira Felho, Aline Yae Kina, Grahame N. Taylor, Fabian Schneider, Julie Murison, Stefan Hauck, Mike Sahl, Matthias Krull, Jonathan James Wylde
-
Patent number: 11583787Abstract: This invention provides a concentrated demulsifier composition comprising A) at least 50 wt.-% of a demulsifier, selected from the group consisting of a polymeric nonionic oil-soluble demulsifier for mineral oils, and an alkyl aryl sulphonic acid or its salt, and mixtures thereof, B) 0.1 to 20 wt.-% of a surfactant selected form anionic, cationic, zwitterionic and nonionic surfactants, the surfactant being different from the demulsifier, C) less than 20 wt.-% of a water-immiscible organic solvent, D) 3 to 49 wt.-% of a water-miscible organic solvent and E) 0 to 5 wt.-% of water.Type: GrantFiled: May 16, 2018Date of Patent: February 21, 2023Assignee: CLARIANT INTERNATIONAL LTDInventors: Antonio Pedro de Oliveira Filho, Carlos Augusto Blasques Tooge, Thiago Nogueira, Everton Basso, Sergio Costa Da Silva, Carlos Alberto Magaton, Matthias Krull
-
Patent number: 11555140Abstract: This invention provides a composition comprising I. at least one reaction product between a nitrogen-free monohydric alcohol and an aldehyde or ketone, and II. at least one reaction product between a nitrogen-free sugar alcohol and an aldehyde or ketone, and optionally III. at least one reaction product from III.a) formaldehyde, and III.b) an amine, selected from the group consisting of primary alkyl amines having 1 to 4 carbon atoms, and primary hydroxy alkyl amines having 2 to 4 carbon atoms, and optionally IV. at least one solid suppression agent selected from the group consisting of IV(a). alkali or alkaline earth metal hydroxides IV(b). mono-, di- or tri-hydroxy alkyl, aryl or alkylaryl amines, IV(c). mono-, di- or tri-alkyl, aryl or alkylaryl primary, secondary and tertiary amines or IV(d). multifunctional amines and IV(e). mixtures of compounds of groups IV(a) to IV(c). wherein alkyl is C1 to C15, aryl is C6 to C15 and alkylaryl is C7 to C15.Type: GrantFiled: December 22, 2017Date of Patent: January 17, 2023Assignee: CLARIANT INTERNATIONAL LTDInventors: Antonio Pedro de Oliveira Filho, Aline Yae Kina, Grahame N. Taylor, Fabian Schneider, Julie Murison, Stefan Hauck, Mike Sahl, Matthias Krull, Jonathan James Wylde
-
Patent number: 11530347Abstract: This invention provides a composition comprising I. at least one reaction product between a nitrogen-free monohydric alcohol and an aldehyde or ketone, and II. at least one reaction product between a nitrogen-free polyhydric alcohol and an aldehyde or ketone, and optionally III. at least one reaction product from III.a) formaldehyde, and III.b) an amine, selected from the group consisting of primary alkyl amines having 1 to 4 carbon atoms, and primary hydroxy alkyl amines having 2 to 4 carbon atoms, and optionally IV. at least one solid suppression agent selected from the group consisting of IV(a). alkali or alkaline earth metal hydroxides IV(b). mono-, di- or tri-hydroxy alkyl, aryl or alkylaryl amines, IV(c). mono-, di- or tri-alkyl, aryl or alkylaryl primary, secondary and tertiary amines or IV(d). multifunctional amines and IV(e). mixtures of compounds of groups IV(a) to IV(c). wherein alkyl is C1 to C15, aryl is C6 to C15 and alkylaryl is C7 to C15.Type: GrantFiled: May 17, 2017Date of Patent: December 20, 2022Assignee: Clariant International LtdInventors: Antonio Pedro De Oliveira Filho, Aline Kina, Grahame Taylor, Jonathan Wylde, James Begeal, Ali Yousef, Matthias Krull, Mike Sahl