Abstract: An aromatics/naphthalene rich stream obtained by processing heavy gas oil derived from tar sands and cycle oils derived from cracking heavy gas oil may optionally be blended and subjected to a hydrogenation process and a ring opening reaction typically in the presence of a zeolite, alumina, or silica alumina based catalyst which may contain noble metals and or copper or molybdenum to produce paraffinic feedstocks for further chemical processing.

Abstract: Less conventional sources of hydrocarbon feedstocks such as oil sands, tar sands and shale oils are being exploited. These feedstocks generate a larger amount of heavy oil, gas oil, asphaltene products and the like containing multiple fused aromatic ring compounds. These multiple fused aromatic ring compounds can be converted into feed for a hydrocarbon cracker by first hydrogenating at least one ring in the compounds and subjecting the resulting compound to a ring opening and cleavage reaction. The resulting product comprises lower paraffins suitable for feed to a cracker, higher paraffins suitable for example as a gasoline fraction and mono aromatic ring compounds (e.g. BTX) that may be further treated.

Abstract: A stainless steel comprising at least 20 weight % of chromium and at least 1.0 weight % of manganese is adapted to support an overcoating having a thickness from 1 to 10 microns of a spinel of the formula MnxCr3?xO4 wherein x is from 0.5 to 2. Preferably the overcoating is on chromia and has stability against chemical reaction at temperatures at least 25° C. higher than the uncoated chromia.

Abstract: A thermal cracking process using tubes, pipes, and coils made of. An outermost surface covering not less than 55% of stainless steel, said surface having a thickness from 0.1 to 15 microns and being a spinel of the formula MnxCr3-xO4 wherein x is from 0.5 to 2 is not prone to coking and is suitable for hydrocarbyl reactions such as furnace tubes for cracking.

Abstract: In a radiant heating box there is a convection current which flows over the surface of tubes in the box. Adding ribs to the external surface of vertical tubes provides an enhancement to the heat transfer by convection and increases the heat transfer to the tubes.

Abstract: The present invention provides a process to treat steels, preferably carbon steel to reduce the tendency of the steel to form coke when in contact with hydrocarbons at elevated temperatures. The steel may be first reduced then treated with a mixture of compounds which further modify the reduced surface and finally the treated steel surface is cured. The treated steel has a reduced propensity to form coke when in contact with hydrocarbons particularly at higher temperatures.

Abstract: A composite surface having a thickness from 10 to 5,000 microns comprising a spinel of the formula MnxCr3?xO4 wherein x is from 0.5 to 2 and oxides of Mn, Si selected from the group consisting of MnO, MnSiO3, Mn2SiO4 and mixtures thereof which are not prone to coking and are suitable for hydrocarbyl reactions such as furnace tubes for cracking.

Abstract: A composite surface having a thickness from 10 to 5,000 microns comprising a spinel of the formula MnxCr3-xO4 wherein x is from 0.5 to 2 and oxides of Mn, Si selected from the group consisting of MnO, MnSiO3, Mn2SiO4 and mixtures thereof which are not prone to coking and are suitable for hydrocarbyl reactions such as furnace tubes for cracking.

Abstract: An outermost surface covering not less than 55% of stainless steel, said surface having a thickness from 0.1 to 15 microns and being a spinel of the formula MnxCr3-xO4 wherein x is from 0.5 to 2 is not prone to coking and is suitable for hydrocarbyl reactions such as furnace tubes for cracking.

Abstract: The present invention provides a process to treat steels, preferably carbon steel to reduce the tendency of the steel to form coke when in contact with hydrocarbons at elevated temperatures. The steel may be first reduced then treated with a mixture of compounds which further modify the reduced surface and finally the treated steel surface is cured. The treated steel has a reduced propensity to form coke when in contact with hydrocarbons particularly at higher temperatures.

Abstract: In a steam cracking operation the formation of coke is a problem which needs to be overcome. While significant work has been done on decoking of furnaces little work has been done regarding transfer line exchangers. Coking of transfer line exchangers (TLE) may be reduced by injection of a solution containing at least one group 1 or 2 metal dichromate or dichromate and one or more of a group 1, 2 or 7 metal carbonate into the TLE.

Abstract: In a steam cracking operation the formation of coke is a problem which needs to be overcome. While significant work has been done on decoking of furnaces little work has been done regarding transfer line exchangers. Coking of transfer line exchangers (TLE) may be reduced by injection of a solution containing at least one group 1 or 2 metal dichromate or dichromate and one or more of a group 1, 2 or 7 metal carbonate into the TLE.

Abstract: Heat resistant stainless steel may be treated in a low oxidizing atmosphere in a heat/soak-heat/soak sequence to deplete its surface of Ni and Cr which tend to catalyze coking of hydrocarbons in contact with the surface of the stainless steel, and enrich it with elements which are inert to coke formation. Parts made of stainless steel, such as furnace tubes or coils, treated in accordance with the present invention when used have a significantly reduced rate of catalytic coking.

Abstract: A combined chain of a high temperature, high conversion steam cracker in combination with a polymerization or oligomerization unit provides capital and operating cost reduction.

Abstract: A method for prolonging a hydroconversion catalyst life-time is provided. An additive functional to partially redirect the deposition of catalytic poisoning agents on the catalyst is utilized. The additive may comprise a chemically inert, porous carbonaceous material or ferruginous clay.