Patents by Inventor Michael Alexandre

Michael Alexandre has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9290676
    Abstract: The present invention concerns a fireproof composition consisting of reticulated polysiloxane and raw carbon nanotubes with a “bound rubber” value greater than or equal to 15 grams of carbon nanotube, said carbon nanotubes representing between 0.05 and 1% of the total weight of said composition.
    Type: Grant
    Filed: November 20, 2012
    Date of Patent: March 22, 2016
    Assignee: Nanocyl S.A.
    Inventors: Michael Alexandre, Philippe Dubois, Myriam Devalckenaere, Michael Claes
  • Patent number: 9249253
    Abstract: The process of obtaining a polylactide-urethane copolymer is described which includes contacting an ?, ? dihydroxyl polylactide prepolymer of general formula I wherein X is NH or O, R is an alkyl or an aryl group, n and n? are integer numbers which are substantially the same and are in the range from 20 to 140, with a diisocyanate compound of general formula II O?C?N—R?—N?C?O wherein R? is an alkyl or an aryl group and with an amine or an alcohol of general formula III R?X?]2 wherein R? is an alkyl or an aryl group and X? is NH2 or OH, and with the proviso that at least one of R or R? is an aryl group.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: February 2, 2016
    Assignee: FUTERRO S.A.
    Inventors: Philippe Dubois, Philippe Coszach, Gloria Vendrell, Philippe Degee, Michael Alexandre, Ibrahim Barakat, Jean Marie Raquez
  • Patent number: 8119713
    Abstract: A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: February 21, 2012
    Assignees: Materia Nova, Ecole Nationale Superieure de Chimie de Lillie, Ecole Nationale Superieure des Arts et Industries Textiles
    Inventors: Philippe Dubois, Marius Murariu, Michael Alexandre, Philippe Degee, Serge Bourbigot, Rene Delobel, Gaelle Fontaine, Eric Devaux
  • Patent number: 7968660
    Abstract: This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: June 28, 2011
    Assignee: Nanocyl S.A.
    Inventors: Philippe Dubois, Michael Alexandre, Daniel Bonduel, Michael Mainil
  • Publication number: 20110021651
    Abstract: The invention relates to a method for making a fireproof polymer foam, and to a fireproof polymer foam containing a mixture of a polymer composition containing one or more optionally-substituted, sequenced or random, thermoplastic and/or elastomer homopolymers, copolymers or mixtures thereof, from 0.05 to 10 wt %, preferably from 0.5 to 5 wt %, relative to the mixture, of carbon nanotubes, and from 0.05 to 15 wt %, preferably from 0.5 to 10 wt %, relative to the mixture, of red phosphorus.
    Type: Application
    Filed: January 23, 2009
    Publication date: January 27, 2011
    Applicant: NMC S.A.
    Inventors: Jean-Pierre Mayeres, Denis Job, Leila Bonnaud, Michael Alexandre, Philippe Dubois, Fouad Laoutid
  • Publication number: 20100184894
    Abstract: A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.
    Type: Application
    Filed: February 1, 2008
    Publication date: July 22, 2010
    Applicants: Materia Nova, Ecole Nationale Superieure De Chimie de Lille, Ecole Nationale Superieure des Arts et Industries Textiles
    Inventors: Philippe Dubois, Marius Murariu, Michael Alexandre, Philippe Degee, Serge Bourbigot, Rene Delobel, Gaelle Fontaine, Eric Devaux
  • Publication number: 20100113734
    Abstract: A process for producing polylactide-urethane copolymers, which comprises the step of contacting a polylactide having terminal hydroxyl groups, produced by contacting at least one lactide monomer with a diol or diamine, with a diisocyanate compound optionally in the presence of a second diol or diamine in the presence of a catalytic system under polymerisation conditions characterised in that the polylactide and the polylactide-urethane copolymers are produced by reactive extrusion.
    Type: Application
    Filed: September 27, 2007
    Publication date: May 6, 2010
    Applicants: TOTAL PETROCHEMICALS RESEARCH FELUY, FUTERRO S.A.
    Inventors: Philippe Dubois, Philippe Coszach, Gloria Vendrell, Fabrice Stassin, Caroline Jourdanne, Luc Lienard, Philippe Degee, Ibrahim Barakat, Michael Alexandre, Jean Marie Raquez
  • Publication number: 20100016538
    Abstract: A polylactide-urethane copolymer obtainable by a process, which comprises the step of contacting: an ?, ? dihydroxyl polylactide prepolymer of general formula I wherein: X is NH or O, R is an alkyl or an aryl group, n and n? are integer numbers which are substantially the same and which are comprised in the range from 20 to 140, a diisocyanate compound of general formula II O?C?N—R?—N?C?O wherein: R? is an alkyl or an aryl group and an amine or an alcohol of general formula III R??[X?]2 wherein: R? is an alkyl or an aryl group and X? is NH2 or OH with the proviso that at least one of R or R? is an aryl group
    Type: Application
    Filed: September 27, 2007
    Publication date: January 21, 2010
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Philippe Dubois, Philippe Coszach, gloria Vendrell, Philippe Degee, Michael Alexandre, Ibrahim Barakat, Jean Marie Raquez
  • Publication number: 20090298994
    Abstract: This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.
    Type: Application
    Filed: June 10, 2009
    Publication date: December 3, 2009
    Applicant: Nanocyl S.A.
    Inventors: Philippe Dubois, Michael Alexandre, Daniel Bonduel, Michael Mainil
  • Patent number: 7550543
    Abstract: The invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a cocatalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in the field of polymers, especially that of nanotechnologies.
    Type: Grant
    Filed: August 5, 2004
    Date of Patent: June 23, 2009
    Assignee: S.A. Nanocyl
    Inventors: Philippe Dubois, Michael Alexandre, Daniel Bonduel, Michael Mainil
  • Publication number: 20080293877
    Abstract: The present invention concerns a fireproof composition consisting of reticulated polysiloxane and raw carbon nanotubes with a “bound rubber” value greater than or equal to 15 grams of carbon nanotube, said carbon nanotubes representing between 0.05 and 1% of the total weight of said composition.
    Type: Application
    Filed: October 3, 2006
    Publication date: November 27, 2008
    Inventors: Michael Alexandre, Philippe Dubois, Myriam Devalckenaere, Michael Claes
  • Publication number: 20080207824
    Abstract: The invention concerns a method for dispersing carbon nanotubes in a polymer matrix including a step of preparing carbon nanotubes coated with a polymer coating by a method for polymerizing a monomer using a catalytic system wherein carbon nanotubes are used as catalytic support, the carbon nanotubes comprising in surface the catalytic system for polymerizing the coating polymer, and the coating polymer being non-miscible in the host polymer matrix, followed by a step of hot process mixing of the coated carbon nanotubes with a polymer matrix.
    Type: Application
    Filed: May 24, 2006
    Publication date: August 28, 2008
    Applicant: Nanocyl S.A
    Inventors: Michael Alexandre, Daniel Bonduel, Michael Claes, Dubois Philippe, Sophie Peeterbroeck, Sven Pegel, Petra Potschke
  • Publication number: 20070184969
    Abstract: The invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a cocatalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in the field of polymers, especially that of nanotechnologies.
    Type: Application
    Filed: August 5, 2004
    Publication date: August 9, 2007
    Applicant: S.A. NANOCYL
    Inventors: Phillippe Dubois, Michael Alexandre, Daniel Bonduel, Mainil Michael
  • Publication number: 20050154116
    Abstract: The present invention is related to nanocomposites comprising polymers, carbon nanotubes and layered silicate nanoparticles. The present invention also concerns methods for obtaining said nanocomposites as well as their uses.
    Type: Application
    Filed: March 20, 2003
    Publication date: July 14, 2005
    Inventors: Janos Nagy, Christophe Pirlot, Antonio Fonseca, Gregory Philippin, Joseph Delhalle, Zineb Mekhalif, Robert Sporken, Philippe Dubois, Michael Alexandre, Gunter Beyer
  • Publication number: 20040106720
    Abstract: The invention relates to a method for preparing nanocomposite aliphatic polyester consisting of the mixing of a nanofiller in at least one monomer that can form an aliphatic polyester and the intercalative polymerisation of the mixture obtained in the presence of a supercritical fluid.
    Type: Application
    Filed: December 30, 2003
    Publication date: June 3, 2004
    Inventors: Robert Jerome, Cedric Calberg, Fabrice Stassin, Olivier Helleux, Philippe Dubois, Nadege Pantoustier, Michael Alexandre, Benedicte Lepoittevin
  • Patent number: 6465543
    Abstract: The present invention is a nanocomposite which is a dispersion of nanofiller particles derived from layered metal oxides or metal oxide salts. The nanocomposite is advantageously prepared by first swelling an untreated clay in water, then removing the water to form an organophilic clay that is dispersible in non-polar organic solvents. The organophilic clay can then be treated with an alkyl aluminoxane and subsequently a catalyst to form a complex that promotes olefin or styrenic polymerization and platelet dispersion. The nanocomposite can be prepared directly by in situ polymerization of the olefin or the styrene at the nanofiller particles without shear, without an ion exchange step, and without the need to incorporate polar substituents into the polyolefin or polystyrene.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: October 15, 2002
    Assignee: The Dow Chemical Company
    Inventors: Michael Alexandre, Philippe G. Dubois, Robert J. E. G. Jerome, Miguel Garcia-Marti, Tao Sun, Juan M. Garces, Dean M. Millar, Alexander Kuperman
  • Patent number: 6207775
    Abstract: The present invention relates to a process for preparing a filled polymer composite comprising from 1 to 98 percent by weight of an interpolymer and from 2 to 99 percent by weight of a filler, said process comprising copolymerization in the presence of a cyclopentadienyl-containing transition metal catalyst and a filler, said filler having immobilized thereon a suitable cocatalyst.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: March 27, 2001
    Assignee: The Dow Chemical Company
    Inventors: Miguel García Martí, Michael Alexandre, Philippe G. Dubois, Robert J. E. G. Jérô ;me, François J. Hindryckx