Abstract: The present development is a catalyst for use in the water-gas-shift reaction. The catalyst includes a Group VIII or Group IB metal, a transition metal promoter selected from the group consisting of rhenium, niobium, silver, manganese, vanadium, molybdenum, titanium, tungsten and a combination thereof, and a ceria-based support. The support may further include gadolinium, samarium, zirconium, lithium, cesium, lanthanum, praseodymium, manganese, titanium, tungsten or a combination thereof. A process for preparing the catalyst is also presented. In a preferred embodiment, the process involves providing “clean” precursors as starting materials in the catalyst preparation.

Abstract: A method for producing a substantially desulfurized hydrocarbon fuel stream at temperatures less than 100° C. including providing a nondesulfurized fuel cell hydrocarbon fuel stream and passing the fuel stream through a sulfur adsorbent system containing a specialized sulfur adsorbent containing hydrated alumina to produce a substantially desulfurized hydrocarbon fuel stream.

Abstract: A process for the desulfurization of a fuel cell feed stream, wherein a sulfur contaminated hydrocarbon feed stream within a fuel cell system is desulfurized by passing it over a catalyst adsorbent containing from about 30 percent to about 80 percent nickel or a nickel compound, from about 5 percent to about 45 percent silica as a carrier, from about 1 percent to about 10 percent alumina as a promoter and from about 0.01 percent to about 15 percent magnesia as a promoter. The invention also includes a fuel cell system utilizing this catalyst adsorbent.

Abstract: A stable water gas shift catalyst comprising platinum, rhenium and lanthanum on an anatase titanium dioxide support is described. The catalyst of the present invention is at least as efficient in converting CO to CO2 at low temperatures as the catalysts of the prior art. Further, the catalyst is about three times more stable than the catalysts of the prior art.

Abstract: A stable water gas shift catalyst comprising platinum, rhenium and lanthanum on a high surface area rutile titanium dioxide support is described. The catalyst of the present invention is at least as efficient in converting CO to CO2 at low temperatures as the catalysts of the prior art. Further, the catalyst is about three times more stable than the catalysts of the prior art.