Abstract: Acrylic polymer layers and colloidal silver halide photographic emulsions are coated to form layers without repellent spots from solutions containing a perfluoro compound .[.containing an intralinear carbonyl or sulfonyl group selected from the group: (1) perfluorocarbon compounds derived from perfluorocarboxylic acids having the general structure ##STR1## where C.sub.f is a fully fluorinated (perfluoro) saturated chain consisting of five or more carbon atoms which may or may not be an oxygen-interrupted carbon chain; X=OY or an amino group, where Y is H, alkali metal or an ammonium group, and (2) perfluoro compounds.]. derived from perfluorosulfonic and perfluorosulfuric acids having the general structure(C.sub.f).[..sub.x .]. (C.sub.H).sub.y (X)(Z)where C.sub.f is a fully fluorinated .Iadd.(perfluoro) saturated .Iaddend.carbon chain .[.as defined in paragraph (1).]. .Iadd.having six or more carbon atoms which may or may not be an oxygen-interrupted carbon chain.Iaddend.; C.sub.