Patents by Inventor Michael Brunnemann
Michael Brunnemann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6609040Abstract: Method of analyzing and optimizing a multistage manufacturing process which includes a number of standard steps that are carried out identically and which are followed by tuning steps that are carried out in order to achieve predefined product properties, their type, number and exit being variable. The individual steps relate to at least one production-specific property an are recorded quantitatively in an electronic database. The property can be, for example, a proportion of the quantities, a proportion of the costs, or the effects of an individual step on a product property to be achieved. Examples of a multistage manufacturing process are the manufacture of a coating from a plurality of individual components and additives. With the aid of the information compiled in a database, individual steps can be reduced in terms of their number and their extent.Type: GrantFiled: October 16, 2000Date of Patent: August 19, 2003Assignee: BASF Coatings AGInventor: Michael BrĂ¼nnemann
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Patent number: 6120851Abstract: The present invention relates to a coating composition comprising(A) at least one hydroxyl-containing component which [lacuna] of(A1) from 5 to 60% by weight of at least one polyester and(A2) from 40 to 95% by weight of at least one polyacrylate resin which has been prepared at least partially in the presence of component (A1) and(B) at least one crosslinking agent, characterized in that component (A2) is obtainable from the monomer units:(a) a cycloaliphatic ester of (meth)acrylic acid,(b) a hydroxyl-containing alkyl ester of (meth)acrylic acid,(c) a monomer which is different from (a) and (b) and has at least two polymerizable, olefinically unsaturated double bonds,(d) optionally a further hydroxyl-containing, ethylenically unsaturated monomer which is different from (a), (b) and (c),(e) an aliphatic ester of (meth)acrylic acid which is different from (a), (b), (c) and (d),(f) a vinyl-aromatic hydrocarbon which is different from (a), (b), (c), (d) and (e), and(g) a further ethylenically unsaturated monomerType: GrantFiled: January 25, 1999Date of Patent: September 19, 2000Assignee: BASF Coatings AGInventors: Harald Borgholte, Heinz-Peter Rink, Werner-Alfons Jung, Michael Brunnemann
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Patent number: 6099912Abstract: The present invention relates to a coating composition comprising at least one hydroxyl-containing polyacrylate resin as binder component (A) and at least one crosslinking agent (B),component (A) being obtainable by free-radical polymerization of:(a) from 5 to 80% by weight of at least one cycloaliphatic ester of (meth)acrylic acid,(b) from 10 to 50% by weight of at least one hydroxyl-containing alkyl ester of (meth)acrylic acid,(c) from 1 to 25% by weight of at least one monomer having at least two polymerizable, olefinically unsaturated double bonds,(d) from 0 to 25% by weight of at least one further hydroxyl-containing monomer,(e) from 5 to 80% by weight of at least one aliphatic ester of (meth)acrylic acid,(f) from 0 to 40% by weight of at least one vinyl-aromatic compound, and(g) from 0 to 40% by weight of at least one further monomer,the sum of the proportions by weight of all monomers (a) to (g) always being 100% by weight.Type: GrantFiled: January 25, 1999Date of Patent: August 8, 2000Assignee: BASF Coatings AGInventors: Harald Borgholte, Heinz-Peter Rink, Werner-Alfons Jung, Michael Brunnemann
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Patent number: 6013739Abstract: The present invention provides a coating composition and a process for producing a multicoat finish therefrom. The coating composition has a binder component obtained by polymerizing: (a) from 10 to 51% by weight of a mixture of hydroxy n-butyl (meth)acrylate(s) and hydroxy n-propyl (meth)acrylate(s), (b) from 0 to 20% by weight of at least one further hydroxyl group-containing monomer, (c) from 28 to 85% by weight of at least one (cyclo)aliphatic (meth)acrylic acid ester, (d) from 0 to 25% by weight of at least one aromatic vinyl compound, (e) from 0 to 5% by weight of at least one unsaturated carboxylic acid, and (f) from 0 to 20% by weight of further monomers, to give a polyacrylate resin having a hydroxyl number of from 60 to 200, an acid number of from 0 to 35, and an Mn of from 1000 to 5000.Type: GrantFiled: September 4, 1996Date of Patent: January 11, 2000Assignee: BASF Coatings AGInventors: Heinz-Peter Rink, Michael Brunnemann, Ulrike Rockrath
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Patent number: 6001947Abstract: The present invention relates to a coating composition comprising(A) at least one hydroxyl-containing polyacrylate resin,(B) at least one isocyanate crosslinking agent and, if desired,(C) at least one hydroxyl-containing polyester-modified polyacrylate resin,wherein the polyacrylate resin (A) is obtainable by polymerizing(a1) at least one essentially carboxyl-free (meth)acrylic ester,(a2) at least one copolymerizable, hydroxyl-containing monomer which is different from (a3)(a3) at least one reaction product of acrylic acid and/or methacrylic acid with the glycidyl ester of an .alpha.-branched monocarboxylic acid having 5 to 18 carbon atoms per molecule,(a4) if desired, an [sic] at least one carboxyl-containing monomer,(a5) at least one polysiloxane macromonomer having a number-average molecular weight of from 1000 to 40,000 and on average from 0.5 to 2.5 ethylenically unsaturated double bonds per molecule or having on average from 0.5 to 2.Type: GrantFiled: February 4, 1998Date of Patent: December 14, 1999Assignee: BASF Coatings AGInventors: Michael Brunnemann, Harald Borgholte, Peter Hoffmann, Olaf Hallmann, Bernhard Rubbert
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Patent number: 5916938Abstract: The present invention relates to a solution of a polyacrylate resin in one or more organic solvents, containing one or more phosphites, characterized in that the solution contains from 0.05 to 1.0% by weight, based on the solids content of the acrylate resin solution, of one or more phosphites and in that the phosphite has been added, either partially or entirely, after the polymerization reaction, at a temperature below the polymerization temperature.The present invention further relates to coating compositions which contain these polyacrylate resin solutions, their use in processes for producing a multilayer protective and/or decorative coating on a substrate surface, and the use of the coating compositions in the automotive refinishing sector.Type: GrantFiled: January 15, 1997Date of Patent: June 29, 1999Assignee: BASF Coatings AGInventors: Michael Brunnemann, Heinz-Peter Rink, Harald Borgholte, Werner-Alfons Jung, Peter Hoffmann
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Patent number: 5876802Abstract: The present invention relates to an aqueous two-component polyurethane coating composition comprisingA) a water-dilutable polyacrylate resin (A) having an OH number of from 40 to 200 and an acid number of from 20 to 100 mg of KOH/g, andB) a polyisocyanate component,characterized in that the water-dilutable acrylate resin is obtainable by solution polymerization ofat least one ester of (meth)acrylic acid and a cycloaliphatic C.sub.6 to C.sub.10 alcohol, with the exception of cyclohexyl methacrylate,at least one hydroxyl-containing monomer,if desired, at least one vinyl ester of .alpha.-branched monocarboxylic acids having 5 to 18 carbon atoms per molecule and/or at least one reaction product of acrylic acid and/or methacrylic acid with the glycidyl ester of .alpha.Type: GrantFiled: July 3, 1997Date of Patent: March 2, 1999Assignee: BASF Coatings AGInventors: Michael Brunnemann, Uwe Meisenburg, Egbert Nienhaus, Heinz-Peter Rink
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Patent number: 5759631Abstract: Coating composition comprising(A) at least one hydroxyl group-containing polyacrylate resin obtained by polymerizing(a) from 5 to 80% by weight of a cycloaliphatic ester of methacrylic acid and/or acrylic acid, or a mixture of such monomers,(b) from 10 to 50% by weight of a hydroxyl group-containing alkyl ester of methacrylic acid and/or acrylic acid, or mixtures of such monomers,(c) from 0 to 25% by weight of a hydroxyl group-containing, ethylenically unsaturated monomer, different from (a) and (b), or a mixture of such monomers,(d) from 5 to 80% by weight of an aliphatic ester of methacrylic and/or acrylic acid, different from (a)-(c), or a mixture of such monomers,(e) from 0 to 40% by weight of an aromatic vinyl hydrocarbon, different from (a)-(d), or a mixture of such monomers, and(f) from 0 to 40% by weight of an additional ethylenically unsaturated monomer, different from (a)-(e), or a mixture of such monomers,and(B) at least one crosslinking agent.Type: GrantFiled: September 3, 1996Date of Patent: June 2, 1998Assignee: BASF Lacke+Farben AGInventors: Heinz-Peter Rink, Michael Brunnemann
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Patent number: 5691419Abstract: A coating agent comprises a binding agentcontaining at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; and one or more epoxy resins.Type: GrantFiled: February 1, 1994Date of Patent: November 25, 1997Assignee: BASF Lacke + Farben, AGInventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
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Patent number: 5686531Abstract: A coating agent comprises a binding agent containing at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; one or more addition and/or condensation resins with carboxyl groups; and one or more epoxy resins.Type: GrantFiled: May 24, 1995Date of Patent: November 11, 1997Assignee: BASF Lacke + Farben, AGInventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
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Patent number: 5483004Abstract: The present invention relates to an acrylate copolymer containing amino groups, carboxyl groups and, if appropriate, hydroxyl groups which is characterized in that it has been produced by preparing an acrylate copolymer containing amino groups and, if appropriate, carboxyl groups, by means ofA) free-radical solution polymerization, using azo initiators at temperatures from 80.degree. to 150.degree. C., ofa.sub.1) 1 to 20% by weight of vinylimidazole and/or dimethylaminopropylmethacrylamide,a.sub.2) 0 to 50% by weight of one or more monomers containing hydroxyl groups,a.sub.3) 0 to 50% by weight of one or more monomers containing carboxyl groups, anda.sub.4) 30 to 85% by weight of at least one further ethylenically unsaturated copolymerizable monomer,the total of the proportions by weight of the components a.sub.1 to a.sub.4 always being 100% by weight, and the proportions by weight of the components a.sub.2 and a.sub.Type: GrantFiled: March 30, 1994Date of Patent: January 9, 1996Assignee: BASF Lacke + Farben AGInventors: Peter Hoffmann, Michael Brunnemann
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Coating agents based on hydroxyl-containing polycondensation and polyaddition products and their use
Patent number: 5326820Abstract: The present invention relates to coating agents based on hydroxyl-containing binders and isocyanate-containing crosslinking agents, in which coating agentsI.) the binder comprisesA1) 5 to 80% by weight of at least one polyester or one alkyd resin having an OH number from 0 to 200 mg of KOH/g and an acid number from 0 to 200 mg of KOH/g,A2) 95 to 20% by weight of at least one polyacrylate having an OH number from 30 to 250 mg of KOH/g and an acid number from 0 to 50 mg of KOH/g,the sum of the weight proportions of components (A1) and (A2) being in each case 100% by weight, andII.) the binder is obtainable from1.) at least one polycondensation resin whose acid component comprises 5 to 100 mol % of cycloaliphatic polycarboxylic acids and/or esterifiable derivatives thereof,2.) at least one polyacrylate, at least some of which has been prepared in the presence of the polycondensation resin obtained in the first process step and3.Type: GrantFiled: March 15, 1993Date of Patent: July 5, 1994Assignee: BASF Lacke+Farben AktiengesellschaftInventors: Peter Hoffmann, Werner-Alfons Jung, Michael Brunnemann