Abstract: An inkjet printable enamel ink including: at least one glass frit; at least one pigment; a crystalline bismuth silicate powder; and an organic carrier, wherein the glass frit, pigment, and crystalline bismuth silicate powder have a d99 particle size distribution of less than 4 micrometers in the organic carrier, wherein the ink has a viscosity less than 30 mPa·S?1 at 100 s?1 shear rate and a temperature of 35° C., and wherein the ink has a total solid content, including the glass frit, pigment, and crystalline bismuth silicate powder, of no more than 60 wt %.

Abstract: An enamel paste composition is provided for fabricating a coated glass article includes a glass substrate, an enamel layer disposed on the glass substrate, and a thin coating having a thickness of no greater than 0.5 micrometres disposed on the enamel layer. The enamel paste composition is formulated such that it provides a smooth surface and does not crystallize during processing of the coated glass article, thereby improving the quality of the thin coating disposed thereon.

Abstract: A paste for coating a glass substrate which, after coating, is subjected to firing and chemical strengthening by ion exchange to form an enamel coated, chemically strengthened glass product, the paste containing an organic carrier fluid; a first inorganic frit having a first softening point; and a second inorganic frit having a second softening point, wherein the softening point of the first inorganic frit is higher than the softening point of the second inorganic frit such that the second inorganic frit can be softened and sintered at a temperature lower than the softening point of the first inorganic frit, and wherein the first inorganic frit includes an exchangeable ion content which can be ion exchanged to chemically strengthen the first inorganic frit.

Abstract: A metal complex of the formula (1) TCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is the number 1 or 2, TCy is a thiophene-fused cyclopentadienyl-type ligand of the formula (2) is described. Methods of making and using the metal complex are also described.

Abstract: A metal complex of the formula (1) InCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is number of 1 to 2, InCy is an indole fused cyclopentadienyl-type ligand of the formula (2) wherein R1 independently is a C1-C4-alkyl, m is a number of 0 to 4, R2 is a C1-C10-alkyl, C5-C10-cycloalkyl, or a C6-C10-aryl unsubstituted or substituted with C1-C10-alkyl or C1-C4-dialkyl amino, R3, R4 and R5 each is independently selected from hydrogen, C1-C4-alkyl, C6-C10-aryl unsubstituted or substituted with C1-C4-alkyl, halide, or both of C1-C4-alkyl and halide and, L is an amidinate ligand of the formula (3a) wherein the amidine-containing ligand (3a) is bonded to the metal M via the imine nitrogen atom N2, wherein R7 is independently selected from C1-C4-alkyl and halide and q is a number of 0 to 4, Sub4 is a cyclic or linear aliphatic or aromatic substituent.

Abstract: Disclosed is a composition for sealing inorganic substrates. The composition includes a glass frit and optionally a filler material, wherein the glass frit contains: 30 to 65 wt % V2O5; 5 to 35 wt % P2O5; 0 to 30 wt % TeO2; 0 to 30 wt % Bi2O3; 0 to 15 wt % ZnO; 0 to 10 wt % MnO; 0 to 5 wt % B2O3; 0 to 5 wt % total alkali metal oxides; 0 to 2 wt % Nb2O5; 0 to 2 wt % WO3; 0 to 2 wt % MoO3; 0 to 2 wt % SiO2; and 0 to 2 wt % Al2O3.

Abstract: A composition for sealing inorganic substrates, the composition comprising a glass frit and a filler material, wherein said glass frit comprises: 60 to 85 wt % Bi2O3; 3 to 15 wt % ZnO; 2 to 10 wt % B2O3; 0.6 to 5 wt % SiO2; 0.6 to 5 wt % Al2O3; and 0.1 to 0.5 wt % of a compound selected from NaF and BaF2.

Abstract: A metal complex of the formula (1) InCyLMZp??(1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, InCy is an indole fused cyclopentadienyl-type ligand of the formula (2) wherein R1 means for each index m individually a C1-C4-alkyl that substitutes a hydrogen atom of the benzene ring, m is a number of 0 to 4, preferably 0 to 2, in particular 0, R2 means C1-C10-alkyl, C5-C10-cycloalkyl, and an unsubstituted or C1-C10-alkyl or C1-C4-dialkyl amino substituted C6-C10-aryl, in particular C1-C4-alkyl substituted phenyl, more preferably methyl, phenyl or di-C1-C4-alkyl substituted phenyl, in particular di-tert.

Abstract: A metal complex of the formula (1) TCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is the number 1 or 2, TCy is a thiophene-fused cyclopentadienyl-type ligand of the formula (2) is described. Methods of making and using the metal complex are also described.