Abstract: A solid oxide cell (SOC) includes a fuel electrode, an oxygen electrode, and an electrolyte. In some embodiments, the solid oxide cell is a reversible proton conducting solid oxide cell (P-rSOC). In some embodiments, the oxygen electrode is a perovskite oxide material having a formula such as PrBa0.8Ca0.2Co2O5+?, PrBa0.9Co1.96Nb0.04O5, PrBaCo1.6Fc0.2Nb0.2?xO5+?, PrBa0.5Sr0.5Co1.5Fe0.5O5+? (PBSCF), or PrBaCo2O5+? (PBC) and it is coated with a perovskite oxide catalyst such as PrCoO3.

Abstract: Disclosed are air electrode materials suitable for use in solid oxide electrochemical cells (SOCs). The disclosed cells can operate in a dual function modes, i.e., as a fuel cell and as an electrolysis cell. In both cases, chemical energy and electrical energy can be directly convert from one mode to the other; thereby providing a highly efficient energy conversion process that can be used as a sustainable energy source.

Abstract: Disclosed herein are electrolytes having increased proton conduction and steam tolerance for use in solid oxide electrolysis cells (SOECs). The disclosed SOECs provide an enhanced means for obtaining hydrogen. The disclosed SOECs provide enhanced conductivity and stability and, therefore, result in higher performance when used to fabricate electrolysis cells, fuel cells, and reversible cells.

Abstract: Disclosed herein are barium hafnate comprising proton-conducting electrolytes for use in solid oxide fuel cells. The disclosed electrolytes are also useful for electrolysis operations and for carbon dioxide tolerance.

Abstract: Disclosed herein are barium hafnate comprising proton-conducting electrolytes for use in solid oxide fuel cells. The disclosed electrolytes are also useful for electrolysis operations and for carbon dioxide tolerance.

Abstract: Disclosed are air electrode materials suitable for use in solid oxide electrochemical cells (SOCs). The disclosed cells can operate in a dual function modes, i.e., as a fuel cell and as an electrolysis cell. In both cases, chemical energy and electrical energy can be directly convert from one mode to the other; thereby providing a highly efficient energy conversion process that can be used as a sustainable energy source.

Abstract: A hybrid catalyst coating composed of a conformal thin film with exsoluted PrOx nano-particles. The conformal PNM thin film can be a perovskite composition of PrNi0.5Mn0.5O3 (PNM). The PrOx nano-particles dramatically enhance the oxygen reduction reaction kinetics via a high concentration of oxygen vacancies while the thin PNM film effectively suppresses strontium segregation from the cathode of an intermediate-temperature solid oxide fuel cell.

Abstract: The present invention provides a layered lithium-rich manganese-based cathode material with olivine structured LiMPO4 surface modification and a preparation method thereof. The preparation method comprises: firstly, preparing a pure-phase layered lithium-rich manganese-based cathode material by using a coprecipitation method and a high temperature sintering method, and then uniformly coating and doping olivine-structured LiMPO4 to the surface of the layered lithium-manganese-rich composite cathode material by using a sol-gel method. According to the present invention, the surface of the layered lithium-rich manganese-based cathode material is modified by olivine structured LiMPO4, such that cycle stability thereof is effectively improved, and voltage drop generated by the material in the cycle course is inhibited. The preparation method according to the present invention is simple, low cost, environmentally friendly, and is suitable for large-scale industrial production.

Abstract: Disclosed are a lithium anode surface modification method for a lithium metal battery and a lithium metal battery. The modification method comprises the following steps: immersing, in a dry protective gas atmosphere, a lithium metal anode in a fluorine ion-containing liquid, or dropping a fluorine ion-containing liquid on a surface of the lithium metal anode; after fluorination and removal, a protective layer rich in lithium fluoride is formed on the surface of the lithium metal anode, and a lithium metal-coated lithium metal anode is obtained.

Abstract: A method of fabricating a SSZ/SDC bi-layer electrolyte solid oxide fuel cell, comprising the steps of: fabricating an NiO-YSZ anode substrate from a mixed NiO and yttria-stabilized zirconia by tape casting; sequentially depositing a NiO-SSZ buffer layer, a thin SSZ electrolyte layer and a SDC electrolyte on the NiO-YSZ anode substrate by a particle suspension coating or spraying process, wherein the layers are co-fired at high temperature to densify the electrolyte layers to at least about 96% of their theoretical densities; and painting/spraying a SSC-SDC slurry on the SDC electrolyte to form a porous SSC-SDC cathode. A SSZ/SDC bi-layer electrolyte cell device and a method of using such device are also discussed.

Abstract: The present invention provides a layered lithium-rich manganese-based cathode material with olivine structured LiMPO4 surface modification and a preparation method thereof. The preparation method comprises: firstly, preparing a pure-phase layered lithium-rich manganese-based cathode material by using a coprecipitation method and a high temperature sintering method, and then uniformly coating and doping olivine-structured LiMPO4 to the surface of the layered lithium-manganese-rich composite cathode material by using a sol-gel method. According to the present invention, the surface of the layered lithium-rich manganese-based cathode material is modified by olivine structured LiMPO4, such that cycle stability thereof is effectively improved, and voltage drop generated by the material in the cycle course is inhibited. The preparation method according to the present invention is simple, low cost, environmentally friendly, and is suitable for large-scale industrial production.

Abstract: A solid oxide fuel cell capable of directly utilizing hydrocarbons as a fuel source at operating temperatures between 200° C. and 500° C. The anode, electrolyte, and cathode of the solid oxide fuel cell can include technologies for improved operation at temperatures between 200° C. and 500° C. The anode can include technologies for improved direct utilization of hydrocarbon fuel sources.

Abstract: A solid oxide fuel cell capable of directly utilizing hydrocarbons as a fuel source at operating temperatures between 200° C. and 500° C. The anode, electrolyte, and cathode of the solid oxide fuel cell can include technologies for improved operation at temperatures between 200° C. and 500° C. The anode can include technologies for improved direct utilization of hydrocarbon fuel sources.

Abstract: A hybrid catalyst coating composed of a conformal thin film with exsoluted PrOx nano-particles. The conformal PNM thin film can be a perovskite composition of PrNi0.5Mn0.5O3 (PNM). The PrOx nano-particles dramatically enhance the oxygen reduction reaction kinetics via a high concentration of oxygen vacancies while the thin PNM film effectively suppresses strontium segregation from the cathode of an intermediate-temperature solid oxide fuel cell.

Abstract: A composition of matter is disclosed which is a perovskite having a composition A2?xA?xB2?yB?yO6??, where A is a praseodymium (Pr) element at the A-site of the perovskite, A? is a strontium (Sr) element at the A-site of the perovskite, B is a cobalt (Co) element at the B-site of the perovskite, and B? is a manganese (Mn) element at the B-site of the perovskite, and where 0<x ?1 and 0<y<2. Also disclosed is an electrode material Conformally coated with the composition of matter. Also disclosed are methods of producing the composition of matter and conformally coating the electrode material. Also disclosed an electrode is conformally coated with a praseodymium strontium manganese perovskite and a method for the coating.

Abstract: A composition of matter is disclosed which is a perovskite having a composition A2-xA?xB2-yB?yO6-?, where A is a praseodymium (Pr) element at the A-site of the perovskite, A? is a strontium (Sr) element at the A-site of the perovskite, B is a cobalt (Co) element at the B-site of the perovskite, and B? is a manganese (Mn) element at the B-site of the perovskite, and where 0<x?1 and 0<y<2. Also disclosed is an electrode material Conformally coated with the composition of matter. Also disclosed are methods of producing the composition of matter and conformally coating the electrode material. Also disclosed an electrode is conformally coated with a praseodymium strontium manganese perovskite and a method for the coating.

Abstract: The present invention discloses an integrated SOFC system powered by natural gas. Specifically, a SOFC-O cell is combined with a SOFC-H cell so as to take advantage of the high operating temperature and steam reforming capabilities of the SOFC-O cell as well as the higher fuel conversion efficiency of the SOFC-H cell.

Abstract: Embodiments of the present anhydrous fuel cell electrodes comprise an anhydrous catalyst layer and a gas diffusion layer, wherein the anhydrous catalyst layer comprises at least one catalyst, about 5 mg/cm2 to about 100 mg/cm2 of phosphoric acid added as a catalyzing reagent during formation of the catalyst layer, and a binder comprising at least one triazole modified polymer, wherein the triazole modified polymer comprises a polysiloxane backbone and a triazole substituent.

Abstract: The present invention relates to a novel method for preparing a BZCYYb material to be used in a solid oxide fuel cell. In particular, the method comprises mixing particular nano-sized and micro-sized ingredients and the size selection provides greatly improved performance characteristics of the resulting material. In particular, barium carbonate powder, zirconium oxide powder having particle diameters in the nanometer range, and cerium oxide powder having particle diameter in the micrometer range are used together with ytterbium oxide powder, and yttrium oxide powder.

Abstract: Embodiments of the present disclosure include chemical compositions, structures, anodes, cathodes, electrolytes for solid oxide fuel cells, solid oxide fuel cells, fuel cells, fuel cell membranes, separation membranes, catalytic membranes, sensors, coatings for electrolytes, electrodes, membranes, and catalysts, and the like, are disclosed.