Abstract: Metal oxide having a surface onto which a multitude of individual polymers are grafted, each polymer comprising an addition polymer having a first and a second end, and a first moiety comprising a terminal phosphonate group, which first moiety is bonded to the first end, which phosphonate group attaches to the metal oxide surface in such a way that the multitude of the grafted polymers comprises at least one group of adjacent polymers that have a stretched chain conformation wherein the adjacent stretched chains have a substantially parallel orientation, such that the polymers within said group together form a brush structure. Method of grafting a multitude of individual polymers onto a surface of a metal oxide.

Abstract: An apparatus for depolymerization of polymers, in particular polyesters, polyamides, polyurethanes and polycarbonates, comprises a microwave depolymerization reactor having a reaction chamber; a microwave generation and transport system to send microwaves into the reaction chamber and comprising a microwave generator and a guide device housed in the reaction chamber to convey and distribute microwaves in the reaction chamber; a mixing device, rotating around the axis in the reaction chamber and configured so as to dynamically distribute inside the reaction chamber a mixture of liquids and solids contained in the reaction chamber; and a pressurization system configured to vary the pressure within the reaction chamber.

Abstract: Metal oxide having a surface onto which a multitude of individual polymers are grafted, each polymer comprising an addition polymer having a first and a second end, and a first moiety comprising a terminal phosphonate group, which first moiety is bonded to the first end, which phosphonate group attaches to the metal oxide surface in such a way that the multitude of the grafted polymers comprises at least one group of adjacent polymers that have a stretched chain conformation wherein the adjacent stretched chains have a substantially parallel orientation, such that the polymers within said group together form a brush structure. Method of grafting a multitude of individual polymers onto a surface of a metal oxide.

Abstract: Metal oxide having a surface onto which a multitude of individual polymers are grafted, each polymer comprising an addition polymer having a first and a second end, and a first moiety comprising a terminal phosphonate group, which first moiety is bonded to the first end, which phosphonate group attaches to the metal oxide surface in such a way that the multitude of the grafted polymers comprises at least one group of adjacent polymers that have a stretched chain conformation wherein the adjacent stretched chains have a substantially parallel orientation, such that the polymers within said group together form a brush structure. Method of grafting a multitude of individual polymers onto a surface of a metal oxide.

Abstract: Metal oxide having a surface onto which a multitude of individual polymers are grafted, each polymer comprising an addition polymer having a first and a second end, and a first moiety comprising a terminal phosphonate group, which first moiety is bonded to the first end, which phosphonate group attaches to the metal oxide surface in such a way that the multitude of the grafted polymers comprises at least one group of adjacent polymers that have a stretched chain conformation wherein the adjacent stretched chains have a substantially parallel orientation, such that the polymers within said group together form a brush structure. Method of grafting a multitude of individual polymers onto a surface of a metal oxide.

Abstract: Photocatalytic composite materials, namely materials capable of promoting photo-initiated chemical reactions and processes for producing such materials, are provided. The invention further provides processes for producing photocatalytic composite materials which includes a macroporous matrix, the macroporous matrix having a surface grafting of preformed titanium dioxide nanocrystals, wherein the macroporous matrix may be produced by a sol-gel technique from a precursor of the macroporous matrix in the presence of a template-forming polymer and of hydrophobically-functionalized nano-crystalline titanium-dioxide particles.