Abstract: An aqueous solution for electroless autocatalytic copper plating, containing a source of cupric ions, a source of hydroxylic ions, a reducing agent and a complexing agent in such a quantity as to render soluble the cupric ions in an alkaline medium, which further contains a stabilizing mixture formed by allylthiourea, at least a ferrocyanide of alkali metal or of ammonium ion, and at least an octylphenylether of ethylene polyoxide with 9-10 moles of ethylene oxide for each mole of octylphenol, the said three stabilizing compounds exerting a synergical action.This solution shows a very good stability and produces copper deposits having clear and brilliant appearance and good ductility properties.