Abstract: The present invention relates to a lithium composite oxide capable of improving capacity and lifetime characteristics of a lithium secondary battery and a lithium secondary battery including the same. According to the present invention, since the atomic ratio of boron (B) and nickel (Ni) in the surface region of the lithium composite oxide including primary particles enabling lithium intercalation and deintercalation and secondary particles formed by aggregating the primary particles is in a specific range, the stability of the lithium composite oxide may be improved, and thus it is possible to improve the capacity and lifetime characteristics of the lithium secondary battery using the lithium composite oxide as a positive electrode active material.

Abstract: A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2?20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2?) of 104 peak in XRD, defined by a hexagonal lattice having R-3m space group, in a range of Formula 1: where M is selected from: B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and any combination thereof, 0.9?a?1.3, 0.6?x?1.0, 0.0?y?=0.4, 0.0?z?0.4, and 0.0?1?x?y?z?0.

Abstract: The present invention relates to a positive electrode active material and a lithium secondary battery using a positive electrode containing the positive electrode active material. More particularly, the present invention relates to a positive electrode active material that is able to solve a problem of increased resistance according to an increase in Ni content by forming a charge transport channel in a lithium composite oxide and a lithium secondary battery using a positive electrode containing the positive electrode active material.

Abstract: A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2?20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2?) of 104 peak in XRD, defined by a hexagonal lattice having R-3m space group, in a range of Formula 1: LiaNixCoyMnzM1-x-y-zO2,??[Chemical Formula 1] where M is selected from: B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and any combination thereof, 0.9?a?1.3, 0.6?x?1.0, 0.0?y?=0.4, 0.0?z?0.4, and 0.0?1-x-y-z?0.4, ?0.025?FWHM(104)?{0.04+(xfirst particle?0.6)×0.25}?0.025,??[Formula 1] where FWHM(104) is represented by Formula 2, FWHM(104)={(FWHMChemical Formula 1 powder(104)?0.1×mass ratio of second particles)/mass ratio of first particles}?FWHMSi powder (220).

Abstract: The present invention relates to a positive electrode active material and a lithium secondary battery using a positive electrode containing the positive electrode active material. More particularly, the present invention relates to a positive electrode active material that is able to solve a problem of increased resistance according to an increase in Ni content by forming a charge transport channel in a lithium composite oxide and a lithium secondary battery using a positive electrode containing the positive electrode active material.

Abstract: The present invention relates to a positive electrode active material and a lithium secondary battery using a positive electrode comprising the same, and more particularly, to a positive electrode active material which has improved electrochemical properties and improved stability by controlling a pore area and a pore shape of a lithium composite oxide included in the positive electrode active material by adjusting the proportions of ammonia and caustic soda, used in co-precipitation for synthesizing a precursor of the positive electrode active material, and a lithium secondary battery using a positive electrode containing the positive electrode active material.

Abstract: The present invention relates to a method of preparing a positive electrode active material for a lithium secondary battery, and more particularly, to a method of preparing a positive electrode active material for a lithium secondary battery, which is able to improve electrochemical properties and stability by controlling the specific surface area of a positive electrode active material.

Abstract: A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2?20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2?) of 104 peak in XRD, defined by a hexagonal lattice having R-3m space group, in a range of Formula 1: LiaNixCoyMnzM1-x-y-zO2, ??[Chemical Formula 1] where M is selected from: B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and any combination thereof, 0.9?a?1.3, 0.6?x?1.0, 0.0?y?=0.4, 0.0?z?0.4, and 0.0?1-x-y-z?0.4, ?0.025?FWHM(104)?{0.04+(xfirst particle?0.6)×0.25}?0.025, ??[Formula 1] where FWHM(104) is represented by Formula 2, FWHM(104)={(FWHMChemical Formula 1 powder(104)?0.1×mass ratio of second particles)/mass ratio of first particles}?FWHMSi powder (220).

Abstract: A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2?20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2?) of 104 peak in XRD, defined by a hexagonal lattice having R-3m space group, in a range of Formula 1: LiaNixCoyMnzM1-x-y-zO2,??[Chemical Formula 1] where M is selected from: B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and any combination thereof, 0.9?a?1.3, 0.6?x?1.0, 0.0?y?=0.4, 0.0?z?0.4, and 0.0?1?x?y?z?0.4, ?0.025?FWHM(104)?{0.04+(xfirst particle?0.6)×0.25}?0.025,??[Formula 1] where FWHM(104) is represented by Formula 2, FWHM(104)={(FWHMChemical Formula 1 powder(104)?0.1×mass ratio of second particles)/mass ratio of first particles}?FWHMSi powder(220).

Abstract: The present invention relates to a lithium composite oxide capable of improving capacity and lifetime characteristics of a lithium secondary battery and a lithium secondary battery including the same. According to the present invention, since the atomic ratio of boron (B) and nickel (Ni) in the surface region of the lithium composite oxide including primary particles enabling lithium intercalation and deintercalation and secondary particles formed by aggregating the primary particles is in a specific range, the stability of the lithium composite oxide may be improved, and thus it is possible to improve the capacity and lifetime characteristics of the lithium secondary battery using the lithium composite oxide as a positive electrode active material.

Abstract: A lithium complex oxide includes a mixture of first particles of n1 (n1>40) aggregated primary particles and second particles of n2 (n2?20) aggregated primary particles, the lithium complex oxide represented by Chemical Formula 1 and having FWHM (deg., 2?) of 104 peak in XRD, defined by a hexagonal lattice having R-3m space group, in a range of Formula 1: LiaNixCoyMnzM1-x-y-zO2,??[Chemical Formula 1] where M is selected from: B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and any combination thereof, 0.9?a?1.3, 0.6?x?1.0, 0.0?y?=0.4, 0.0?z?0.4, and 0.0?1?x?y?z?0.4, ?0.025?FWHM(104)?{0.04+(xfirst particle?0.6)×0.25}?0.025,??[Formula 1] where FWHM(104) is represented by Formula 2, FWHM(104)={(FWHMChemical Formula 1 powder(104)?0.1×mass ratio of second particles)/mass ratio of first particles}?FWHMSi powder(220).

Abstract: The present invention relates to a positive electrode active material and a lithium secondary battery using a positive electrode containing the positive electrode active material. More particularly, the present invention relates to a positive electrode active material that is able to solve a problem of increased resistance according to an increase in Ni content by forming a charge transport channel in a lithium composite oxide and a lithium secondary battery using a positive electrode containing the positive electrode active material.

Abstract: The present invention relates to a lithium composite oxide including a coating layer having a boron-containing oxide and a lithium secondary battery including the same. More particularly, the present invention relates to a lithium composite oxide improved in lifetime and capacity characteristics by inducing a predetermined correlation between the molar ratio of nickel in a lithium composite oxide including a coating layer having a boron-containing oxide and a full width at half-maximum (FWHM; deg., 2?) of a (104) peak among XRD peaks defined by the hexagonal lattice with an R-3m space group, and a lithium secondary battery including the same.

Abstract: In an embodiment of the present invention, a positive active material for a lithium secondary battery is represented by Formula 1, and includes a core including a compound having a core portion and a surface portion, and the compound has a lower L3/L2 intensity ratio of Ni in the surface portion than an L3/L2 intensity ratio of Ni in the core portion. Li[LizA(1-z-a)Da]EbO2-b??[Formula 1] (In the above formula (1), A is Ni?Co?Mn?, D is at least one element selected from the group consisting of Na, K, Mg, Ca, Sr, Ni, Co, Ti, Al, B, Si, Sn, Mn, Cr, Fe, V, Zr, Nb, and Mo, E is at least one element selected from the group consisting of P, F, and S, ?0.05?z?0.1, 0?a?0.05, 0?b?0.05, 0.3???0.9, 0.05???0.4, and 0.05???0.4.) (The L3/L2 intensity ratio of Ni is the oxidation number of Ni measured by electronic energy loss spectroscopy (EELS).).

Abstract: In an embodiment of the present invention, a positive active material for a lithium secondary battery is represented by Formula 1, and includes a core including a compound having a core portion and a surface portion, and the compound has a lower L3/L2 intensity ratio of Ni in the surface portion than an L3/L2 intensity ratio of Ni in the core portion. Li[LizA(1-z-a)Da]EbO2-b ??[Formula 1] (In the above formula (1), A is Ni?Co?Mn?, D is at least one element selected from the group consisting of Na, K, Mg, Ca, Sr, Ni, Co, Ti, Al, B, Si, Sn, Mn, Cr, Fe, V, Zr, Nb, and Mo, E is at least one element selected from the group consisting of P, F, and S, ?0.05?z?0.1, 0?a?0.05, 0?b?0.05, 0.3???0.9, 0.05???0.4, and 0.05???0.4.) (The L3/L2 intensity ratio of Ni is the oxidation number of Ni measured by electronic energy loss spectroscopy (EELS).