Patents by Inventor Michael-Joachim Brekner

Michael-Joachim Brekner has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6593452
    Abstract: The present invention relates to a fiber which comprises at least one partly crystalline cycloolefin copolymer which can be prepared by polymerization of a symmetrical polycyclic olefin, an acyclic olefin and, if desired, a monocyclic olefin in the presence of a catalyst system comprising an aluminoxane and a metallocene compound of the formula
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: July 15, 2003
    Assignee: Ticona GmbH
    Inventors: Frank Osan, Michael-Joachim Brekner
  • Publication number: 20030045656
    Abstract: The present invention relates to a fiber which comprises at least one partly crystalline cycloolefin copolymer which can be prepared by polymerization of a symmetrical polycyclic olefin, an acyclic olefin and, if desired, a monocyclic olefin in the presence of a catalyst system comprising an aluminoxane and a metallocene compound of the formula 1
    Type: Application
    Filed: May 21, 2002
    Publication date: March 6, 2003
    Inventors: Frank Osan, Michael-Joachim Brekner
  • Patent number: 6469114
    Abstract: Disclosed are compounds of the following core structure, and their use as polymerization catalysts: wherein M1 is a group lVb transition metal, R5 is a substituted aryl group, and Ra forms a heteroatom-containing ring fused to the cyclopentadienyl ring.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: October 22, 2002
    Assignee: Basell Polyolefins GmbH
    Inventors: Jörg Schottek, Roland Kratzer, Andreas Winter, Volker Fraaije, Michael-Joachim Brekner, Markus Oberhoff
  • Patent number: 6458919
    Abstract: The present invention relates to a fiber which comprises at least one partly crystalline cycloolefin copolymer which can be prepared by polymerization of a symmetrical polycyclic olefin, an acyclic olefin and, if desired, a monocyclic olefin in the presence of a catalyst system comprising an aluminoxane and a metallocene compound of the formula
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: October 1, 2002
    Assignee: Ticona GmbH
    Inventors: Frank Osan, Michael-Joachim Brekner
  • Patent number: 6262197
    Abstract: The present invention relates to a metallocene compound containing at least two metallocene fragments L—MX2—L which are different from one another and having the formula I where B is a bridging unit, m is an integer from 2 to 100,000, M is a metal atom of group IVb, Vb or VIb of the Periodic Table of the Elements, X are identical or different in one metallocene fragment L—MX2—L and are each, independently of one another, hydrogen, a C1-C40-hydrocarbon-containing group, an OH group, a halogen atom or a pseudohalogen, L are identical or different in one metallocene fragment and are each, independently of one another, a &pgr; ligand or another electron donor. The metallocene compound can advantageously be used as a catalyst component for olefin polymerization.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: July 17, 2001
    Assignee: Targor GmbH
    Inventors: Michael Aulbach, Michael-Joachim Brekner, Frank Küber, Roland Zenk
  • Patent number: 6214951
    Abstract: Thermoplastic cycloolefin copolymers (COCs) having high tear strength and low optical attenuation, a process for their preparation, and their use as optical waveguides (optical fibers).
    Type: Grant
    Filed: April 28, 1997
    Date of Patent: April 10, 2001
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Hellmuth Deckers, Frank Osan
  • Patent number: 6169052
    Abstract: Chemically homogeneous cycloolefin copolymers of polycyclic olefins, such as, for example, norbornene or tetracyclododecene, with cycloolefins and/or acyclic olefins are obtained without ring opening and in a high space-time yield if a catalyst system is used which comprises an aluminoxane and a stereorigid metallocene compound of an element from groups IVb to VIb, of the formula the part of the metallocene molecule formed by M1 and the substituents R16-R17 having C1-symmetry or being in the meso-form.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: January 2, 2001
    Assignee: Targor GmbH
    Inventors: Michael-Joachim Brekner, Frank Osan, J{umlaut over (u)}rgen Rohrmann, Martin Antberg
  • Patent number: 5789492
    Abstract: For optical applications, transparent amorphous thermo-plastics, such as polyaryl ether ketones, are of considerable interest. However, polyaryl ether ketones have inadequate UV stability and weathering resistance while amorphous polyaryl esters do not have these negative properties. The properties can be improved by means of polymer alloys, giving weathering-resistant materials from homogeneously mixed polymers which comprise at least one amorphous polyaryl ether ketone and at least one amorphous polyaryl ester.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: August 4, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Hansotto Drotloff, Otto Hermann-Schonherr, Arnold Schneller
  • Patent number: 5744664
    Abstract: A substrate for liquid-crystal displays is formed from polymers of polycyclic olefins by polymerization, without ring opening, of at least one monomer of the formula (I), (II), (III), (IV), (V) or (VI). The novel use of cycloolefin copolymers as substrate material facilitates process temperatures of above 180.degree. C. in the production of displays. Cycloolefin copolymers are lighter and less brittle than glass. Compared with other plastics, they have advantages in photoelastic constants, thermal expansion, hardness, density, transparency, water absorption and with respect to birefringence. Furthermore, they have high resistance to polar solvents.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: April 28, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Dietmar Jungbauer
  • Patent number: 5733991
    Abstract: Cycloolefin polymers having a high viscosity number are obtained by polymerization of a polycyclic olefin and, if desired, an acyclic olefin and/or a monocyclic olefin in the presence of a catalyst system which comprises an aluminoxane and a metallocene compound of the formula ##STR1## in which R.sup.16 is fluorenyl or indenyl and R.sup.17 is cyclopentadienyl and the bridge R.sup.18 contains silicon.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: March 31, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Rohrmann, Michael-Joachim Brekner, Frank Kuber, Frank Osan, Thomas Weller
  • Patent number: 5719095
    Abstract: The invention relates to a process for the preparation of a catalyst system supported on a support. The catalyst system is built up from at least one catalyst and at least one cocatalyst. The catalyst and the cocatalyst supported on a support material are brought into contact in a suspension solution. The fixing of the catalyst to the support is carried out under the action of microwaves.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: February 17, 1998
    Assignee: Hoechst AG
    Inventors: Michael-Joachim Brekner, Bernd Bachmann, Frank Osan, Klaus Alberti, Andreas Winter
  • Patent number: 5707728
    Abstract: A magneto-optical recording medium containing a substrate formed from polymers which are prepared by polymerization without ring cleavage, of monomers comprising polycyclic olefins, such as norbornene, results in a recording medium having increased thermal dimensional stability and resistance to hydrolysis, and decreased moisture absorption and birefringence.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: January 13, 1998
    Assignee: Ticona GmbH
    Inventors: Michael-Joachim Brekner, Egon Hellstern, Christoph Weber
  • Patent number: 5646220
    Abstract: Cycloolefin block copolymers, which in particular are suitable as phase promoters, are preferably obtained by copolymerization of polycyclic olefins, such as norbornene, with acyclic olefins, such as ethylene, by, at a molecular weight distribution M.sub.w /M.sub.n of the polymer block forming of less than 2, changing the reaction conditions one or more times in such a way that the monomer/comonomer ratio changes by at least 10% or a further polymerizable monomer is metered into the monomer or the monomers.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: July 8, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Frank Osan, Jurgen Rohrmann
  • Patent number: 5637400
    Abstract: Thermoplastic cycloolefin copolymers (COCs) having low melt viscosity and low optical attenuation, a process for their preparation, and their use as optical waveguides (optical fibers).
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: June 10, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Hellmuth Deckers, Frank Osan
  • Patent number: 5602219
    Abstract: Transparent cycloolefin copolymers having a high tensile strength are obtained by polymerization of a polycyclic olefin, ethylene and, if desired, an acyclic olefin and/or a monocylcic olefin in the presence of a catalyst system which comprises a cocatalyst and an asymmetrical metallocene compound of the formula ##STR1## in which R.sup.16 is cyclopentadienyl and R.sup.17 is indenyl.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: February 11, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael Aulbach, Michael-Joachim Brekner, Frank K uber, Frank Osan, Thomas Weller, J urgen Rohrmann
  • Patent number: 5583192
    Abstract: A flexible single- or multilayer non-oriented or mono- or biaxially oriented film in which at least one layer comprises a cycloolefin copolymer, wherein the cycloolefin copolymer has a mechanical loss factor (tan .delta.) of .gtoreq.0.015 at 50.degree. C. below the glass transition temperature.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: December 10, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Cynthia Bennett, Michael-Joachim Brekner, Otto Herrmann-Schoenherr, Frank Osan
  • Patent number: 5552504
    Abstract: A film including semi-crystalline cycloolefin copolymers which have a content of catalyst residues of <100 ppm and their use as capacitor films, reproduction films, film keyboards and film switches, substrates for liquid crystal displays and packaging films.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: September 3, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Cynthia Bennett, Michael-Joachim Brekner, Jochen Coutandin, Otto Herrmann-Schoenherr, Frank Osan
  • Patent number: 5545829
    Abstract: Process for preparing cycloolefin copolymers Process for preparing cycloolefin polymers from cyclic and acylcic olefin monomers using a catalyst system in a reaction space, wherein the residence time of the monomers in the reaction space is separated from the residence time of the catalyst system in the reaction space.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: August 13, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Michael-Joachim Brekner, Frank Osan
  • Patent number: 5534606
    Abstract: A rigid single- or multilayer non-oriented or mono- or biaxially oriented film in which at least one layer comprises a cycloolefin copolymer, wherein the cycloolefin copolymer has an intrinsic E modulus (E.sub.i) which has the following dependence on the glass transition temperature T.sub.g :E.sub.i =(0.0025[GPa/.degree.C.].times.T.sub.g [.degree.C.])+B[GPa]where B=2.93-3.19 and T.sub.g is the glass transition temperature.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: July 9, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Cynthia Bennett, Michael-Joachim Brekner, Otto Herrmann-Schoenherr, Frank Osan
  • Patent number: 5498677
    Abstract: A material of a cycloolefin copolymer has a structure of alternating cycloolefin sequences, and has crystallinity in a temperature range from 210.degree. to 320.degree. C. The cycloolefin is prepared by polymerization of at least one polycyclic olefin, monocyclic and/or acyclic olefin with an open-chain olefin using a catalyst of a metallocene and an aluminoxane.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: March 12, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Thomas Weller, Michael-Joachim Brekner, Frank Osan