Patents by Inventor Michael Grahl

Michael Grahl has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20050004320
    Abstract: A process for preparing polyisocyanate-modified polycarboxylic acids by conversion of anhydride-group-free polycarboxylic acids with isocyanate-functional compounds. The process includes reacting A) an anhydride-group-free polycarboxylic-acid component with B) an isocyanate-functional component having an (average) isocyanate functionality of at least 1.8, at an equivalent ratio of carboxylic acid groups to isocyanate groups of from 1.2:1 to 120:1. The polyisocyanate-modified polycarboxylic acids are solid below 40° C. and liquid above 130° C., and have an average carboxylic acid functionality of at least 1.8, a content of free carboxylic acid groups of from 4.0 wt. % to 80.0 wt. % and a content of amide groups of from 0.4 wt. % to 32.5 wt. %.
    Type: Application
    Filed: June 21, 2004
    Publication date: January 6, 2005
    Inventors: Hans-Josef Laas, Christoph Gurtler, Reinhard Halpaap, Michael Grahl, Peter Thometzek, James Rawlins
  • Publication number: 20040265597
    Abstract: The invention relates to the use of special mixtures of at least two polycarboxylic acids as crosslinker components for thermally curing powder-lacquer binding agents having groups that are capable of reacting with carboxyl groups. The mixtures include at least two polycarboxylic acids each melting above 95° C. and having up to 20 carbon atoms and consist of at least 5 wt. %, of the polycarboxylic acid with the lowest melting point and at least 10 wt. %, of the polycarboxylic acid with the highest melting point of all polycarboxylic acids present in the mixture to at least 5 wt. %. Additionally, the polycarboxylic acid mixture is a solid below 40° C. and a liquid above 160° C.
    Type: Application
    Filed: June 21, 2004
    Publication date: December 30, 2004
    Inventors: Hans-Josef Laas, Christoph Gurtler, Reinhard Halpaap, Michael Grahl, Peter Thometzek, James Rawlins
  • Publication number: 20040133035
    Abstract: The present invention relates to novel blocked, elimination-free polyurethane (PUR) crosslinking agents, to a process for their preparation and to their use as starting components for the production of polyurethane plastics, especially as crosslinking agents for thermally crosslinkable powder coatings.
    Type: Application
    Filed: December 17, 2003
    Publication date: July 8, 2004
    Inventors: Dorota Greszta-Franz, Christoph Gurtler, Reinhard Halpaap, Michael Schelhaas, Michael Grahl
  • Publication number: 20040059082
    Abstract: The invention relates to novel polyaddition compounds containing uretdione groups, to a process for preparing them and to their use as a starting component in the preparation of polyurethane plastics.
    Type: Application
    Filed: July 3, 2003
    Publication date: March 25, 2004
    Inventors: Hans-Josef Laas, Reinhard Halpaap, Peter Thometzek, Michael Grahl, Hans-Ulrich Meier-Westhues
  • Patent number: 6423777
    Abstract: The invention relates to new high-functional polyaddition compounds which contain free isocyanate groups with an average isocyanate functionality of 2.1 to 8.0, a concentration of uretdione of 10 to 18 wt. %, a concentration of urethane of 10 to 20 wt. % and a concentration of ester groups —CO—O and/or carbonate groups —O—CO—O of 1 to 17 wt. %, a process for the preparation thereof and their use as starting components for the preparation of polyurethane plastics, in particular as cross-linking agents for heat-curable powder coatings.
    Type: Grant
    Filed: September 5, 2000
    Date of Patent: July 23, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Josef Laas, Ulrich Freudenberg, Reinhard Halpaap, Michael Grahl
  • Patent number: 6297343
    Abstract: The present invention relates to polyaddition compounds, which are solid below 40° C. and liquid above 125° C., are prepared by the reaction of an isocyanate component containing uretdione groups with a polyol containing ester and/or carbonate groups, other than hydroxypivalic acid neopentylglycol ester, and have a) an average isocyanate functionality of 2.0 to 8.0 and a content of free isocyanate groups (calculated as NCO; molecular weight=42) of 2.1 to 6.0 wt. %, b) a content of uretdione groups (calculated as C2N2O2; molecular weight=84) of 10 to 19 wt. %, c) a content of urethane groups (calculated as —NH—CO—O; molecular weight=59) of 10 to 17 wt. % and d) a content of ester groups —CO—O (calculated as —CO—O; molecular weight=44) and/or carbonate groups —O—CO—O (calculated as —CO—O; molecular weight=44) of 1 to 17 wt. %.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: October 2, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Josef Laas, Ulrich Freudenberg, Reinhard Halpaap, Michael Grahl