Patents by Inventor Maurice S. Brookhart
Maurice S. Brookhart has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7297806Abstract: Alpha-olefin are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The ?-olefin are useful as monomers and chemical intermediates.Type: GrantFiled: September 5, 2002Date of Patent: November 20, 2007Assignees: EI du Pont de Nemours and Company, University of North CarolinaInventors: Maurice S. Brookhart, III, Brooke L. Small
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Patent number: 7271231Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: October 20, 2003Date of Patent: September 18, 2007Assignee: E. I. du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian
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Patent number: 7060768Abstract: Certain complexes containing ligands having a phosphino group, amino group or an imino group, and a second functional group such as amide, ester or ketone, when complexed to transition metals, catalyze the (co)polymerization of olefinic compounds such as ethylene, ?-olefins and/or acrylates. A newly recognized class of ligands for making copolymer containing polar monomers using late transition metal complexes is described.Type: GrantFiled: January 20, 2004Date of Patent: June 13, 2006Assignees: E.I. duPont de Nemours and Company, University of North Carolina at Chapel HillInventors: Maurice S. Brookhart, Keith Kunitsky, Weijun Liu, Jon M. Malinoski, Lin Wang, Ying Wang, Lynda Kaye Johnson, Kristina A. Kreutzer, Steven Dale Ittel
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Patent number: 7034093Abstract: Late transition metal complexes of certain neutral iminophosphine ligands are useful as components of polymerization catalysts for olefins. Useful metals in the complexes include Ni, Pd, Fe and Co. Oligomers and/or polymers of olefins such as ethylene can be made.Type: GrantFiled: March 5, 2003Date of Patent: April 25, 2006Assignees: E. I. du Pont de Nemours and Company, University of North CarolinaInventors: Maurice S. Brookhart, Olafs Daugulis
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Patent number: 6897272Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: August 23, 2000Date of Patent: May 24, 2005Assignee: E.I. Du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Samuel David Arthur, Stephan James McLain
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Patent number: 6894134Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: June 22, 2001Date of Patent: May 17, 2005Assignees: E. I. duPont de Nemours and Company, University of North Carolina at Chapel HillInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Elizabeth Forrester McCord, Stephan James McLain, Samuel David Arthur
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Publication number: 20040158012Abstract: Certain complexes containing ligands having a phosphino group, amino group or an imino group, and a second functional group such as amide, ester or ketone, when complexed to transition metals, catalyze the (co)polymerization of olefinic compounds such as ethylene, &agr;-olefins and/or acrylates. A newly recognized class of ligands for making copolymer containing polar monomers using late transition metal complexes is described.Type: ApplicationFiled: January 20, 2004Publication date: August 12, 2004Inventors: Maurice S. Brookhart, Keith Kunitsky, Weijun Liu, Jon M. Malinoski, Lin Wang, Ying Wang, Lynda Kaye Johnson, Kristina A. Kreutzer, Steven Dale Ittel
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Publication number: 20040102591Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: ApplicationFiled: October 20, 2003Publication date: May 27, 2004Inventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian
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Patent number: 6740715Abstract: Alpha-olefins are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The &agr;-olefins are useful as monomers and chemical intermediates.Type: GrantFiled: September 5, 2002Date of Patent: May 25, 2004Assignees: E. I. du Pont de Nemours and Company, University of North CarolinaInventors: Maurice S. Brookhart, III, Brooke L. Small
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Patent number: 6710007Abstract: Certain complexes containing ligands having a phosphino group, amino group or an imino group, and a second functional group such as amide, ester or ketone, when complexed to transition metals, catalyze the (co)polymerization of olefinic compounds such as ethylene, &agr;-olefins and/or acrylates. A newly recognized class of ligands for making copolymer containing polar monomers using late transition metal complexes is described.Type: GrantFiled: January 25, 2002Date of Patent: March 23, 2004Assignees: E. I. du Pont de Nemours and Company, University of North Carolina at Chapel HillInventors: Maurice S. Brookhart, Keith Kunitsky, Weijun Liu, Jon M. Malinoski, Lin Wang, Ying Wang, Lynda Kaye Johnson, Kristina A. Kreutzer, Steven Dale Ittel
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Patent number: 6670297Abstract: Catalysts for the polymerization of olefins are provided. The catalysts contain transition metals including nickel and palladium and a diimine ligand in a square planar configuration with two other ligands, and are useful in the polymerization of, for example, olefins, cycloolefins, olefinic esters, and olefinic carboxylic acids. The cocatalyst forms a useable coordinating anion. Polymerization processes using the catalysts can produce homopolymers and copolymers, and the polymers produced may be crosslinked and/or exhibit branching.Type: GrantFiled: November 6, 2000Date of Patent: December 30, 2003Assignees: E. I. du Pont de Nemours and Company, University of North CarolinaInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian
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Publication number: 20030171508Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: ApplicationFiled: June 22, 2001Publication date: September 11, 2003Inventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Jerald Feldman, Elizabeth Forrester McCord, Stephan James McLain, Kristina Ann Kreutzer, Alison Margaret Anne Bennett, Edward Bryan Coughlin, Steven Dale Ittel, Anju Parthasarathy, Daniel Joseph Tempel
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Publication number: 20030125485Abstract: Certain complexes containing ligands having a phosphino group, amino group or an imino group, and a second functional group such as amide, ester or ketone, when complexed to transition metals, catalyze the (co)polymerization of olefinic compounds such as ethylene, &agr;-olefins and/or acrylates. A newly recognized class of ligands for making copolymer containing polar monomers using late transition metal complexes is described.Type: ApplicationFiled: January 25, 2002Publication date: July 3, 2003Inventors: Maurice S. Brookhart, Keith Kunitsky, Weijun Liu, Jon M. Malinoski, Lin Wang, Ying Wang, Lynda Kaye Johnson, Kristina A. Kreutzer, Steven Dale Ittel
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Patent number: 6573353Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: September 12, 2000Date of Patent: June 3, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Elizabeth Forrester McCord, Stephan James McLain, Daniel Joseph Tempel
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Publication number: 20030050494Abstract: Alpha-olefins are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The &agr;-olefins are useful as monomers and chemical intermediates.Type: ApplicationFiled: September 5, 2002Publication date: March 13, 2003Inventors: Maurice S. Brookhart, Brooke L. Small
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Publication number: 20030036615Abstract: Alpha-olefins are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The &agr;-olefins are useful as monomers and chemical intermediates.Type: ApplicationFiled: September 5, 2002Publication date: February 20, 2003Inventors: Maurice S. Brookhart, Brooke L. Small
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Patent number: 6495646Abstract: Polyolefins with unique highly branched structures, and which have unusually low Mark-Houwink constants are described. They are useful for instance as elastomers, viscosity index modifiers and lubricating oil bases.Type: GrantFiled: February 29, 2000Date of Patent: December 17, 2002Assignees: E. I. du Pont de Nemours and Company, University of North Carolina at Chapel HillInventors: Samuel David Arthur, Maurice S. Brookhart, III, Patricia Metzger Cotts, Zhibin Guan, Lynda Kaye Johnson, Christopher Moore Killian, Elizabeth Forrester McCord, Stephan James McLain
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Patent number: 6489497Abstract: Alpha-olefins are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator compound such as an alkyl aluminum compound. Novel bisimines and their iron complexes are also disclosed. The &agr;-olefins are useful as monomers and chemical intermediates.Type: GrantFiled: July 7, 2000Date of Patent: December 3, 2002Assignees: E. I. du Pont de Nemours and Company, University of North CarolinaInventors: Maurice S. Brookhart, III, Brooke L. Small
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Patent number: 6451940Abstract: Selected nickel complexes of the anions of certain 2-aminotropones are olefin polymerization catalysts. Novel 2-aminotropones and their nickel complexes are also disclosed together with methods of making these 2-aminotropones. Suitable complexes have the following structure: wherein: R2 is hydrocarbyl or substituted hydrocarbyl, provided that R2 is attached to said nitrogen atom in (I) by an atom that has at least 2 other atoms that are not hydrogen attached to it; and R3, R4, R5, R6 and R7 are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, provided that any two of R3, R4, R5, R6 and R7 vicinal to one another may form a ring; L1 is a monodentate monoanionic ligand and L2 is a monodentate neutral ligand or an empty coordination site, or L1 and L2 taken together are a monoanionic bidentate ligand.Type: GrantFiled: October 13, 2000Date of Patent: September 17, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: Frederick Hicks, Maurice S. Brookhart
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Patent number: 6310163Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: July 10, 1997Date of Patent: October 30, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Jerald Feldman, Elizabeth Forrester McCord, Stephan James McLain, Kristina Ann Kreutzer, Alison Margaret Anne Bennett, Edward Bryan Coughlin, Steven Dale Ittel, Anju Parthasarathy, Daniel Joseph Tempel