Abstract: A method for monitoring the quality of a laser process such as a laser welding process includes monitoring the light emitted from the weld plasma above the surface of the workpiece irradiated by the laser beam. The intensity of the light emitted from the plasma is compared to a predetermined value of the light emission as determined under process and workpiece conditions that produce welds of acceptable quality. Variations of the monitored light intensity greater than a preselected value can be valuated as unacceptable welds. Such variations can be caused by changes in the laser beam power, the workpiece speed, laser focusing problems, insufficient shield gas flow, workpiece deformation and weld contamination. The process monitors the light emission for a selected range of wavelengths that correspond to the major emission peaks of the light spectrum. The method enables in-process control of laser processes.

Abstract: A method and apparatus for noninvasively measuring blood glucose levels provides an indirect, reagentless, differential, photoacoustic technique which responds to absorption in a thin surface layer. An excitation source provides electromagnetic energy which is utilized to irradiate the tissue, such as skin. The output of the radiation of the excitation source at the desired wavelength is coupled through a transmission device, such as a fiber optic bundle, which irradiates the electromagnetic energy onto the body surface. Upon irradiation, acoustic energy is generated by the absorption of the electromagnetic energy in a relatively thin layer of the sample to be measured, characterized by a heat-diffusing length. The acoustic energy is detected by the probe which includes a measuring cell, reference cell, window and differential microphone. Absorption of the light beam results in periodic heating of the tissue, at and near the tissue surface.

Abstract: A method and apparatus for monitoring the quality of a laser process such as a welding process comprises monitoring the light emitted from the weld plasma above the surface of the workpiece being irradiated by the laser beam. The size of the plasma is determined from the light emission and compared to a predetermined value of the size as determined under process and workpiece conditions that produce welds of acceptable quality. Variations of the monitored plasma size greater than a preselected value can represent unacceptable welds. Such variations can be caused by changes in the laser beam power, the workpiece speed, laser focusing problems, insufficient shield gas flow, workpiece deformation and weld contamination. The process monitors the light emission from a selected range of wavelengths that correspond to the major emission peaks of the light spectrum. The process enables in-process control.

Abstract: The system and method are set forth for photoacoustical analysis of isotope and other compounds having telltale absorption wavelenghths between 1700-2500 nm. The system and method includes a Co:Mg F.sub.2, optical parametric oscillator (OPO) or diode laser tunable between 1700-2500 nm which is directed into a sample at energies sufficient to generate detectable acoustical emissions. A microphone detects the emissions for processing and analysis. The system and method is adapted to detect stable isotope compounds such as .sup.13 CO.sub.2 as well as other chemical compounds. For non-gaseous compounds, a CO.sub.2 or diode laser is used to photoablate the gaseous sample containing the suspected compound.

Abstract: A method and apparatus for noninvasively measuring blood glucose levels provides an indirect, reagentless, differential, photoacoustic technique which responds to absorption in a thin surface layer. An excitation source provides electromagnetic energy which is utilized to irradiate the tissue, such as skin. The output of the radiation of the excitation source at the desired wavelength is coupled through a transmission device, such as a fiber optic bundle, which irradiates the electromagnetic energy onto the body surface. Upon irradiation, acoustic energy is generated by the absorption of the electromagnetic energy in a relatively thin layer of the sample to be measured, characterized by a heat-diffusing length. The acoustic energy is detected by the probe which includes a measuring cell, reference cell, window and differential microphone. Absorption of the light beam results in periodic heating of the tissue, at and near the tissue surface.

Abstract: A system and method are set forth for photoacoustical analysis of isotope and other compounds having telltale absorption wavelengths between 1700-2500 nm. The system and method includes a Co:Mg F.sub.2, optical parametric oscillator (OPO) or diode laser tunable between 1700-2500 nm which is directed into a sample at energies sufficient to generate detectable acoustical emissions. A microphone detects the emissions for processing and analysis. The system and method is adapted to detect stable isotope compounds such as .sup.13 CO.sub.2 as well as other chemical compounds. For non-gaseous compounds, a CO.sub.2 or diode laser is used to photoablate the gaseous sample contacting the suspected compound.

Abstract: This invention deals with a process for the production of hydroperoxides from their corresponding hydrocarbons via the use of certain ketones, particularly aryl ketones, generally having strong substituent electrophilic groups, as promoters. These promoters increase the rate of thermal oxidation and improve selectivity to the hydroperoxide products.

Abstract: A vacuum or high pressure seal operative at high temperatures is formed by placing a thin metal foil over an opening, and forming an electrical seam weld at the interface of the surface and the foil by guiding a needle-like electrode along a path around the opening at a substantially constant rate, with substantially constant pressure being applied to the electrode as it is moved along the path. When supported, the seal is capable of withstanding high pressures, say ten atmospheres, at high temperatures, say 500.degree. C.