Abstract: A negative electrode for an electrochemical cell that cycles lithium includes a negative electrode including an electroactive material layer disposed on a current collector that has lithiated silicon oxide (LSO) negative electroactive material at ? about 10 weight % to ? about 30 weight % of a total weight of the electroactive material layer and a carbonaceous negative electroactive material, such as graphite. An electrochemical cell that incorporates such a negative electrode may also include a second electrode comprising a porous positive active material layer comprising a positive lithium containing, nickel-rich electroactive material, such as a lithium nickel manganese cobalt aluminum oxide, a porous separating layer disposed between the first electrode and the second electrode and an electrolyte disposed in pores of the separating layer.

Abstract: An electrochemical cell that cycles lithium ions includes a positive electrode that includes a positive electroactive material, a negative electrode that includes a negative electroactive material, and a free-standing separating layer disposed between the positive electrode and the negative electrode. The free-standing separating layer includes a gel membrane that includes a polymer host and a liquid electrolyte and an integrated structural component disposed within the gel membrane. The integrated structural component may be selected from the group consisting of: a plurality of solid-state electrolyte particles, a nonwoven material, and a combination thereof.

Abstract: A modular bipolar solid-state battery includes T solid-state battery modules, where T is an integer greater than one. Each of the T solid-state battery modules includes an enclosure, a first terminal arranged on a first side of the enclosure, a second terminal arranged on a second side of the enclosure opposite to the first side of the enclosure, and N solid-state battery cells arranged and interconnected in the enclosure, where N is an integer greater than one. The T solid-state battery modules are connected in at least one of series and parallel. A positive terminal of the modular bipolar solid-state battery is connected to at least one of the T solid-state battery modules. A negative terminal of the modular bipolar solid-state battery is connected to at least another one of the T solid-state battery modules.

Abstract: A method for testing a sample of a battery cell includes arranging the sample of the battery cell in a sample pan of a test crucible; arranging a spacer on the sample of the battery cell; sealing the sample pan; and performing differential scanning calorimetry (DSC) testing of the sample.

Abstract: A vehicle system is provided and includes a modular dynamically allocated capacity storage system (MODACS) and an active management module. The MODACS includes blocks of cells. The active management module is configured to: detect a first state of a first block of cells of the blocks of cells; determine whether a safety fault condition exists with the first block of cells based on the first state of the first block of cells; in response to detecting existence of the safety fault condition, isolate the first block of cells from other ones of the blocks of cells; subsequent to isolating the first block of cells, actively discharge and detect a second state of the first block of cells; and based on the second state, continue isolating the first block of cells or reconnecting the first block of cells such that the first block of cells is no longer isolated.

Abstract: A method for manufacturing a gel membrane for a battery cell includes supplying a first substrate to a first roller; heating a gel membrane solution in a tank, wherein the gel membrane solution includes a polymer and a liquid electrolyte comprising one or more lithium salts; arranging a slot die within a predetermined distance of the first substrate located on the first roller; pumping the gel membrane solution into an inlet of the slot die; depositing a gel membrane layer from an outlet of the slot die onto the first substrate supported by the first roller; and cooling the gel membrane layer on the first substrate.

Abstract: A battery includes positive and negative current collectors and a plurality of bipolar electrodes arranged in a stack between the positive and negative current collectors. The positive and negative current collectors and the stack of the plurality of bipolar electrodes are folded in an S-shape.

Abstract: The present disclosure provides a modified binder for use in an electrochemical cell that cycles lithium ions. The modified binder includes one or more agglomerates of polytetrafluoroethylene nanoparticles, where each of the polytetrafluoroethylene nanoparticles includes a polytetrafluoroethylene core and a polymeric shell that is disposed on exposed surfaces of the core. The polymeric shell can include a polymer selected from the group consisting of: polyethylene oxide, polyglycidyl methacrylate, polyvinylidene difluoride, fluoride-hexafluoropropylene, polypropylene oxide, polyacrylonitrile, polymethacrylonitrile, polymethyl methacrylate, derivatives and co-polymers, and combinations thereof, and in certain instances, also a humidity tolerant lithium salt.

Abstract: The present disclosure relates to a solid-state electrochemical cell having a uniformly distributed solid-state electrolyte and methods of fabrication relating thereto. The method may include forming a plurality of apertures within the one or more solid-state electrodes; impregnating the one or more solid-state electrodes with a solid-state electrolyte precursor solution so as to fill the plurality of apertures and any other void or pores within the one or more electrodes with the solid-state electrolyte precursor solution; and heating the one or more electrodes so as to solidify the solid-state electrolyte precursor solution and to form the distributed solid-state electrolyte.

Abstract: A method of manufacturing an electrode for an electrochemical cell includes providing an admixture including an electroactive material, a binder, and a solvent. The method further includes rolling the admixture to form a sheet and forming a multi-layer stack from the sheet. The method further includes forming an electrode film precursor by performing a plurality of sequential rollings, each including rolling the stack through a first gap. The plurality of sequential rollings includes first and second rollings. In the first rolling, the stack is in a first orientation. In the second rolling, the stack is in a second orientation different from the first orientation. The method further includes forming an electrode film by rolling the electrode film precursor through a second gap less than or equal to the first gap. The method further includes drying the electrode film to remove at least a portion of the solvent.

Abstract: A bipolar battery includes N battery cores each comprising a cathode electrode, an anode electrode, and a separator, where N is an integer greater than one. N?1 bipolar plates include a first layer made of a first material, a second layer made of a second material, a center portion, and first and second sides extending transversely relative to the center portion. A battery enclosure including a cover and a lower portion including sides defining a cavity. The N?1 bipolar plates are arranged in the cavity between adjacent ones of the N battery cores and the N battery cores are connected in series by the N?1 bipolar plates. The first and second sides of the N?1 bipolar plates are one of inserted into “L”-shaped slots in the sides of the lower portion, and molded into the sides of the lower portion.

Abstract: A method for fabricating a dual-layer capacitive cabode electrode includes fabricating a first film including capacitive active material; fabricating a second film including cathode active material; hot jointing the first film and the second film to create a cabode film; and laminating the cabode film onto opposite sides of a current collector using conductive adhesive.

Abstract: A bipolar solid-state battery includes N solid-state battery cells. Each of the N solid-state battery cells includes M solid-state cores each comprising a first current collector, cathode active material, a separator, anode active material, and a second current collector, where N and M are integers greater than one. The M solid-state cores are connected in parallel by connecting the first current collectors of the M solid-state cores in each of the N solid-state battery cells together and by connecting the second current collectors of the M solid-state cores in each of the N solid-state battery cells together. N?1 clad plates including a first side made of a first material and a second side made of a second material. The N?1 clad plates are arranged between adjacent ones of the N solid-state battery cells and the N solid-state battery cells are connected in series by the N?1 clad plates.

Abstract: The present disclosure provides an electrochemical device that cycles lithium ions. The electrochemical device includes at least one first cell unit and at least one second cell unit. The at least one first cell unit includes a nickel-rich positive electroactive material. The nickel-rich positive electroactive material can be represented by: LiM1xM2yM3zM4(1-x-y-z)O2 where M1, M2, M3, and M4 are each a transition metal independently selected from the group consisting of: nickel, manganese, cobalt, aluminum, and combinations thereof, where 0?x?1, 0?y?1, and 0?z?1. The at least one second cell unit includes a phosphate-based positive electroactive material. The phosphate-based electroactive material can be selected from the group consisting of: lithium manganese iron phosphates (LiMnxFe1-xPO4, where 0?x?1) (LMFP), lithium vanadium oxygen phosphates (LixVOPO4, where 0?x?1), lithium vanadium phosphates, lithium vanadium fluorophosphates, and combinations thereof.

Abstract: A method of making a capacitor-assisted hybrid electrode for a lithium-ion electrochemical cell includes admixing a solvent, a cellulose-based dispersant, and a plurality of capacitive particles comprising carbon to form a dispersion. The cellulose-based dispersant forms hydrogen bonds with one or more carbonyl-groups on the capacitive particles comprising carbon. The dispersion is combined with an electroactive material, an electrically conductive material, and a binder to form a slurry. The slurry is applied to a current collector and solidified to form the capacitor-assisted hybrid electrode having a composite hybrid active layer on the current collector. Capacitor-assisted hybrid electrodes formed from such methods are also provided.

Abstract: A battery cell includes a plurality of cathodes and a plurality of anodes. A plurality of solid electrolyte layers are arranged between first adjacent ones of the plurality of cathodes and the plurality of anodes. A plurality of clad current collectors are arranged between second adjacent ones of the plurality of cathodes and the plurality of anodes. The plurality of clad current collector includes a first foil layer, a second foil layer and a thermal interface layer including adhesive and at least one material that increases thermal and electrical conductivity of the thermal interface layer.

Abstract: An electrode assembly for an electrochemical cell that cycles lithium ions is provided. The electrode assembly includes one or more electroactive material layers including a plurality of electroactive material particles and a plurality of binder material fibers dispersed with the electroactive material particles. At least one electroactive material particle of the plurality may have a first protective layer coated thereon, and at least one binder material fiber of the plurality may have a second protective layer coated thereon. The first and second protective layers may be the same or different. The binder material fibers can include polytetrafluoroethylene (PTFE).

Abstract: An electrochemical cell that includes a first electrode, a second electrode, and an electrolyte layer that is disposed between the first electrode and the second electrode is provided. The electrolyte layer includes a porous scaffold having a porosity greater than or equal to about 50 vol. % to less than or equal to about 90 vol. %, and a solution-processable solid-state electrolyte that at least partially fills the pores of the porous scaffold. The porous scaffold is defined by a plurality of fibers having an average diameter greater than or equal to about 0.01 micrometer to less than or equal to about 10 micrometers and an average length greater than or equal to about 1 micrometer to less than or equal to about 20 micrometers. The solution-processable solid-state electrolyte includes is selected from the group consisting of: sulfide-based solid-state particles, halide-based solid-state particles, hydride-based solid-state particles, and combinations thereof.

Abstract: A hybridized lithium-ion battery that includes one or more positive electrode assemblies is provided. Each of the one or more positive electrode assemblies includes a positive electrode current collector and one or more positive electroactive material layers disposed on one or more surfaces of the positive electrode current collector. The hybridized lithium-ion battery also includes two or more negative electrode current collectors, and one or more negative electroactive material layers disposed on one or more surfaces of at least one of the two or more negative electrode current collectors, where a total number of the one or more positive electroactive material layers is greater than a total number of negative electroactive material layers. The hybridized lithium-ion battery also includes two or more separating layers physically separating the positive electrode assemblies and the negative electroactive material layers or the positive electrode assemblies and the negative electrode current collectors.

Abstract: A polymer blocker for use in an electrochemical battery that cycles lithium ions is provided. The polymer blocker includes a polymeric layer, a first adhesive layer that includes a first adhesive and is disposed on or near a first surface of the polymeric layer, and a second adhesive layer that includes a second adhesive and is disposed on or near a second surface of the polymeric layer. The polymeric layer has a porosity greater than or equal to about 50 vol. % to less than or equal to about 95 vol. %. A portion of the first adhesive impregnates a first portion of the polymeric layer, and a portion of the second adhesive impregnating a second portion of the polymeric layer. The first and second portions of the polymeric layer may be the same or different.