Patents by Inventor Michael D. Vitrano

Michael D. Vitrano has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 12371595
    Abstract: A low activation temperature heat seal hot melt adhesive for packaging applications based on a blend of metallocene catalyzed polyolefin polymer, tackifying resin, wax and other optional additives. In order to achieve the high viscosity suitable for an extrusion heat seal application, the adhesive composition of the invention is highly loaded with polymer, and thus should have a viscosity of about 50,000 centipoise or more measured at a temperature of 300° F. Accordingly, the hot melt adhesive composition contains about 50% to about 90% by weight of metallocene catalyzed polyolefin polymer, about 5% to about 50% by weight of tackifying resin, about 0.5% to about 40% by weight of wax, about 0.1% to about 5% by weight of a stabilizer or antioxidant, and 0% to about 25% by weight of optional additives. The hot melt adhesive composition must have an activation temperature of about 160° F. or less, and provide a minimum peel force of about 1.
    Type: Grant
    Filed: January 22, 2016
    Date of Patent: July 29, 2025
    Assignee: Bostik, Inc.
    Inventors: Monina D. Kanderski, Michael D. Vitrano
  • Publication number: 20230313004
    Abstract: A hot melt adhesive comprises a polylactide homopolymer or copolymer, such as polylactic acid; sulfonated copolyester; and at least one plasticizer, and is compostable. The plasticizer may be a solid plasticizer, such as a benzoate, and a second plasticizer may also be used. The adhesive is suitable for use in a variety of applications, such as case and carton applications, use with burlap or other compostable substrates for tree bulbs or plant seeds, and use with other compostable films, and is especially appropriate for dual-walled paperboard beverage cups. The adhesive demonstrates good bond performance comparable to non-compostable adhesives over a range of temperatures, reflective of the temperatures of hot and cold beverages.
    Type: Application
    Filed: April 24, 2023
    Publication date: October 5, 2023
    Inventors: Monina D. KANDERSKI, Michael D. VITRANO, David P. KEULER, Deepa PUTHANPARAMBIL, Jacqueline M. LAMBERT, Brian J. MORROW
  • Patent number: 11661537
    Abstract: A hot melt adhesive comprises a polylactide homopolymer or copolymer, such as polylactic acid; sulfonated copolyester; and at least one plasticizer, and is compostable. The plasticizer may be a solid plasticizer, such as a benzoate, and a second plasticizer may also be used. The adhesive is suitable for use in a variety of applications, such as case and carton applications, use with burlap or other compostable substrates for tree bulbs or plant seeds, and use with other compostable films, and is especially appropriate for dual-walled paperboard beverage cups. The adhesive demonstrates good bond performance comparable to non-compostable adhesives over a range of temperatures, reflective of the temperatures of hot and cold beverages.
    Type: Grant
    Filed: September 6, 2019
    Date of Patent: May 30, 2023
    Assignee: Bostik, Inc.
    Inventors: Monina D. Kanderski, Michael D. Vitrano, David P. Keuler, Deepa Puthanparambil, Jacqueline M. Lambert, Brian J. Morrow
  • Publication number: 20230002651
    Abstract: A hot melt pressure sensitive adhesive composition comprises: (a) a block copolymer comprising a first polymer block comprising an ethylene residue and a second polymer block comprising a C1 to C4 alkyl acrylate residue, wherein the block copolymer has a melt index as measured in accordance with ASTM D1238 of between about 0.1 and about 250 g/10 min; (b) a tackifying resin; and (c) a plasticizer. A method for making a laminate comprises the steps of: applying the hot melt pressure sensitive adhesive composition of the invention in a molten state to a primary substrate and allowing the adhesive to cool to form a bond with said primary substrate. Certain adhesives the invention perform comparably to certain styrene block copolymer adhesives, but provides an alternative polymer source.
    Type: Application
    Filed: December 4, 2020
    Publication date: January 5, 2023
    Inventors: Kathleen M. Davis, Michael D. Vitrano, Patrick J. Czaplewski, Lauren M. Rohde
  • Patent number: 10815398
    Abstract: A hot melt adhesive that is composed of a metallocene catalyzed polyethylene polymer, a hydrogenated styrenic block copolymer, a tackifying resin, and a solid plasticizer. The preferred polyethylene polymer is an ethylene-octene copolymer, and the preferred styrenic block copolymer is a styrene-ethylene-butylene-styrene having less than 30% styrene content. The preferred solid plasticizer is either glycerol tribenzoate or 1,4-cyclohexane dimethanol dibenzoate.
    Type: Grant
    Filed: April 9, 2012
    Date of Patent: October 27, 2020
    Assignee: BOSTIK, INC.
    Inventors: Michael D. Vitrano, Kevin Stafeil, Tsebaot Hailemichael
  • Publication number: 20200079981
    Abstract: A hot melt adhesive comprises a polylactide homopolymer or copolymer, such as polylactic acid; sulfonated copolyester; and at least one plasticizer, and is compostable. The plasticizer may be a solid plasticizer, such as a benzoate, and a second plasticizer may also be used. The adhesive is suitable for use in a variety of applications, such as case and carton applications, use with burlap or other compostable substrates for tree bulbs or plant seeds, and use with other compostable films, and is especially appropriate for dual-walled paperboard beverage cups. The adhesive demonstrates good bond performance comparable to non-compostable adhesives over a range of temperatures, reflective of the temperatures of hot and cold beverages.
    Type: Application
    Filed: September 6, 2019
    Publication date: March 12, 2020
    Inventors: Monina D. Kanderski, Michael D. VITRANO, David P. KEULER, Deepa PUTHANPARAMBIL, Jacqueline M. LAMBERT, Brian J. MORROW
  • Patent number: 10081212
    Abstract: A non-pressure sensitive hot melt adhesive for use in mailer applications uses a styrenic block copolymer (SBC) with a hydrogenated mid-block as the primary polymer in the composition. The adhesive contains about 10% to about 50% by weight of the SBC, about 2% to about 30% by weight of a polyolefin polymer as a secondary polymer in the composition, about 10% to about 70% by weight of a suitable plasticizer, about 0% to about 30% by weight of a wax, about 0% to about 50% by weight of one or more tackifying resins, about 0.1% to about 4% by weight of a stabilizer, and about 0% to about 3% by weight of auxiliary additives, so that the viscosity of the composition is equal to or less than about 10,000 cP at 163° C. The formulation balances the cohesive and adhesive strength required to insure the adhesive fails cohesively to prevent paper tear.
    Type: Grant
    Filed: July 1, 2015
    Date of Patent: September 25, 2018
    Assignee: BOSTIK, INC.
    Inventors: Monina D. Kanderski, Michael D. Vitrano
  • Publication number: 20180244962
    Abstract: A hot melt adhesive composition containing a functionalized polymer, namely, a metallocene catalyzed polyolefin elastomer grafted with maleic anhydride, together with a non-functionalized secondary polymer, namely, a metallocene catalyzed random or block polyolefin elastomer having a melt index equal to or greater than 15, a first tackifying resin having a softening point of at least 95° C., and a wax. The composition may optionally include an aromatic reinforcing resin having a softening point equal to or higher than 115° C., and a plasticizer. These hot melts provide superior hot tack, excellent adhesion, flexibility, and heat resistance above 150° F. in applications such as rigid packaging, hot fill packaging, and bottle labeling.
    Type: Application
    Filed: April 30, 2018
    Publication date: August 30, 2018
    Inventors: Monina D. Kanderski, Michael D. Vitrano
  • Patent number: 9982171
    Abstract: A hot melt adhesive composition containing a functionalized polymer, namely, a metallocene catalyzed polyolefin elastomer grafted with maleic anhydride, together with a non-functionalized secondary polymer, namely, a metallocene catalyzed random or block polyolefin elastomer having a melt index equal to or greater than 15, a first tackifying resin having a softening point of at least 95° C., and a wax. The composition may optionally include an aromatic reinforcing resin having a softening point equal to or higher than 115° C., and a plasticizer. These hot melts provide superior hot tack, excellent adhesion, flexibility, and heat resistance above 150° F. in applications such as rigid packaging, hot fill packaging, and bottle labeling.
    Type: Grant
    Filed: September 25, 2014
    Date of Patent: May 29, 2018
    Assignee: Bostik, Inc.
    Inventors: Monina D. Kanderski, Michael D. Vitrano
  • Patent number: 9404004
    Abstract: A hot applied, non-crosslinking, non-butyl, sealant. These sealants are composed of olefin polymers, styrenic block copolymers, an ethylene vinyl acetate copolymer, tackifying resins, plasticizers, and preferably inorganic fillers, and organosilane adhesion promoters. Optionally, the sealant may include UV absorbers, antioxidants, pigments, and the like. The sealants are suitable for use as edge sealants for insulated glass (IG) window units.
    Type: Grant
    Filed: December 28, 2012
    Date of Patent: August 2, 2016
    Assignee: BOSTIK, INC.
    Inventors: Patrick John Czaplewski, David P. Keuler, Michael D. Vitrano
  • Publication number: 20160215176
    Abstract: A low activation temperature heat seal hot melt adhesive for packaging applications based on a blend of metallocene catalyzed polyolefin polymer, tackifying resin, wax and other optional additives. In order to achieve the high viscosity suitable for an extrusion heat seal application, the adhesive composition of the invention is highly loaded with polymer, and thus should have a viscosity of about 50,000 centipoise or more measured at a temperature of 300° F. Accordingly, the hot melt adhesive composition contains about 50% to about 90% by weight of metallocene catalyzed polyolefin polymer, about 5% to about 50% by weight of tackifying resin, about 0.5% to about 40% by weight of wax, about 0.1% to about 5% by weight of a stabilizer or antioxidant, and 0% to about 25% by weight of optional additives. The hot melt adhesive composition must have an activation temperature of about 160° F. or less, and provide a minimum peel force of about 1.
    Type: Application
    Filed: January 22, 2016
    Publication date: July 28, 2016
    Applicant: Bostik, Inc.
    Inventors: Monina D. Kanderski, Michael D. Vitrano
  • Publication number: 20160177119
    Abstract: A hot applied, non-crosslinking, non-butyl, sealant. These sealants are composed of olefin polymers, styrenic block copolymers, an ethylene vinyl acetate copolymer, tackifying resins, plasticizers, and preferably inorganic fillers, and organosilane adhesion promoters. Optionally, the sealant may include UV absorbers, antioxidants, pigments, and the like. The sealants are suitable for use as edge sealants for insulated glass (IG) window units.
    Type: Application
    Filed: December 28, 2012
    Publication date: June 23, 2016
    Applicant: Bostik, Inc.
    Inventors: Patrick John Czaplewski, David P. Keuler, Michael D. Vitrano
  • Publication number: 20160002508
    Abstract: A non-pressure sensitive hot melt adhesive for use in mailer applications uses a styrenic block copolymer (SBC) with a hydrogenated mid-block as the primary polymer in the composition. The adhesive contains about 10% to about 50% by weight of the SBC, about 2% to about 30% by weight of a polyolefin polymer as a secondary polymer in the composition, about 10% to about 70% by weight of a suitable plasticizer, about 0% to about 30% by weight of a wax, about 0% to about 50% by weight of one or more tackifying resins, about 0.1% to about 4% by weight of a stabilizer, and about 0% to about 3% by weight of auxiliary additives, so that the viscosity of the composition is equal to or less than about 10,000 cP at 163° C. The formulation balances the cohesive and adhesive strength required to insure the adhesive fails cohesively to prevent paper tear.
    Type: Application
    Filed: July 1, 2015
    Publication date: January 7, 2016
    Applicant: BOSTIK, INC.
    Inventors: Monina D. Kanderski, Michael D. Vitrano
  • Publication number: 20150087760
    Abstract: A hot melt adhesive composition containing a functionalized polymer, namely, a metallocene catalyzed polyolefin elastomer grafted with maleic anhydride, together with a non-functionalized secondary polymer, namely, a metallocene catalyzed random or block polyolefin elastomer having a melt index equal to or greater than 15, a first tackifying resin having a softening point of at least 95° C., and a wax. The composition may optionally include an aromatic reinforcing resin having a softening point equal to or higher than 115° C., and a plasticizer. These hot melts provide superior hot tack, excellent adhesion, flexibility, and heat resistance above 150° F. in applications such as rigid packaging, hot fill packaging, and bottle labeling.
    Type: Application
    Filed: September 25, 2014
    Publication date: March 26, 2015
    Applicant: Bostik, Inc.
    Inventors: Monina D. Kanderski, Michael D. Vitrano
  • Patent number: 8481634
    Abstract: A hot melt desiccant matrix composition has an organic binder and an absorbent material as components thereof. The organic binder includes about 10% to 80% by weight of a propylene based poly-?-olefin polymer having a melting point or a glass transition temperature less than 180° C., a density in the range of 0.85 to 0.95 g/cc or a blend of poly-?-olefin polymers; about 5% to 70% by weight of a plasticizer having a flash point equal to or greater than 180° C.; about 0% to 50% by weight a compatible tackifier; and a stabilizer in the amount of about 0% to 5% by weight. The absorbent component may be a water/moisture absorbing material, or a VOC absorbing material, or a blend of water/moisture absorbing and VOC absorbing materials. The absorbent material is selected from absorbing materials including, but not limited to, silica gels, activated carbons, silica alumina, calcium sulfate, calcium oxide, natural zeolites and molecular sieves and the mixtures thereof.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: July 9, 2013
    Assignee: Bostik, Inc.
    Inventors: Baoyu Wang, Michael D. Vitrano
  • Publication number: 20120259050
    Abstract: A hot melt adhesive that is composed of a metallocene catalyzed polyethylene polymer, a hydrogenated styrenic block copolymer, a tackifying resin, and a solid plasticizer. The preferred polyethylene polymer is an ethylene-octene copolymer, and the preferred styrenic block copolymer is a styrene-ethylene-butylene-styrene having less than 30% styrene content. The preferred solid plasticizer is either glycerol tribenzoate or 1,4-cyclohexane dimethanol dibenzoate.
    Type: Application
    Filed: April 9, 2012
    Publication date: October 11, 2012
    Applicant: BOSTIK, INC.
    Inventors: Michael D. Vitrano, Kevin Stafeil, Tsebaot Hailemichael
  • Publication number: 20090069170
    Abstract: A hot melt desiccant matrix composition has an organic binder and an absorbent material as components thereof. The organic binder includes about 10% to 80% by weight of a propylene based poly-?-olefin polymer having a melting point or a glass transition temperature less than 180° C., a density in the range of 0.85 to 0.95 g/cc or a blend of poly-?-olefin polymers; about 5% to 70% by weight of a plasticizer having a flash point equal to or greater than 180° C.; about 0% to 50% by weight a compatible tackifier; and a stabilizer in the amount of about 0% to 5% by weight. The absorbent component may be a water/moisture absorbing material, or a VOC absorbing material, or a blend of water/moisture absorbing and VOC absorbing materials. The absorbent material is selected from absorbing materials including, but not limited to, silica gels, activated carbons, silica alumina, calcium sulfate, calcium oxide, natural zeolites and molecular sieves and the mixtures thereof.
    Type: Application
    Filed: September 7, 2007
    Publication date: March 12, 2009
    Inventors: Baoyu Wang, Michael D. Vitrano