Abstract: A process for producing an object from a precursor comprises the steps of: depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; repeating step II) until the precursor is formed; wherein the depositing of a free-radically crosslinked resin at least in step II) is effected by exposure and/or irradiation of a selected region of a free-radically crosslinkable resin corresponding to the respectively selected cross section of the object and wherein the free-radically crosslinkable resin has a viscosity (23° C., DIN EN ISO 2884-1) of ?5 mPas to ?100000 mPas.

Abstract: The present invention relates to hydrophilized polyurethanes having a particularly high content of hydroxy-functional, unsaturated triglycerides, to a process for preparing polyurethane dispersions based thereon, to the use of the dispersions as binders in oxidatively drying coating materials having particularly high chemical resistance, and to articles and substrates coated with these coating materials.

Abstract: The present invention relates to a process for the preparation of highly reactive, low-viscosity and water-dilutable polyisocyanate reaction products which contain activated groups which react, by polymerization, with ethylenically unsaturated compounds under the action of actinic radiation. The present invention furthermore relates to a process for the preparation of such products and their use.

Abstract: The present invention provides a process for preparing radiation-curing allophanates having residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, wherein (A) compounds containing isocyanate groups, (B) hydroxy-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups) and (C) optionally further compounds containing NCO-reactive groups, also optionally in the presence of a catalyst, are used to form NCO-group-containing urethanes having radiation-curing groups, which are subsequently reacted, without further addition of compounds containing isocyanate groups, in the presence of an allophanatization catalyst, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and, where used, C) being 1.45:1.0 to 1.1:1.0.

Abstract: The present invention provides a process for preparing radiation-curing allophanates having residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, wherein (A) compounds containing isocyanate groups, (B) hydroxy-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups) and (C) optionally further compounds containing NCO-reactive groups, also optionally in the presence of a catalyst, are used to form NCO-group-containing urethanes having radiation-curing groups, which are subsequently reacted, without further addition of compounds containing isocyanate groups, in the presence of an allophanatization catalyst, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and, where used, C) being 1.45:1.0 to 1.1:1.0.

Abstract: The present invention provides novel polyurethane-based wound dressing foams, obtained by foaming and curing silane-terminated polyurethanes.

Abstract: The present invention relates to a process for the preparation of low-viscosity polyisocyanate reaction products which contain allophanate groups, can be readily emulsified in water and contain activated groups which react, by polymerization, with ethylenically unsaturated compounds under the action of actinic radiation. The present invention furthermore relates to the products which can be prepared by the process according to the invention and their use.

Abstract: The present invention relates to a process for the preparation of highly reactive, low-viscosity and water-dilutable polyisocyanate reaction products which contain activated groups which react, by polymerization, with ethylenically unsaturated compounds under the action of actinic radiation. The present invention furthermore relates to a process for the preparation of such products and their use.

Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.

Abstract: Processes comprising: (a) providing a composition comprising at least one silane-terminated polyurethane preploymer prepared by a process comprising: reacting (A) at least one polyether having a number average molecular weight (Mn) of 2000 to 8000 g/mol, and comprising 10 to 30 wt % ethylene oxide units based on all alkylene oxide units in the polyether; with (B) at least one isocyanate and alkoxysilane group-containing compound of the formula (I): wherein each of X, Y, and Z independently represents a C1-C8 alkyl or a C1-C8 alkoxy residue, with the proviso that at least one of X, Y, and Z represents a C1-C8 alkoxy group; and wherein R is an at least bifunctional, organic residue; (b) foaming the composition, and (c) curing the foamed composition in the presence of water; and uses of polyurethane foams prepared thereby.

Abstract: This invention relates to DVDs made from polycarbonate and a special UV curable bonder material consisting of A) an urethane acrylate oligomer as binder, which is the reaction product of i) one or more polyisocyanates and ii) one or more hydroxyfunctional lactone ester (meth)acrylates having a number average molecular weight of from 200 g/mol to 2000 g/mol and having the formula: CH2?C(R1)—C(O)—O—R2—[O—C(O)—R3]n—OH wherein, n is an integer from 1 to 5, R1 is hydrogen or methyl, R2 represents an alkylene group or substituted alkylene group having from 2 to 10 carbon atoms and R3 represents a straight or branched chain alkylene group of from 3 to 8 carbon atoms, and which may be substituted with one or more alkyl groups having from 1 to 12 carbon atoms, B) a reactive thinner, comprising of mono functional acrylates and/or (meth)acrylates C) a photo initiator and D) optional additives which offers improved performance at high data transfer rates.

Abstract: The invention relates to prepolymers containing alkoxysilane groups based on special, low-viscosity polyester polyols, which exhibit particularly high tensile strength, a process for the production thereof and their use as a binder for adhesives, primers or coatings.

Abstract: This invention relates to DVDs made from polycarbonate and a special UV curable bonder material consisting of A) an urethane acrylate oligomer as binder, which is the reaction product of i) one or more polyisocyanates and ii) one or more hydroxyfunctional lactone ester (meth)acrylates having a number average molecular weight of from 200 g/mol to 2000 g/mol and having the formula: CH2?C(R1)—C(O)—O—R2—[O—C(O)—R3]n—OH wherein, n is an integer from 1 to 5, R1 is hydrogen or methyl, R2 represents an alkylene group or substituted alkylene group having from 2 to 10 carbon atoms and R3 represents a straight or branched chain alkylene group of from 3 to 8 carbon atoms, and which may be substituted with one or more alkyl groups having from 1 to 12 carbon atoms, B) a reactive thinner, comprising of mono functional acrylates and/or (meth)acrylates C) a photo initiator and D) optional additives which offers improved performance at high data transfer rates.

Abstract: The present invention relates to a continuous process for preparing hydroxyalkyl (meth)acrylates, more particularly those hydroxyalkyl (meth)acrylates which have more than one (meth)acrylate group per molecule.

Abstract: The invention relates to a continuous process for preparing radiation-curable prepolymers containing urethane groups, more particularly urethane acrylates.

Abstract: The present invention relates to reactive diluents for moisture-curing coating systems containing silane groups. The invention further relates to a method for the production of said diluents, and to the use thereof in coating agents, adhesives and sealants.

Abstract: The present invention relates to a process for preparing low-viscosity reaction products of polyisocyanates containing activated, ethylenically unsaturated groups which react, with polymerization, on exposure to actinic radiation.

Abstract: The present invention relates to a process for preparing low-viscosity reaction products of polyisocyanates containing activated groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation.

Abstract: The present invention relates to a process for preparing alkoxysilane-functional prepolymers by reacting A) 1.0 equivalent of a polyol component have a number average molecular weight of 3000 g/mol to 20,000 g/mol and containing one or more polyoxyalkylene polyols or polyoxyalkylene polyol prepolymers with B) 1.05 to 1.50 equivalent of an isocyanate- and alkoxysilane-functional compound of formula I) wherein X, Y, and Z independently of one another are linear or branched C1-C8 alkyl or C1-C8 alkoxy radicals, wherein at least one of the radicals is a C1-C8 alkoxy group and R is an organic radical having a functionality of at least two, and subsequently further reacting the remaining free NCO groups by allophanatization or by reaction with C) an isocyanate-reactive component. The present invention also relates to the alkoxysilane-functional prepolymers obtained by the process of the invention.

Abstract: The invention relates to prepolymers containing alkoxysilane groups based on special, low-viscosity polyester polyols, which exhibit particularly high tensile strength, a process for the production thereof and their use as a binder for adhesives, primers or coatings.