Abstract: A thermally-integrated lower temperature water-gas shift reactor apparatus for converting carbon monoxide in the presence steam comprises a catalyst bed that is disposed within an outer region surrounding a waste heat recovery steam generator operating at a selected pressure corresponding to the optimum temperature for conducting the catalytic water-gas shift reaction and a process for useful recovery of the exothermic heat of reaction to generate steam that is used in a process for the conversion of hydrocarbon feedstock into useful gases such as hydrogen.

Abstract: A fuel processor apparatus comprising a catalytic tubular reactor is heated using an infrared radiant burner to provide the endothermic heat of reaction needed to reform a mixture of hydrocarbon and steam for the production of a hydrogen-rich gas stream. The hydrogen-rich gas stream is further purified using a sequence of catalytic steps that is fed to a fuel cell whereupon a portion of the hydrogen contained in the gas stream is consumed for the production of electricity by electrochemical reaction with oxygen. An unused portion of the purified hydrogen-rich gas stream exits the fuel cell stack and is combusted in the infrared radiant burner. A fuel cell control system rapidly responds to a variable fuel cell electric demand by adjusting the feed of hydrocarbon to the catalytic tubular reactor to maintain the surface temperature of the infrared radiant burner within defined limits.

Abstract: The formation of coke on metal surfaces exposed to hydrocarbons in a thermal cracking process is reduced by ion implantation of selected antifoulants into such metal surfaces; the antifoulants being chosen from a group of primary elements consisting of aluminum, silicon, and chromium, or combinations thereof, and a group of secondary elements consisting of calcium, lithium, potassium, magnesium, cesium, hafnium, yttrium and zirconium, or combinations thereof.