Abstract: A method forming a composite electrolyte by preparing a suspension. The suspension includes a solvent (comprising 90 wt % to 95 wt % of a total weight of liquids); a non-solvent (comprising 5 wt % to 50 wt % of a total weight of liquids); a binder (comprising 20 wt % to 50 wt % of a total weight of the composite electrolyte) and selected from the group consisting of PVDF, PVDF-HFP, PFTE, PEO, PMMA, PAN, CNC, SBR, and combinations thereof; and a ceramic filler (comprising 50 wt % to 80 wt % of the total weight of the composite electrolyte) having a cross-section diameter ranging from 50 nm to 150 nm and being selected from the group consisting of Al2O3, SiO2, TiO2, MgO, Li2O, LiAlO2, BaTiO3, LaGP, LATP, LLTO, and combinations thereof. The suspension is cast or printed and dried.

Abstract: A method of applying a separator ink onto a dried electrode of a lithium ion battery. The method includes preparing a separator ink suspension, applying the separator ink suspension onto the dried electrode, and drying the applied separator ink suspension.

Abstract: A method forming a composite electrolyte by preparing a suspension. The suspension includes a solvent (comprising 90 wt % to 95 wt % of a total weight of liquids); a non-solvent (comprising 5 wt % to 50 wt % of a total weight of liquids); a binder (comprising 20 wt % to 50 wt % of a total weight of the composite electrolyte) and selected from the group consisting of PVDF, PVDF-HFP, PFTE, PEO, PMMA, PAN, CNC, SBR, and combinations thereof; and a ceramic filler (comprising 50 wt % to 80 wt % of the total weight of the composite electrolyte) having a cross-section diameter ranging from 50 nm to 150 nm and being selected from the group consisting of Al2O3, SiO2, TiO2, MgO, Li2O, LiAlO2, BaTiO3, LaGP, LATP, LLTO, and combinations thereof. The suspension is cast or printed and dried.

Abstract: A composite electrolyte (151). The composite electrolyte (151) including a binder, a solvent, a non-solvent, and a ceramic filler. The non-solvent is configured to cause the binder to self-interact. The composite electrolyte (151) may be cast (138) or printed (144).

Abstract: A tandem solar cell comprises a front subcell; a back subcell; and an interconnecting layer of Cr/MoO3 between the front subcell and the back subcell and connecting the two subcells in series. The back subcell may be an isoindigo-based polymer. The front subcell may comprise a carbazole-thienyl-benzothiadiazole based polymer. The front subcell may comprise an isoindigo-based polymer. The isoindigo-based polymer is a repeating 2-thiophene-terminated polymer. A tandem solar cell comprises a substrate layer; a layer of PCDTBT:PC71BM applied on the substrate layer; a bilayer of chromium and MoO3 applied to the PCDTBT:PC71BM layer; a layer of P(T3-il)-2:PC71BM applied on the bilayer of chromium and MoO3; and Ca and Al electrode layer on the top.

Abstract: A tandem solar cell comprises a back subcell; a front subcell; and an interconnecting layer of Cr/MoO3 between the back subcell and the front subcell and connecting the two subcells in series. The front subcell may comprise a carbazole-thienyl-benzothiadiazole based polymer and the back subcell may comprise an isoindigo-based polymer. A method for making a tandem solar cell comprises a) providing a substrate layer; b) applying a layer of PCDTBT:PC71BM to the substrate layer; c) applying a bilayer of chromium and MoO3 to the PCDTBT:PC71BM layer; d) applying a layer of P(T3-iI)-2:PC71BM on the bilayer of chromium and MoO3; and e) applying a Ca and Al electrode layer on the top.

Abstract: A tandem solar cell comprises a front subcell; a back subcell; and an interconnecting layer of Cr/MoO3 between the front subcell and the back subcell and connecting the two subcells in series. The back subcell may be an isoindigo-based polymer. The front subcell may comprise a carbazole-thienyl-benzothiadiazole based polymer. The front subcell may comprise an isoindigo-based polymer. The isoindigo-based polymer is a repeating 2-thiophene-terminated polymer. A tandem solar cell comprises a substrate layer; a layer of PCDTBT:PC71BM applied on the substrate layer; a bilayer of chromium and MoO3 applied to the PCDTBT:PC71BM layer; a layer of P(T3-il)-2:PC71BM applied on the bilayer of chromium and MoO3; and Ca and Al electrode layer on the top.

Abstract: A composite electrode. The composite electrode including an active material, a conductive additive, a binder, and a solvent. The composite electrode may be cast or printed.

Abstract: A method of applying a separator ink onto a dried electrode of a lithium ion battery. The method includes preparing a separator ink suspension, applying the separator ink suspension onto the dried electrode, and drying the applied separator ink suspension.

Abstract: A method for increasing the speed of aerosol jet assisted printing a layered perovskite structure comprises applying a PEDOT:PSS layer to a substrate; applying an aerosol mist containing methylammonium iodide and lead iodide, with or without additives, atop the PEDOT:PSS layer with an aerosol jet nozzle; and holding the structure to form a methylammonium lead iodide (CH3NH3PbI3) perovskite thin film layer. The substrate may be an ITO glass or plastic substrate, and the PEDOT:PSS layer may be applied by a process selected from spin-coating, inkjet-printing, slot-die-coating, aerosol jet printing, physical vapor deposition, chemical vapor deposition, and electrochemical deposition. The aerosol mist is generated from a single ink comprising all the constituents of methylammonium lead iodide either dissolved or suspended in one or more compatible solvents or co-solvents. The holding of the CH3NH3PbI3 layer may be performed at about 25-120° C. or lower for 96 hours or less.

Abstract: A composite electrolyte (151). The composite electrolyte (151) including a binder, a solvent, a non-solvent, and a ceramic filler. The non-solvent is configured to cause the binder to self-interact. The composite electrolyte (151) may be cast (138) or printed (144).

Abstract: A passive filter for an aerosol printing system. The passive filter includes a housing having a fluid inlet port at a first end and a fluid outlet port at a second end, the fluid inlet and outlet ports being coaxial. A chamber is disposed within the housing and has a ceiling, a base, at least one wall between the ceiling and the base, a chamber entrance in the ceiling, and a chamber exit. The chamber entrance and exit being coaxial to the fluid inlet and outlet ports. The chamber exit is disposed within chamber between the chamber entrance and the base and defining a circumferential trough about the chamber exit.

Abstract: A method for aerosol-jet printing a layered perovskite structure by applying a PEDOT:PSS layer to a substrate; applying a layer of lead iodide (PbI2) to the PEDOT:PSS layer; and applying an aerosol mist of methylammonium iodide (CH3NH3I) atop the PbI2 layer with an aerosol-jet nozzle to form a CH3NH3PbI3 perovskite film layer. The substrate may be an ITO glass substrate, and the PEDOT:PSS layer may be applied by a process selected from spin-coating, inkjet-printing, slot-die-coating, aerosol-jet printing, physical vapor deposition, chemical vapor deposition, and electrochemical deposition. The PbI2 layer may be applied by a process selected from spin-coating, aerosol-jet printing, inkjet-printing, slot-die-coating, physical vapor deposition, chemical vapor deposition, and electrochemical deposition, and the PbI2 for application to the PEDOT:PSS layer may be in a solution of DMF, DMSO, ?-butyrolactone, or a combination thereof.

Abstract: A method for forming a conductive trace on a substrate. A metallic liquid is mixed with a solvent to produce a metallic liquid mixture. The metallic liquid mixture is stimulated to produce a colloidal suspension of discrete metallic liquid particles surrounded by the solvent. The colloidal suspension is aerosolized with a carrier gas, and passed through a nozzle to deposit the discrete metallic liquid particles onto the substrate. The deposited discrete metallic liquid particles are annealed, thereby producing the conductive trace. The conductive trace has a substantially contiguous core of the metallic liquid within a substantially non-electrically conductive solid skin that substantially bounds the liquid core.

Abstract: A method for forming a conductive trace on a substrate. A metallic liquid is mixed with a solvent to produce a metallic liquid mixture. The metallic liquid mixture is stimulated to produce a colloidal suspension of discrete metallic liquid particles surrounded by the solvent. The colloidal suspension is aerosolized with a carrier gas, and passed through a nozzle to deposit the discrete metallic liquid particles onto the substrate. The deposited discrete metallic liquid particles are annealed, thereby producing the conductive trace. The conductive trace has a substantially contiguous core of the metallic liquid within a substantially non-electrically conductive solid skin that substantially bounds the liquid core.

Abstract: A method for aerosol jet printing a layered perovskite structure comprises applying a PEDOT:PSS layer to a substrate; applying a layer of lead iodide (PbI2) to the PEDOT:PSS layer; and applying an aerosol mist of methylammonium iodide (CH3NH3I) atop the PbI2 layer with an aerosol jet nozzle to form a CH3NH3PbI3 perovskite film layer. The substrate may be an ITO glass substrate, and the PEDOT:PSS layer may be applied by a process selected from spin-coating, inkjet-printing, slot-die-coating, aerosol jet printing, physical vapor deposition, chemical vapor deposition, and electrochemical deposition. The PbI2 layer may be applied by a process selected from spin-coating, aerosol jet printing, inkjet-printing, slot-die-coating, physical vapor deposition, chemical vapor deposition, and electrochemical deposition, and the PbI2 for application to the PEDOT:PSS layer may be in a solution of DMF, DMSO, ?-butyrolactone, or a combination thereof. The annealing of the PbI2 layer may be performed at about 80° C. or lower.

Abstract: A layered perovskite structure comprising a substrate having an upper surface and a lower surface; and a layer of a perovskite film on the upper surface. A passivating layer may be applied to the upper surface of the substrate to which the perovskite film is attached. The passivating layer comprises at least one a chalcogenide-containing species with the general chemical formula (E3E4)N(E1E2)N?C?X where any one of E1, E2, E3 and E4 is independently selected from C1-C15 organic substituents comprising from 0 to 15 heteroatoms or hydrogen, and X is S, Se or Te, thiourea, thioacetamide, selenoacetamide, selenourea, H2S, H2Se, H2Te, or LXH wherein L is a Cn organic substituent comprising heteroatoms and X?S, Se, or Te. The substrate comprises PEDOT:PSS, and may further comprise a layered glass/ITO/PEDOT:PSS structure. A passivating layer is applied to the PEDOT:PSS layer, and a top electrode may be applied over the perovskite film.

Abstract: A current collector. The current collector including a porous substrate and an active coating on the porous substrate. The active coating including an active material, a conductive additive, a binder, and an organic solvent.

Abstract: A composite electrode. The composite electrode including an active material, a conductive additive, a binder, and a solvent. The composite electrode may be cast or printed.

Abstract: A method for making a layered perovskite structure comprises: a) performing a vapor assisted surface treatment (VAST) of a substrate with a surface passivating agent; b) applying a layer of PbI2 to the passivating agent; c) exposing the PbI2 to methylammonium iodide (CH3NH3I) in an orthogonal solvent; and d) annealing the structure. A PEDOT:PSS coated ITO glass substrate may be used. The surface passivation agent may be one a chalcogenide-containing species with the general chemical formula (E3E4)N(E1E2)N?C?X where any one of E1, E2, E3 and E4 is independently selected from C1-C15 organic substituents comprising from 0 to 15 heteroatoms or hydrogen, and X is S, Se or Te, thiourea, thioacetamide, selenoacetamide, selenourea, H2S, H2Se, H2Te or LXH wherein L is a Cn organic substituent comprising heteroatoms and X?S, Se, or Te. The passivating agent may be applied by spin-coating, inkjet-printing, slot-die-coating, aerosol-jet printing, PVD, CVD, and electrochemical deposition.