Abstract: A hydrogen-generating device is provided, wherein a first substrate includes a liquid container and a first gas container at a first side thereof, and the first substrate sequentially includes a first and second liquid diffusion area and a diverging channel area from the liquid container to the first gas container. The first and second liquid diffusion areas respectively have a plurality of liquid diffusion structures, and the diverging channel area has a plurality of diverging channels. A laminate covers the first side of the first substrate and includes a liquid feed inlet connected to the liquid container. The first side of a second substrate covers the second side of the first substrate and includes a second gas container and a gas reaction channel located at the first side. A catalyst is disposed in the gas reaction channel and a heater is disposed on the second side of the second substrate.