Patents by Inventor Michael Alexandre
Michael Alexandre has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9290676Abstract: The present invention concerns a fireproof composition consisting of reticulated polysiloxane and raw carbon nanotubes with a “bound rubber” value greater than or equal to 15 grams of carbon nanotube, said carbon nanotubes representing between 0.05 and 1% of the total weight of said composition.Type: GrantFiled: November 20, 2012Date of Patent: March 22, 2016Assignee: Nanocyl S.A.Inventors: Michael Alexandre, Philippe Dubois, Myriam Devalckenaere, Michael Claes
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Patent number: 9249253Abstract: The process of obtaining a polylactide-urethane copolymer is described which includes contacting an ?, ? dihydroxyl polylactide prepolymer of general formula I wherein X is NH or O, R is an alkyl or an aryl group, n and n? are integer numbers which are substantially the same and are in the range from 20 to 140, with a diisocyanate compound of general formula II O?C?N—R?—N?C?O wherein R? is an alkyl or an aryl group and with an amine or an alcohol of general formula III R?X?]2 wherein R? is an alkyl or an aryl group and X? is NH2 or OH, and with the proviso that at least one of R or R? is an aryl group.Type: GrantFiled: September 27, 2007Date of Patent: February 2, 2016Assignee: FUTERRO S.A.Inventors: Philippe Dubois, Philippe Coszach, Gloria Vendrell, Philippe Degee, Michael Alexandre, Ibrahim Barakat, Jean Marie Raquez
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Patent number: 8119713Abstract: A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.Type: GrantFiled: February 1, 2008Date of Patent: February 21, 2012Assignees: Materia Nova, Ecole Nationale Superieure de Chimie de Lillie, Ecole Nationale Superieure des Arts et Industries TextilesInventors: Philippe Dubois, Marius Murariu, Michael Alexandre, Philippe Degee, Serge Bourbigot, Rene Delobel, Gaelle Fontaine, Eric Devaux
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Patent number: 7968660Abstract: This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.Type: GrantFiled: June 10, 2009Date of Patent: June 28, 2011Assignee: Nanocyl S.A.Inventors: Philippe Dubois, Michael Alexandre, Daniel Bonduel, Michael Mainil
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Publication number: 20110021651Abstract: The invention relates to a method for making a fireproof polymer foam, and to a fireproof polymer foam containing a mixture of a polymer composition containing one or more optionally-substituted, sequenced or random, thermoplastic and/or elastomer homopolymers, copolymers or mixtures thereof, from 0.05 to 10 wt %, preferably from 0.5 to 5 wt %, relative to the mixture, of carbon nanotubes, and from 0.05 to 15 wt %, preferably from 0.5 to 10 wt %, relative to the mixture, of red phosphorus.Type: ApplicationFiled: January 23, 2009Publication date: January 27, 2011Applicant: NMC S.A.Inventors: Jean-Pierre Mayeres, Denis Job, Leila Bonnaud, Michael Alexandre, Philippe Dubois, Fouad Laoutid
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Publication number: 20100184894Abstract: A polylactide-based polymer or copolymer (PLA) compositions with improved flame retardancy properties as obtained by conventional melt-blending of PLA polyester matrix (1) with both calcium sulfate (2) and organo-modified layered silicates (OMLS) (3). Combination of CaSO4 and OMLS exhibits synergistic effects on PLA flame retardancy by both significantly increasing the time to ignition and decreasing the heat release rate per unit area, and promoting non-dripping properties. Moreover, all other properties of PLA remain almost unchanged or are improved as regards to pristine PLA, especially thermal and mechanical properties.Type: ApplicationFiled: February 1, 2008Publication date: July 22, 2010Applicants: Materia Nova, Ecole Nationale Superieure De Chimie de Lille, Ecole Nationale Superieure des Arts et Industries TextilesInventors: Philippe Dubois, Marius Murariu, Michael Alexandre, Philippe Degee, Serge Bourbigot, Rene Delobel, Gaelle Fontaine, Eric Devaux
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Publication number: 20100113734Abstract: A process for producing polylactide-urethane copolymers, which comprises the step of contacting a polylactide having terminal hydroxyl groups, produced by contacting at least one lactide monomer with a diol or diamine, with a diisocyanate compound optionally in the presence of a second diol or diamine in the presence of a catalytic system under polymerisation conditions characterised in that the polylactide and the polylactide-urethane copolymers are produced by reactive extrusion.Type: ApplicationFiled: September 27, 2007Publication date: May 6, 2010Applicants: TOTAL PETROCHEMICALS RESEARCH FELUY, FUTERRO S.A.Inventors: Philippe Dubois, Philippe Coszach, Gloria Vendrell, Fabrice Stassin, Caroline Jourdanne, Luc Lienard, Philippe Degee, Ibrahim Barakat, Michael Alexandre, Jean Marie Raquez
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Publication number: 20100016538Abstract: A polylactide-urethane copolymer obtainable by a process, which comprises the step of contacting: an ?, ? dihydroxyl polylactide prepolymer of general formula I wherein: X is NH or O, R is an alkyl or an aryl group, n and n? are integer numbers which are substantially the same and which are comprised in the range from 20 to 140, a diisocyanate compound of general formula II O?C?N—R?—N?C?O wherein: R? is an alkyl or an aryl group and an amine or an alcohol of general formula III R??[X?]2 wherein: R? is an alkyl or an aryl group and X? is NH2 or OH with the proviso that at least one of R or R? is an aryl groupType: ApplicationFiled: September 27, 2007Publication date: January 21, 2010Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventors: Philippe Dubois, Philippe Coszach, gloria Vendrell, Philippe Degee, Michael Alexandre, Ibrahim Barakat, Jean Marie Raquez
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Publication number: 20090298994Abstract: This invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a co-catalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in a field of polymers, especially that of nanotechnologies.Type: ApplicationFiled: June 10, 2009Publication date: December 3, 2009Applicant: Nanocyl S.A.Inventors: Philippe Dubois, Michael Alexandre, Daniel Bonduel, Michael Mainil
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Patent number: 7550543Abstract: The invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a cocatalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in the field of polymers, especially that of nanotechnologies.Type: GrantFiled: August 5, 2004Date of Patent: June 23, 2009Assignee: S.A. NanocylInventors: Philippe Dubois, Michael Alexandre, Daniel Bonduel, Michael Mainil
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Publication number: 20080293877Abstract: The present invention concerns a fireproof composition consisting of reticulated polysiloxane and raw carbon nanotubes with a “bound rubber” value greater than or equal to 15 grams of carbon nanotube, said carbon nanotubes representing between 0.05 and 1% of the total weight of said composition.Type: ApplicationFiled: October 3, 2006Publication date: November 27, 2008Inventors: Michael Alexandre, Philippe Dubois, Myriam Devalckenaere, Michael Claes
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Publication number: 20080207824Abstract: The invention concerns a method for dispersing carbon nanotubes in a polymer matrix including a step of preparing carbon nanotubes coated with a polymer coating by a method for polymerizing a monomer using a catalytic system wherein carbon nanotubes are used as catalytic support, the carbon nanotubes comprising in surface the catalytic system for polymerizing the coating polymer, and the coating polymer being non-miscible in the host polymer matrix, followed by a step of hot process mixing of the coated carbon nanotubes with a polymer matrix.Type: ApplicationFiled: May 24, 2006Publication date: August 28, 2008Applicant: Nanocyl S.AInventors: Michael Alexandre, Daniel Bonduel, Michael Claes, Dubois Philippe, Sophie Peeterbroeck, Sven Pegel, Petra Potschke
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Publication number: 20070184969Abstract: The invention relates to a method for producing carbon nanotubes in a dispersed state. The method comprises a stage whereby polymerization is carried out from at least one so-called monomer of interest, in the presence of a catalytic system. The catalytic system comprises a cocatalyst/catalyst catalytic couple that is supported by a catalyst carrier, which corresponds to said carbon nanotubes. The invention also relates to composite materials obtained by said method, and to a catalytic system for implementing said method. The invention further relates to the use of the inventive method and products in the field of polymers, especially that of nanotechnologies.Type: ApplicationFiled: August 5, 2004Publication date: August 9, 2007Applicant: S.A. NANOCYLInventors: Phillippe Dubois, Michael Alexandre, Daniel Bonduel, Mainil Michael
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Publication number: 20050154116Abstract: The present invention is related to nanocomposites comprising polymers, carbon nanotubes and layered silicate nanoparticles. The present invention also concerns methods for obtaining said nanocomposites as well as their uses.Type: ApplicationFiled: March 20, 2003Publication date: July 14, 2005Inventors: Janos Nagy, Christophe Pirlot, Antonio Fonseca, Gregory Philippin, Joseph Delhalle, Zineb Mekhalif, Robert Sporken, Philippe Dubois, Michael Alexandre, Gunter Beyer
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Publication number: 20040106720Abstract: The invention relates to a method for preparing nanocomposite aliphatic polyester consisting of the mixing of a nanofiller in at least one monomer that can form an aliphatic polyester and the intercalative polymerisation of the mixture obtained in the presence of a supercritical fluid.Type: ApplicationFiled: December 30, 2003Publication date: June 3, 2004Inventors: Robert Jerome, Cedric Calberg, Fabrice Stassin, Olivier Helleux, Philippe Dubois, Nadege Pantoustier, Michael Alexandre, Benedicte Lepoittevin
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Patent number: 6465543Abstract: The present invention is a nanocomposite which is a dispersion of nanofiller particles derived from layered metal oxides or metal oxide salts. The nanocomposite is advantageously prepared by first swelling an untreated clay in water, then removing the water to form an organophilic clay that is dispersible in non-polar organic solvents. The organophilic clay can then be treated with an alkyl aluminoxane and subsequently a catalyst to form a complex that promotes olefin or styrenic polymerization and platelet dispersion. The nanocomposite can be prepared directly by in situ polymerization of the olefin or the styrene at the nanofiller particles without shear, without an ion exchange step, and without the need to incorporate polar substituents into the polyolefin or polystyrene.Type: GrantFiled: December 21, 2000Date of Patent: October 15, 2002Assignee: The Dow Chemical CompanyInventors: Michael Alexandre, Philippe G. Dubois, Robert J. E. G. Jerome, Miguel Garcia-Marti, Tao Sun, Juan M. Garces, Dean M. Millar, Alexander Kuperman
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Patent number: 6207775Abstract: The present invention relates to a process for preparing a filled polymer composite comprising from 1 to 98 percent by weight of an interpolymer and from 2 to 99 percent by weight of a filler, said process comprising copolymerization in the presence of a cyclopentadienyl-containing transition metal catalyst and a filler, said filler having immobilized thereon a suitable cocatalyst.Type: GrantFiled: August 27, 1998Date of Patent: March 27, 2001Assignee: The Dow Chemical CompanyInventors: Miguel García Martí, Michael Alexandre, Philippe G. Dubois, Robert J. E. G. Jérô ;me, François J. Hindryckx