Patents by Inventor Michael A. Kryzman

Michael A. Kryzman has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11624121
    Abstract: Disclosed is a solution composition which may be used for a single-bath electrochemical passivation and a method using the same. The solution composition includes a metal cation, a metal-oxide anion; and an organic ligand, and optionally includes a non-metallic oxide anion or a polymer. The solution composition may prevent undesired precipitation of metal oxides before performing passivation. In addition, the method of passivation using the solution composition in a single-bath use is also provided.
    Type: Grant
    Filed: February 14, 2020
    Date of Patent: April 11, 2023
    Assignee: RAYTHEON TECHNOLOGIES CORPORATION
    Inventors: Weilong Zhang, Michael A. Kryzman
  • Patent number: 11613813
    Abstract: Disclosed is a corrosion inhibition coating, comprising: a base comprising a silicate matrix, wherein aluminum, an aluminum alloy, or a combination thereof, is present within the silicate matrix; and an inhibitor comprising: zinc molybdate, cerium citrate, magnesium metasilicate, a metal phosphate silicate, or a combination thereof, wherein a curing temperature of the corrosion inhibition coating is about 20° C. to about 190° C., preferably about 20° C. to about 120° C. Also disclosed is a substrate coated with the corrosion inhibition coating, wherein the substrate is a peened part.
    Type: Grant
    Filed: April 2, 2020
    Date of Patent: March 28, 2023
    Assignee: HAMILTON SUNDSTRAND CORPORATION
    Inventors: Tianli Zhu, Weilong Zhang, Michael A. Kryzman, Blair A. Smith, Georgios S. Zafiris, Olivier Brucelle
  • Publication number: 20220195604
    Abstract: Disclosed is a phosphate coating, comprising: a phosphate portion, wherein the phosphate portion comprises pores, wherein the pores are at least partially filled with a corrosion inhibition sealant, wherein the corrosion inhibition sealant comprises: a base, wherein the base comprises a matrix and a metal within the matrix, wherein the metal within the matrix comprises aluminum, an aluminum alloy, zinc, a zinc alloy, magnesium, a magnesium alloy, or a combination thereof and an inhibitor mixed within the base, wherein the inhibitor comprises zinc molybdate, magnesium metasilicate, trivalent chromium, tungstenate, a metal phosphate silicate, or a combination thereof.
    Type: Application
    Filed: December 23, 2020
    Publication date: June 23, 2022
    Inventors: Blair A. Smith, Steven Poteet, Vijay V. Pujar, Georgios S. Zafiris, Weilong Zhang, Michael A. Kryzman
  • Patent number: 11149353
    Abstract: A method of disposing a corrosion resistant system to a substrate may comprise applying a plating material to the substrate; forming a chemical conversion coating solution by combining a solvent, at least one corrosion inhibitive cation comprising at least one of zinc, calcium, strontium, magnesium, or aluminum, at least one corrosion inhibitive anion comprising at least one of phosphate, molybdate, or silicate, and a complexing agent; and applying the chemical conversion coating solution to the plating material on the substrate.
    Type: Grant
    Filed: September 25, 2019
    Date of Patent: October 19, 2021
    Assignee: Goodrich Corporation
    Inventors: Michael A. Kryzman, Georgios S. Zafiris, Mark R. Jaworowski, Weilong Zhang, Roque Panza-Giosa, Marilea Manzini
  • Patent number: 11091840
    Abstract: A corrosion resistant article including an aluminum substrate and a corrosion-inhibiting cerium based corrosion inhibitor corrosion inhibiting additive on the aluminum substrate, the corrosion inhibiting additive comprising an anodic corrosion inhibitor and a cathodic corrosion inhibitor, the anodic corrosion inhibitor greater than 25 wt % of the total inhibitor.
    Type: Grant
    Filed: July 16, 2018
    Date of Patent: August 17, 2021
    Assignee: Raytheon Technologies Corporation
    Inventors: Zhongfen (Vivian) Ding, Georgios S. Zafiris, Weilong Zhang, Michael A. Kryzman, Catalin G. Fotache, Mark R. Jaworowski
  • Patent number: 10829647
    Abstract: Disclosed is a corrosion inhibition coating, comprising: a base comprising a matrix and a metal within the matrix; and an inhibitor comprising: zinc molybdate, cerium citrate, magnesium metasilicate, a metal phosphate silicate, or a combination thereof, wherein the metal within the matrix comprises aluminum, an aluminum alloy, zinc, a zinc alloy, magnesium, a magnesium alloy, or a combination thereof. Also disclosed is a substrate coated with the corrosion inhibition coating.
    Type: Grant
    Filed: December 11, 2018
    Date of Patent: November 10, 2020
    Assignee: HAMILTON SUNSTRAND CORPORATION
    Inventors: Tianli Zhu, Blair A. Smith, Weilong Zhang, Michael A. Kryzman, Georgios S. Zafiris, Bart Antonie van Hassel
  • Patent number: 10801123
    Abstract: A method of coating a metal article is disclosed that includes immersing a metal article having an exterior anodized layer in a bath containing a chemically active corrosion inhibitor, and applying a voltage to the article during the immersing, the voltage driving the chemically active corrosion inhibitor from the bath into the exterior anodized layer. An article is also disclosed that has a substrate comprising a metal, and a porous anodized layer formed on an exterior surface of the substrate that is infiltrated with a chemically active corrosion inhibitor, the anodized layer having an inward-facing region and an outward-facing region, the anodized layer having a greater concentration of chemically active corrosion inhibitors in the inward-facing region than in the outward-facing region.
    Type: Grant
    Filed: March 27, 2017
    Date of Patent: October 13, 2020
    Assignee: RAYTHEON TECHNOLOGIES CORPORATION
    Inventors: Zhongfen Ding, Robert R. Hebert, Weilong Zhang, Bart Antonie van Hassel, Mark R. Jaworowski, Michael A. Kryzman, Blair A. Smith, Georgios S. Zafiris, Promila Bhaatia, Mark A. Brege, Shaahin Amini, Vijay V. Pujar
  • Publication number: 20200318244
    Abstract: Disclosed is a corrosion inhibition coating, comprising: a base comprising a silicate matrix, wherein aluminum, an aluminum alloy, or a combination thereof, is present within the silicate matrix; and an inhibitor comprising: zinc molybdate, cerium citrate, magnesium metasilicate, a metal phosphate silicate, or a combination thereof, wherein a curing temperature of the corrosion inhibition coating is about 20° C. to about 190° C., preferably about 20° C. to about 120° C. Also disclosed is a substrate coated with the corrosion inhibition coating, wherein the substrate is a peened part.
    Type: Application
    Filed: April 2, 2020
    Publication date: October 8, 2020
    Inventors: Tianli Zhu, Weilong Zhang, Michael A. Kryzman, Blair A. Smith, Georgios S. Zafiris, Olivier Brucelle
  • Publication number: 20200232113
    Abstract: Disclosed is a solution composition which may be used for a single-bath electrochemical passivation and a method using the same. The solution composition includes a metal cation, a metal-oxide anion; and an organic ligand, and optionally includes a non-metallic oxide anion or a polymer. The solution composition may prevent undesired precipitation of metal oxides before performing passivation. In addition, the method of passivation using the solution composition in a single-bath use is also provided.
    Type: Application
    Filed: February 14, 2020
    Publication date: July 23, 2020
    Inventors: Weilong Zhang, Michael A. Kryzman
  • Publication number: 20200181424
    Abstract: Disclosed is a corrosion inhibition coating, comprising: a base comprising a matrix and a metal within the matrix; and an inhibitor comprising: zinc molybdate, cerium citrate, magnesium metasilicate, a metal phosphate silicate, or a combination thereof, wherein the metal within the matrix comprises aluminum, an aluminum alloy, zinc, a zinc alloy, magnesium, a magnesium alloy, or a combination thereof. Also disclosed is a substrate coated with the corrosion inhibition coating.
    Type: Application
    Filed: December 11, 2018
    Publication date: June 11, 2020
    Inventors: Tianli Zhu, Blair A. Smith, Weilong Zhang, Michael A. Kryzman, Georgios S. Zafiris, Bart Antonie van Hassel
  • Publication number: 20200148895
    Abstract: In one aspect, a coating for protecting a component exposed to a corrosive environment includes an epoxy phenolic resin, a non-chromated corrosion inhibitor pigment additive and a dispersing agent. In another aspect, a method of protecting an article exposed to a corrosive environment includes applying a corrosion-resistant epoxy phenolic coating to a surface of the article exposed to a corrosive environment and curing the corrosion-resistant epoxy phenolic coating. The epoxy phenolic coating contains up to 15 percent by volume of a non-chromated corrosion inhibitor pigment additive having a particle size less than 10 micrometers.
    Type: Application
    Filed: November 9, 2018
    Publication date: May 14, 2020
    Inventors: Michael E. Folsom, Krystyna Kapalczynski, Sean C. Emerson, Michael A. Kryzman, Weilong Zhang, Thomas F. Pinkerman, Georgios S. Zafiris
  • Publication number: 20200063284
    Abstract: A sealing process includes applying a first reactant to a substrate having a porous structure, the first reactant comprising a chromium (III) precursor and a transition metal precursor and applying a second reactant to the first reactant, the second reactant comprising a rare earth element precursor and an alkaline earth element precursor to form reservoirs of trivalent chromium in pore space of the porous structure, and a physical barrier over the substrate and the reservoirs.
    Type: Application
    Filed: October 29, 2019
    Publication date: February 27, 2020
    Inventors: Bart Antonie van Hassel, Georgios S. Zafiris, Zhongfen Ding, Michael A. Kryzman, Mark R. Jaworowski, Weina Li, Blair A. Smith, Weilong Zhang, Promila Bhaatia
  • Patent number: 10563317
    Abstract: Disclosed is a solution composition which may be used for a single-bath electrochemical passivation and a method using the same. The solution composition includes a metal cation, a metal-oxide anion; and an organic ligand, and optionally includes a non-metallic oxide anion or a polymer. The solution composition may prevent undesired precipitation of metal oxides before performing passivation. In addition, the method of passivation using the solution composition in a single-bath use is also provided.
    Type: Grant
    Filed: May 31, 2018
    Date of Patent: February 18, 2020
    Assignee: UNITED TECHNOLOGIES CORPORATION
    Inventors: Weilong Zhang, Michael A. Kryzman
  • Publication number: 20200017975
    Abstract: A method of disposing a corrosion resistant system to a substrate may comprise applying a plating material to the substrate; forming a chemical conversion coating solution by combining a solvent, at least one corrosion inhibitive cation comprising at least one of zinc, calcium, strontium, magnesium, or aluminum, at least one corrosion inhibitive anion comprising at least one of phosphate, molybdate, or silicate, and a complexing agent; and applying the chemical conversion coating solution to the plating material on the substrate.
    Type: Application
    Filed: September 25, 2019
    Publication date: January 16, 2020
    Applicant: GOODRICH CORPORATION
    Inventors: Michael A. Kryzman, Georgios S. Zafiris, Mark R. Jaworowski, Weilong Zhang, Roque Panza-Giosa, Marilea Manzini
  • Patent number: 10480093
    Abstract: A sealing process includes applying a first reactant to a substrate having a porous structure, the first reactant comprising a chromium (III) precursor and a transition metal precursor and applying a second reactant to the first reactant, the second reactant comprising a rare earth element precursor and an alkaline earth element precursor to form reservoirs of trivalent chromium in pore space of the porous structure, and a physical barrier over the substrate and the reservoirs.
    Type: Grant
    Filed: May 12, 2017
    Date of Patent: November 19, 2019
    Assignee: UNITED TECHNOLOGIES CORPORATION
    Inventors: Bart Antonie van Hassel, Georgios S. Zafiris, Zhongfen Ding, Michael A. Kryzman, Mark R. Jaworowski, Weina Li, Blair A. Smith, Weilong Zhang, Promila Bhaatia
  • Patent number: 10479896
    Abstract: A corrosion inhibition composition is disclosed comprising a zinc oxide, a zinc phosphate, a calcium silicate, an aluminum phosphate, a zinc calcium strontium aluminum orthophosphate silicate hydrate, a molybdate compound, a silicate compound, and a zinc phthalate compound.
    Type: Grant
    Filed: February 21, 2019
    Date of Patent: November 19, 2019
    Assignee: GOODRICH CORPORATION
    Inventors: Michael A. Kryzman, Georgios S. Zafiris, Mark R. Jaworowski, Weilong Zhang, Roque Panza-Giosa, Marilea Manzini
  • Patent number: 10465292
    Abstract: A method of disposing a corrosion resistant system to a substrate may comprise applying a plating material to the substrate; forming a chemical conversion coating solution by combining a solvent, at least one corrosion inhibitive cation comprising at least one of zinc, calcium, strontium, magnesium, or aluminum, at least one corrosion inhibitive anion comprising at least one of phosphate, molybdate, or silicate, and a complexing agent; and applying the chemical conversion coating solution to the plating material on the substrate.
    Type: Grant
    Filed: October 7, 2016
    Date of Patent: November 5, 2019
    Assignee: GOODRICH CORPORATION
    Inventors: Michael A. Kryzman, Georgios S. Zafiris, Mark R. Jaworowski, Weilong Zhang, Roque Panza-Giosa, Marilea Manzini
  • Publication number: 20190233943
    Abstract: A coated substrate made by a method that includes pre-treating a metal substrate, immersing the metal substrate in a trivalent chromium bath which does not contain hexavalent chromium, post-treating the coated metal substrate with an oxidizer, and curing the coated metal substrate in a controlled environment.
    Type: Application
    Filed: April 5, 2019
    Publication date: August 1, 2019
    Inventors: Mark R. Jaworowski, Blair A. Smith, Georgios S. Zafiris, Weilong Zhang, Michael A. Kryzman, Theresa A. Hugener
  • Publication number: 20190185680
    Abstract: A corrosion inhibition composition is disclosed comprising a zinc oxide, a zinc phosphate, a calcium silicate, an aluminum phosphate, a zinc calcium strontium aluminum orthophosphate silicate hydrate, a molybdate compound, a silicate compound, and a zinc phthalate compound.
    Type: Application
    Filed: February 21, 2019
    Publication date: June 20, 2019
    Applicant: Goodrich Corporation
    Inventors: Michael A. Kryzman, Georgios S. Zafiris, Mark R. Jaworowski, Weilong Zhang, Roque Panza-Giosa, Marilea Manzini
  • Patent number: 10294570
    Abstract: A method for making an environmentally-safe chromium based corrosion resistant coating includes pre-treating a metal substrate, immersing the metal substrate in a trivalent chromium bath which does not contain hexavalent chromium, post-treating the coated metal substrate with an oxidizer, and curing the coated metal substrate in a controlled environment.
    Type: Grant
    Filed: April 11, 2016
    Date of Patent: May 21, 2019
    Assignee: Hamilton Sundstrand Corporation
    Inventors: Mark R. Jaworowski, Blair A. Smith, Georgios S. Zafiris, Weilong Zhang, Michael A. Kryzman, Treese Hugener-Campbell, Bart Antonie van Hassel