Abstract: A method for protecting a surface of an article includes preparing or otherwise providing a reactive solution of a form of polyaniline and an acid, thereafter applying the reactive solution to the surface of the article to form an adherent conversion coating on the surface, thereafter oxidizing the adherent conversion coating to form an oxidized coating, and thereafter contacting a chromate-free, corrosion inhibiting organic compound such as a salt of a dithiocarbamate or a salt of a dimercaptothiadiazole to the oxidized coating to form a fixed conversion coating on the surface of the article. The resulting article has the fixed conversion coating adhered to the surface of the article. The fixed conversion coating has a mixture of a reduced polyaniline salt, and a fixed disulfur-linked dithiocarbamate polymer or dimer.

Abstract: The corrosion inhibiting activity of a coating is determined from the effect of corrosion inhibiting species released by the coating on the oxygen reduction current for a cathode placed very close to the coating. A rotating disk electrode or pumped solution flow is used to sweep the corrosion inhibiting species from the coating surface to the cathode. The oxygen reduction current is measured under conditions of oxygen diffusion control.

Abstract: A method is provided for enhancing corrosion resistance of a metal surface that includes the step of forming a sol-gel coating in which nanostructured zinc phosphate (Zn3(PO4)2) and zinc oxide (ZnO) phases are present in the mixture. The method may include the steps of mixing an organosilane, organometallic, organic acid, water, and alcohol, and allowing the components of the mixture to partially hydrolyze, followed by adding at least one component having zinc functionality and at least one component having phosphate functionality to the partially hydrolyzed mixture, wherein the zinc component and phosphate component are added in a molar ratio of from about 1.5:1 to about 5:1 (Zn:PO4). The resulting mixture can be applied as a coating to a metal surface to improve the corrosion resistance of the metal and to enhance the adhesion of resinous materials to the metal surface.

Abstract: A method is provided for enhancing corrosion resistance of a metal surface that includes the step of forming a sol-gel coating in which nanostructured zinc phosphate (Zn3(PO4)2) and zinc oxide (ZnO) phases are present in the mixture. The method may include the steps of mixing an organosilane, organometallic, organic acid, water, and alcohol and allowing the components of the mixture to partially hydrolyze, followed by adding at least one component having zinc functionality and at least one component having phosphate functionality to the partially hydrolyzed mixture, wherein the zinc component and phosphate component are added in a molar ratio of from about 1.5:1 to about 5:1 (Zn:PO4). The resulting mixture can be applied as a coating to a metal surface to improve the corrosion resistance of the metal and to enhance the adhesion of resinous materials to the metal surface.

Abstract: The corrosion inhibiting activity of a coating is determined from the effect of corrosion inhibiting species released by the coating on the oxygen reduction current for a cathode placed very close to the coating. A rotating disk electrode or pumped solution flow is used to sweep the corrosion inhibiting species from the coating surface to the cathode. The oxygen reduction current is measured under conditions of oxygen diffusion control.

Abstract: The corrosion inhibiting activity of a coating is determined from the effect of corrosion inhibiting species released by the coating on the oxygen reduction current for a cathode placed very close to the coating. A rotating disk electrode or pumped solution flow is used to sweep the corrosion inhibiting species from the coating surface to the cathode. The oxygen reduction current is measured under conditions of oxygen diffusion control.