Abstract: Lightguide is disclosed. The lightguide includes a light guiding layer for propagating light by total internal reflection, and an optical film that is disposed on the light guiding layer. The optical film includes a plurality of voids, an optical haze that is not less than about 30%, and a porosity that is not less than about 20%. Substantial portions of each two neighboring major surfaces in the lightguide are in physical contact with each other.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films that include embedded nanostructures are disclosed. The articles include a sacrificial template layer having a first surface and a second surface having a structured surface opposite the first surface and a thermally stable backfill layer applied to the second surface of the sacrificial template layer. The thermally stable backfill layer has a structured surface conforming to the structured surface of the sacrificial template layer and the sacrificial template layer comprises inorganic nanomaterials and sacrificial material. The sacrificial material in the sacrificial template layer is capable of being cleanly baked out while leaving a densified layer of inorganic nanomaterials on the structured surface of the thermally stable backfill layer.

Abstract: A method of making patterned structured solid surfaces is disclosed that includes filling a structured template with backfill material to produce a structured transfer film and laminating the structured transfer film to a receptor substrate. The receptor substrate comprises a patterned adhesion promotion layer. The template layer is capable of being removed from the backfill layer while leaving at least a portion of the structured surface of the backfill layer substantially intact. The backfill layer can include at least two different materials, one of which can be an adhesion promotion layer. In some embodiments the backfill layer includes a silsesquioxane such as polyvinyl silsesquioxane. The structured transfer film is a stable intermediate that can be covered temporarily with a release liner for storage and handling.

Abstract: A transfer tape is disclosed that includes a carrier, a template layer having a first surface applied to the carrier and having a second surface opposite the first surface, wherein the second surface comprises a non-planar structured surface, a release coating disposed upon the non-planar structured surface of the template layer, and a backfill layer disposed upon and conforming to the non-planar structured surface of the release coating. In some embodiments, the backfill layer includes a silsesquioxane such as polyvinyl silsesquioxane. The disclosed transfer tape can be used to transfer replicated structures to a receptor substrate.

Abstract: This disclosure generally relates to retroreflective articles that include a low-index material and a printed region. This disclosure also generally relates to methods of making retroreflective articles.

Abstract: Lamination transfer films and methods for transferring a structured layer to a receptor substrate. The transfer films include a carrier substrate having a releasable surface, a sacrificial template layer applied to the releasable surface of the carrier substrate and having a non-planar structured surface, and a thermally stable backfill layer applied to the non-planar structured surface of the sacrificial template layer. The sacrificial template layer is capable of being removed from the backfill layer, such as via pyrolysis, while leaving the structured surface of the backfill layer substantially intact.

Abstract: Retroreflecting optical constructions are disclosed. A disclosed retroreflecting optical construction includes a retroreflecting layer that has a retroreflecting structured major surface, and an optical film that is disposed on the retroreflecting structured major surface of the retroreflecting layer. The optical film has an optical haze that is not less than about 30%. Substantial portions of each two neighboring major surfaces in the retroreflecting optical construction are in physical contact with each other.

Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.

Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.

Abstract: The present disclosure generally relates to patterned gradient polymer films and methods for making the same, and more particularly to patterned gradient optical films that have regions that include variations in optical properties such as refractive index, haze, transmission, clarity, or a combination thereof. The variation in optical properties can occur across a transverse plane of the film as well as through a thickness direction of the film.

Abstract: This disclosure generally relates to retroreflective articles and methods of making such articles.

Abstract: A microstructured article includes a nanovoided layer having opposing first and second major surfaces, the first major surface being microstructured to form prisms, lenses, or other features. The nanovoided layer includes a polymeric binder and a plurality of interconnected voids, and optionally a plurality of nanoparticles. A second layer, which may include a viscoelastic layer or a polymeric resin layer, is disposed on the first or second major surface. A related method includes disposing a coating solution onto a substrate. The coating solution includes a polymerizable material, a solvent, and optional nanoparticles. The method includes polymerizing the polymerizable material while the coating solution is in contact with a microreplication tool to form a microstructured layer. The method also includes removing solvent from the microstructured layer to form a nanovoided microstructured article.

Abstract: Light sources are disclosed. A disclosed light source includes an optically reflective cavity that includes an input port for receiving light and an output port for transmitting light, a lamp that is disposed at the input port, and an optical stack that is disposed at the output port. The optical stack includes a forward scattering optical diffuser that is disposed at the output port and has an optical haze that is not less than about 20%, and an optical film that is disposed on the optical diffuser. The optical film enhance total internal reflection at the interface between the optical film and the optical diffuser. The optical film has an index of refraction that is not greater than about 1.3 and an optical haze that is not greater than about 5%. The optical stack also includes a reflective polarizer layer that is disposed on the optical film. Substantial portions of each two neighboring major surfaces in the optical stack are in physical contact with each other.

Abstract: A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.

Abstract: A process and apparatus for producing a gradient nanovoided article, a gradient nanovoided coating, and a gradient low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent, and providing a first environment proximate a first region of the coating and a different second environment proximate an adjacent region of the coating. The process further includes at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution. The insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution, and a major portion of the solvent from the second solution is removed. A first volume fraction of the plurality of nanovoids proximate the first region of the coating is less than a second volume fraction of the plurality of nanovoids proximate an adjacent of the coating.

Abstract: Optical film is disclosed. The optical film includes a binder, a plurality of particles, and a plurality of interconnected voids. The volume fraction of the plurality of interconnected voids in the optical film is not less than about 20%. The weight ratio of the binder to the plurality of the particles is not less than about 1:2.

Abstract: This disclosure generally relates to retroreflective articles that include a low-index material and a printed region. This disclosure also generally relates to methods of making retroreflective articles.

Abstract: Optical constructions are disclosed. A disclosed optical construction includes a reflective polarizer layer, and an optical film that is disposed on the reflective polarizer layer. The optical film has an optical haze that is not less than about 50%. Substantial portions of each two neighboring major surfaces in the optical construction are in physical contact with each other. The optical construction has an axial luminance gain that is not less than about 1.2.

Abstract: Retroreflective articles and constructions are disclosed. One exemplary retroreflective article or construction includes a retroreflective layer and a low refractive index layer. In one exemplary embodiment, the low refractive index layer is adjacent to at least a portion of a retroreflective structured major surface of the retroreflective layer.

Abstract: A lightguide (3690) is disclosed. The lightguide includes a light guiding layer (3610) for propagating light by total internal reflection, and an optical film (3640) that is disposed on the light guiding layer. The optical film includes a plurality of voids, an optical haze that is not less than about 30%, and a porosity that is not less than about 20%. Substantial portions of each two neighboring major surfaces (3614, 3642) in the lightguide are in physical contact with each other. The lightguide can be used as blacklight in a display system.