Abstract: Adhesives comprising: a) 35-85 weight percent of a pressure sensitive adhesive comprising: i) a polymer selected from rubbers and polyacrylate polymers and ii) optionally one or more tackifiers; and dispersed therein b) 15-50 weight percent fire retardant (FR) particles comprising one or more phosphorus-containing compounds selected from organophosphine oxides and organophosphi-nates. In some embodiments, the phosphorus-containing compounds comprise 35-65 weight percent of an organophosphine oxide and 65-35 weight percent of an organophosphinate. The FR particles may have a D50 particle size of 1-120 micrometers, 40-120 micrometers, or 70-120 micrometers. Adhesive films comprising the adhesives described herein may be free-standing adhesive films or adhesive layers comprised in tapes.

Abstract: A fire resistant (FR) pressure sensitive adhesive (PSA) comprises a blend of: a) a (meth)acrylate polymer comprising cationic monomer units; and b) a non-halogenated flame retardant. In some embodiments, the cationic monomer units comprise cationic quaternary amine groups. The (meth)acrylate polymer may additionally comprise anionic monomer units, in which case the molar ratio of anionic monomer units present in the polymer to cationic monomer units present in the polymer is typically less than 0.9. The FR PSA may be aqueous based and may be free of common solvents. The FR PSA may demonstrate improved flame retardance with good compatibility between PSA and flame retardant, and may retain compatibility even at high loadings of flame retardant.