Patents by Inventor Michael J. Heben
Michael J. Heben has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11189748Abstract: Methods for forming electrical contacts with CdTe layers, methods for forming photovoltaic devices, methods for passivating a CdTe surface, and photovoltaic devices are described.Type: GrantFiled: April 29, 2020Date of Patent: November 30, 2021Assignee: The University of ToledoInventors: Michael J. Heben, Adam B. Phillips, Fadhil K. Alfadhili, Randall J. Ellingson, Ebin Bastola, Dipendra Pokhrel, Kamala Khanal Subedi
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Publication number: 20200343403Abstract: Methods for forming electrical contacts with CdTe layers, methods for forming photovoltaic devices, methods for passivating a CdTe surface, and photovoltaic devices are described.Type: ApplicationFiled: April 29, 2020Publication date: October 29, 2020Applicant: The University of ToledoInventors: Michael J. Heben, Adam B. Phillips, Fadhil K. Alfadhili, Randall J. Ellingson, Ebin Bastola, Dipendra Pokhrel, Kamala Khanal Subedi
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Patent number: 10043922Abstract: A photovoltaic cell structure is disclosed that includes a back contact layer that includes single wall carbon nanotube elements. The single wall carbon nanotube (SWNT) back contact is in electrical communication with an adjacent semiconductor layer and provides a buffer characteristic that impedes elemental metal migration from the back contact into the semiconductor active layers. In one embodiment, the SWNT back contact includes a semiconductor characteristic and a buffer characteristic. In another embodiment, the SWNT back contact further includes a metallic characteristic.Type: GrantFiled: August 13, 2013Date of Patent: August 7, 2018Assignee: The University Of ToledoInventors: Michael J. Heben, Adam B. Phillips, Rajendra R. Khanal, Victor V. Plotnikov, Alvin D. Compaan
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Publication number: 20150221790Abstract: A photovoltaic cell structure is disclosed that includes a back contact layer that includes single wall carbon nanotube elements. The single wall carbon nanotube (SWNT) back contact is in electrical communication with an adjacent semiconductor layer and provides a buffer characteristic that impedes elemental metal migration from the back contact into the semiconductor active layers. In one embodiment, the SWNT back contact includes a semiconductor characteristic and a buffer characteristic. In another embodiment, the SWNT back contact further includes a metallic characteristic.Type: ApplicationFiled: August 13, 2013Publication date: August 6, 2015Applicant: The University of ToledoInventors: Michael J. Heben, Adam B. Phillips, Rajendra R. Khanal, Victor V. Plotnikov, Alvin D. Compaan
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Patent number: 8840724Abstract: The invention relates to a chemical vapor deposition process for the continuous growth of a carbon single-wall nanotube where a carbon-containing gas composition is contacted with a porous membrane and decomposed in the presence of a catalyst to grow single-wall carbon nanotube material. A pressure differential exists across the porous membrane such that the pressure on one side of the membrane is less than that on the other side of the membrane. The single-wall carbon nanotube growth may occur predominately on the low-pressure side of the membrane or, in a different embodiment of the invention, may occur predominately in between the catalyst and the membrane. The invention also relates to an apparatus used with the carbon vapor deposition process.Type: GrantFiled: September 23, 2008Date of Patent: September 23, 2014Assignee: Honda Motor Co., Ltd.Inventors: Leonid Grigorian, Louis Hornyak, Anne C. Dillon, Michael J. Heben
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Publication number: 20090013931Abstract: The invention relates to a chemical vapor deposition process for the continuous growth of a carbon single-wall nanotube where a carbon-containing gas composition is contacted with a porous membrane and decomposed in the presence of a catalyst to grow single-wall carbon nanotube material. A pressure differential exists across the porous membrane such that the pressure on one side of the membrane is less than that on the other side of the membrane. The single-wall carbon nanotube growth may occur predominately on the low-pressure side of the membrane or, in a different embodiment of the invention, may occur predominately in between the catalyst and the membrane. The invention also relates to an apparatus used with the carbon vapor deposition process.Type: ApplicationFiled: September 23, 2008Publication date: January 15, 2009Applicants: HONDA MOTOR CO., LTD., NATIONAL RENEWABLE ENERGY LABORATORYInventors: Leonid Grigorian, Louis Hornyak, Anne C. Dillon, Michael J. Heben
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Patent number: 7448441Abstract: A carbon nanotube heat-exchange system (10) and method for producing the same. One embodiment of the carbon nanotube heat-exchange system (10) comprises a microchannel structure (24) having an inlet end (30) and an outlet end (32), the inlet end (30) providing a cooling fluid into the microchannel structure (24) and the outlet end (32) discharging the cooling fluid from the microchannel structure (24). At least one flow path (28) is defined in the microchannel structure (24), fluidically connecting the inlet end (30) to the outlet end (32) of the microchannel structure (24). A carbon nanotube structure (26) is provided in thermal contact with the microchannel structure (24), the carbon nanotube structure (26) receiving heat from the cooling fluid in the microchannel structure (24) and dissipating the heat into an external medium (19).Type: GrantFiled: September 17, 2002Date of Patent: November 11, 2008Assignee: Alliance for Sustainable Energy, LLCInventors: Terry Joseph Hendricks, Michael J. Heben
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Patent number: 7431965Abstract: The invention relates to a chemical vapor deposition process for the continuous growth of a carbon single-wall nanotube where a carbon-containing gas composition is contacted with a porous membrane and decomposed in the presence of a catalyst to grow single-wall carbon nanotube material. A pressure differential exists across the porous membrane such that the pressure on one side of the membrane is less than that on the other side of the membrane. The single-wall carbon nanotube growth may occur predominately on the low-pressure side of the membrane or, in a different embodiment of the invention, may occur predominately in between the catalyst and the membrane. The invention also relates to an apparatus used with the carbon vapor deposition process.Type: GrantFiled: November 3, 2003Date of Patent: October 7, 2008Assignee: Honda Motor Co., Ltd.Inventors: Leonid Grigorian, Louis Hornyak, Anne C Dillon, Michael J Heben
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Publication number: 20080206463Abstract: The invention relates to a chemical vapor deposition process for the continuous growth of a carbon single-wall nanotube where a carbon-containing gas composition is contacted with a porous membrane and decomposed in the presence of a catalyst to grow single-wall carbon nanotube material. A pressure differential exists across the porous membrane such that the pressure on one side of the membrane is less than that on the other side of the membrane. The single-wall carbon nanotube growth may occur predominately on the low-pressure side of the membrane or, in a different embodiment of the invention, may occur predominately in between the catalyst and the membrane. The invention also relates to an apparatus used with the carbon vapor deposition process.Type: ApplicationFiled: November 3, 2003Publication date: August 28, 2008Inventors: Leonid Grigorian, Louis Hornyak, Anne C. Dillon, Michael J. Heben
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Patent number: 7361430Abstract: The present invention discloses a carbon nanotube (SWNT)-polymer composite actuator and method to make such actuator. A series of uniform composites was prepared by dispersing purified single wall nanotubes with varying weight percents into a polymer matrix, followed by solution casting. The resulting nanotube-polymer composite was then successfully used to form a nanotube polymer actuator.Type: GrantFiled: April 8, 2004Date of Patent: April 22, 2008Assignee: The United States of America as represented by the United States Department of EnergyInventors: Thomas Gennett, Ryne P. Raffaelle, Brian J. Landi, Michael J. Heben
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Patent number: 7160530Abstract: Metal-doped single-walled carbon nanotubes and production thereof. The metal-doped single-walled carbon nanotubes may be produced according to one embodiment of the invention by combining single-walled carbon nanotube precursor material and metal in a solution, and mixing the solution to incorporate at least a portion of the metal with the single-walled carbon nanotube precursor material. Other embodiments may comprise sputter deposition, evaporation, and other mixing techniques.Type: GrantFiled: April 4, 2002Date of Patent: January 9, 2007Assignee: Midwest Research InstituteInventors: Anne C. Dillon, Michael J. Heben, Thomas Gennett, Philip A. Parilla
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Publication number: 20040194944Abstract: A carbon nanotube heat-exchange system (10) and method for producing the same. One embodiment of the carbon nanotube heat-exchange system (10) comprises a microchannel structure (24) having an inlet end (30) and an outlet end (32), the inlet end (30) providing a cooling fluid into the microchannel structure (24) and the outlet end (32) discharging the cooling fluid from the microchannel structure (24). At least one flow path (28) is defined in the microchannel structure (24), fluidically connecting the inlet end (30) to the outlet end (32) of the microchannel structure (24). A carbon nanotube structure (26) is provided in thermal contact with the microchannel structure (24), the carbon nanotube structure (26) receiving heat from the cooling fluid in the microchannel structure (24) and dissipating the heat into an external medium (19).Type: ApplicationFiled: April 8, 2004Publication date: October 7, 2004Inventors: Terry Joseph Hendricks, Michael J. Heben
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Publication number: 20040101466Abstract: Metal-doped single-walled carbon nanotubes and production thereof. The metal-doped single-walled carbon nanotubes may be produced according to one embodiment of the invention by combining single-walled carbon nanotube precursor material and metal in a solution, and mixing the solution to incorporate at least a portion of the metal with the single-walled carbon nanotube precursor material. Other embodiments may comprise sputter deposition, evaporation, and other mixing techniques.Type: ApplicationFiled: May 7, 2003Publication date: May 27, 2004Inventors: Anne C Dillon, Michael J Heben, Thomas Gennett, Philip A Parilla
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Publication number: 20020172767Abstract: The invention relates to a chemical vapor deposition (“CVD”) process for the growth of single-wall carbon nanotube (“SWNT”). According to the invention, methane gas is decomposed in the presence of a supported iron-containing catalyst to grow SWNT material within a growth temperature range from about 670° C. to about 800° C. The process provides higher yields of SWNT material and reduces the formation of amorphous carbon. Thus, the SWNT material produced according to the invention will minimize problems associated with purification steps, such as breakage or damage to the SWNT material. The invention provides for the manufacture of SWNT material at lower temperatures, which not only results in lower equipment and processing costs, but also provides compatibility with substrates that cannot be used at higher temperatures. The invention may be used to provide an inexpensive process for the mass production of SWNT material.Type: ApplicationFiled: April 5, 2001Publication date: November 21, 2002Inventors: Leonid Grigorian, Louis Hornyak, Anne Dillon, Michael J. Heben
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Publication number: 20020150529Abstract: A method of processing single-walled carbon nanotubes (SWNTs) in the formation of superbundles or for use in hydrogen storage, or both, is provided comprising the steps of mixing a SWNT substrate in a solvent solution into a suspension, and agitating the suspension using an ultrasonic energy means.Type: ApplicationFiled: April 3, 2002Publication date: October 17, 2002Inventors: Anne C. Dillon, Thomas Gennett, Michael J. Heben
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Publication number: 20020081380Abstract: Highly purified single-wall carbon nanotubes (SWNTs) and production thereof. The highly purified single-wall carbon nanotubes may be produced according to one embodiment of the invention by generating a crude SWNT material having a carbon nanotube fraction and a non-nanotube carbon fraction, refluxing the crude SWNT material in an acid solution to redistribute the non-nanotube carbon fraction as a uniform carbon coating on the carbon nanotube fraction, and oxidizing the refluxed SWNT material to remove the uniform carbon coating formed thereon. Preferably, metal is also removed during reflux.Type: ApplicationFiled: February 12, 2002Publication date: June 27, 2002Inventors: Anne C. Dillon, Thomas Gennett, Michael J. Heben