Abstract: The present disclosure provides photo-polymerizable components, photo-curable resins comprising one or more of such monomers, as well as polymeric materials formed from the photo-curable resins. Further provided herein are methods of producing the compositions and using the same for the fabrication of medical devices, such as orthodontic appliances.

Abstract: Systems, methods, and devices for additive manufacturing are provided. In some embodiments, a method includes: coupling a plurality of build platforms to a carrier; forming a plurality of 3D objects on the plurality of build platforms using an additive manufacturing process, where each build platform receives at least one 3D object thereon; removing the plurality of build platforms from the carrier; performing post-processing of the plurality of 3D objects while the 3D objects remain on the respective build platforms; and separating the plurality of 3D objects from the respective build platforms.

Abstract: The present disclosure relates to ornamental indicia carrier and method of producing the same. In some embodiments, the ornamental indicia carrier comprises an ultraviolet light (“UV”) cured ink printed on a thin flexible film and combined with an adhesive layer. The ornamental indicia carrier is capable of enduring the conditions inside the mouth for an extended period of time and can be used in conjunction with a dental appliance.

Abstract: A bipod support for a drain cleaning machine is described. The bipod support includes a base, a plurality of legs, a retaining member, and a latch. The retaining member and latch are configured to engage and secure the drain cleaning machine to the bipod support. The bipod support enables rocking movement of the drain cleaning machine while supporting the weight of the machine. Also described are related methods of use of the bipod support.

Abstract: This disclosure provides polymeric materials comprising weak crosslinking covalent bonds and/or weak crosslinking units comprising a weak covalent bond. Weak covalent bonds can be used in place of hydrogen bonds present in traditional polymeric materials (e.g., polyurethanes). Advantageously, the toughness can be controlled by varying the strength of weak covalent bonds and/or by varying the number of weak covalent crosslinks. Crosslinked materials applying the weak covalent crosslinking bonds can be used to create tough materials able to resist stress relaxation. Further, the present disclosure provides polymer chains and polymeric materials comprising inchain loops (also referred to herein as rings). The inchain loops comprise weak bonds and/or weak bridges comprising at least one weak bond.

Abstract: Methods for manufacturing objects are provided herein. In some embodiments, a method includes receiving a digital data set representing an object, and applying energy to a curable material based on the digital data set to form the object. The object can include at least two object portions formed from the curable material using different energy application parameters. The method can further include removing residual curable material from the object. A different amount of the residual curable material can be removed from each of the at least two object portions. After the residual curable material is removed, the at least two object portions can each have different material properties.

Abstract: Methods for manufacturing objects are provided herein. In some embodiments, a method includes receiving a dental appliance formed using an additive manufacturing process, the dental appliance including a plurality of appliance portions. The method can include identifying, based on sensor data, a location of a subset of the appliance portions on the dental appliance. The method can further include applying energy to a subset of the appliance portions to selectively modify one or more material properties of the subset of the appliance portions.

Abstract: Methods for fabricating orthodontic appliances are provided. In some embodiments, a method includes providing a polymerizable composition including a first polymerizable component and a second polymerizable component. The polymerizable composition can be characterized by an initial ratio of the first polymerizable component to the second polymerizable component. The method can include fabricating a portion of the orthodontic appliance from the polymerizable composition by forming a first region of the orthodontic appliance by exposing the polymerizable composition to radiation, the first region including a first ratio of the first polymerizable component to the second polymerizable component. The method can also include forming a second region of the orthodontic appliance, the second region including a second ratio of the first polymerizable component to the second polymerizable component. The initial ratio, the first ratio, and the second ratio can be different.

Abstract: This disclosure provides low-viscosity resins for producing polymers with properties suitable for use in various mechanical appliances, such as orthodontic appliances (e.g., aligners). The low-viscosity resins may be photo-curable and can be used with direct fabrication methods and equipment. In various embodiments, the polymeric materials produced from the low-viscosity resins described herein have high toughness while remaining resistant to stress relaxation. Low-viscosity, photo-curable resins described herein have reduced hydrogen bonding in comparison to traditional materials (e.g., materials having high urethane content) used in orthodontic appliances.

Abstract: According to the techniques herein, one or more sensors coupled to an aligner are used to sense one or more physical qualities of the aligner to determine whether the physical qualities indicate that the aligner material has relaxed and has, e.g., reduced the force systems applied to teeth and/or that the teeth movement for the stage has slowed down. The sensors may provide a signal that represents whether or not the physical qualities fall below a threshold value. A treatment plan may be modified if needed. These techniques have the potential to make treatment plans faster and more effective by speeding up some stages while making sure some, perhaps other, stages are implemented only after the teeth are near the appropriate position.

Abstract: This disclosure provides polymeric materials comprising weak crosslinking covalent bonds and/or weak crosslinking units comprising a weak covalent bond. Weak covalent bonds can be used in place of hydrogen bonds present in traditional polymeric materials (e.g., polyurethanes). Advantageously, the toughness can be controlled by varying the strength of weak covalent bonds and/or by varying the number of weak covalent crosslinks. Crosslinked materials applying the weak covalent crosslinking bonds can be used to create tough materials able to resist stress relaxation. Further, the present disclosure provides polymer chains and polymeric materials comprising inchain loops (also referred to herein as rings). The inchain loops comprise weak bonds and/or weak bridges comprising at least one weak bond.

Abstract: The present disclosure relates to ornamental indicia carrier and method of producing the same. In some embodiments, the ornamental indicia carrier comprises an ultraviolet light (“UV”) cured ink printed on a thin flexible film and combined with an adhesive layer. The ornamental indicia carrier is capable of enduring the conditions inside the mouth for an extended period of time and can be used in conjunction with a dental appliance.

Abstract: A method of 3D printing comprises extruding one or more photo-curable materials from a nozzle to form a first layer that has a first shape specified by the one or more digital files, wherein the first shape corresponds to a first minimum line width that is based on, and narrower than, a diameter of the nozzle. The method further includes directing a light beam onto the first layer according to the one or more digital files to cure a portion of the first layer to create a first cured layer, wherein the first cured layer corresponds to a second shape of a first layer of a 3D printed orthodontic aligner, wherein the light beam has a beam diameter that is smaller than the diameter of the nozzle, and wherein the second shape has a second minimum line width that is smaller than the first minimum line width.

Abstract: According to the techniques herein, one or more sensors coupled to an aligner are used to sense one or more physical qualities of the aligner to determine whether the physical qualities indicate that the aligner material has relaxed and has, e.g., reduced the force systems applied to teeth and/or that the teeth movement for the stage has slowed down. The sensors may provide a signal that represents whether or not the physical qualities fall below a threshold value. A treatment plan may be modified if needed. These techniques have the potential to make treatment plans faster and more effective by speeding up some stages while making sure some, perhaps other, stages are implemented only after the teeth are near the appropriate position.

Abstract: Provided herein are systems and processes to control multiple temperatures in additive manufacturing. Such temperature control adjusts polymer properties and facilitates processing of materials to form 3D objects. The systems and processed disclosed herein also facilitate the processing of typically difficult-to-process materials and deliver such materials to a photocuring zone configured to photopolymerize materials into 3 dimensional objects with a layer-by-layer process. Such processes can include the steps of heating a resin to a flowable temperature, applying the resin to a carrier, cooling the film to increase viscosity or to solidify the resin, and applying the film containing the resin onto an area being printed, then photocuring the film. Also provided herein are resins and related polymer materials having properties that are tunable with exposure to more than one temperature zone. The formed polymers can include multiple regions of polymer material, each independently having distinct properties.

Abstract: A 3D printer comprises a platform, a dispenser and a light source. A heating element heats a material and a nozzle extrudes the heated material onto the platform to form a first layer, having a first shape specified by one or more digital files. The first shape corresponds to a first minimum line width based on a diameter of the nozzle. The light source emits a light beam that is directed onto the first layer according to the one or more digital files to cure a portion of the first layer to create a first cured layer that corresponds to a second shape of a 3D object specified by the one or more digital files. The light beam has a beam diameter that is smaller than the diameter of the nozzle, and the second shape has a second minimum line width that is smaller than the first minimum line width.

Abstract: Provided herein are systems and processes to control multiple temperatures in additive manufacturing. Such temperature control adjusts polymer properties and facilitates processing of materials to form 3D objects. The systems and processes disclosed herein also facilitate the processing of typically difficult-to-process materials and deliver such materials to a photocuring zone configured to photopolymerize materials into 3 dimensional objects with a layer-by-layer process. Such processes can include the steps of heating a resin to a flowable temperature, applying the resin to a carrier, cooling the film to increase viscosity or to solidify the resin, and applying the film containing the resin onto an area being printed, then photocuring the film. Also provided herein are resins and related polymer materials having properties that are tunable with exposure to more than one temperature zone. The formed polymers can include multiple regions of polymer material, each independently having distinct properties.

Abstract: A system includes a partial enclosure configured to hold resin. The system further includes one or more structures configured to at least partially cover the resin. The one or more structures are configured to prevent evaporation of the resin. The system further includes a build platform configured to support an object that is being formed from layers of the resin. A first blade is configured to provide the layers of the resin to form the object on the build platform.

Abstract: A system includes a build platform configured to support an object that is being formed from layers of resin. The system further includes one or more blades configured to provide the layers of resin to form the object on the build platform. At least a first blade of the one or more blades is configured to vibrate to reduce viscosity of the layers of resin.

Abstract: A system includes a carrier film including an outer surface and an inner surface. The inner surface is configured to contact rollers. The system further includes a first blade configured to form a layer of resin on the outer surface of the carrier film. The system further includes a second blade configured to prevent printed features from contacting the first blade. The system further includes a build platform. A portion of the layer of resin is to be added to an object being formed on the build platform.