Abstract: A method of controlling a catalytic exhaust system having a first catalytic unit located upstream of a second catalytic unit includes i) providing a relationship between the temperature of the first catalytic unit, an amount of NH3 stored in the second catalytic unit, and a corresponding limit value of the amount of NH3 permitted in the first catalytic unit; ii) measuring or estimating the amount of NH3 in the second catalytic unit; iii) measuring or estimating the temperature of the first catalytic unit; iv) using the relationship and measured/estimated parameters of steps ii and iii to provide the limit value for the amount of NH3 to be stored in the first catalytic unit; and v) using the parameter from iv in the control of the catalytic exhaust system.

Abstract: The present invention is directed to reaction mixtures comprising a water-surfactant mixture, wherein the catalyst comprises a compound with solubilizing groups. This technology improves the solubility of the reaction components in the water-surfactant mixture and thereby, greatly increases the productivity and selectivity of the chemical reaction.

Abstract: The present invention is directed to reaction mixtures comprising a water-surfactant mixture and a co-solvent. This technology reduced the amount of organic solvents needed for performing chemical reactions. Furthermore, compared to reaction mixtures lacking the co-solvent, solvation of the reactants and products of the chemical reaction is greatly enhanced, leading to a significantly improved yield, purity, reproducibility and robustness.

Abstract: The present invention is directed to aqueous reaction mixtures for enzymatic synthesis reactions comprising a surfactant. The surfactant in the reaction mixture increases stability and yield of the enzymatic reaction. Furthermore, method for performing an enzymatic reaction using said aqueous reaction mixtures are provided.

Abstract: A system of controlling ammonia levels in a catalytic exhaust system comprising: means to provide a target value for ammonia slip/ammonia output from said system or a catalytic unit of said system; first comparison means to compare said target value with a feedback value to provide a command value based on said comparison, and means to control the dosing of a reducing agent such as urea into said exhaust system based on said command value; means to input said command value to a transfer function or model to provide an estimated value of ammonia slip/ammonia output from said catalytic unit/system; means to measure actual ammonia slip/ammonia output from said unit/system; second comparison means to compare said actual value with said estimated value; means to provide said feedback value based on the output from said comparison means.

Abstract: A method of controlling combustion in an internal combustion engine with exhaust after treatment device is proposed, wherein upon detection of a request for a regeneration event of the exhaust after treatment device, a regeneration combustion mode comprising a pilot injection and a retarded main injection is operated. During the regeneration combustion mode the injection timing of the main injection is controlled so that its retard is not later than a retard threshold that is determined as the maximum timing retard to provide the desired torque, but with an injected fuel quantity not exceeding a maximum fuel quantity given by a stored smoke-limit map.

Abstract: A method of operating an internal combustion engine is proposed, the engine comprising an exhaust system with a DOC and a DPF and, downstream thereof a SCR catalyst. The ECU is configured to allow operation in at least one of a normal mode and a heat-up mode. A predicted temperature evolution of said second exhaust after treatment means is regularly determined based on a thermal model taking into account the thermal inertia of the exhaust system and having as input the current temperatures of the DOC/DPF and SCR. The predicted temperature evolution of SCR is indicative of the temperature that the SCR may reach during a simulated time period in case the operating mode. The engine operating mode is changed depending on the predicted temperature evolution.

Abstract: A selective catalytic reduction (SCR) catalyst control system and method for an engine is disclosed. Urea injection to an SCR catalyst is determined based on an SCR catalyst model, which determines a value of stored NH3 in the SCR catalyst based on the NOx engine emission value, the SCR catalyst temperature, the quantity of urea supplied to the SCR catalyst and a pre-determined efficiency of conversion of NOx gases. A target value of stored NH3 and the value of stored NH3 in the SCR catalyst is then used to determine a stored NH3 differential, which is then used to calculate urea injection.

Abstract: A method of operating an internal combustion engine is proposed, the engine comprising an exhaust system with a DOC and a DPF and, downstream thereof a SCR catalyst. The ECU is configured to allow operation in at least one of a normal mode and a heat-up mode. A predicted temperature evolution of said second exhaust after treatment means is regularly determined based on a thermal model taking into account the thermal inertia of the exhaust system and having as input the current temperatures of the DOC/DPF and SCR. The predicted temperature evolution of SCR is indicative of the temperature that the SCR may reach during a simulated time period in case the operating mode. The engine operating mode is changed depending on the predicted temperature evolution.

Abstract: An oxidation catalyst temperature control system and method for an engine having an exhaust means including an oxidation catalyst is provided. A post fuel calculation means calculates a value representing a post quantity of fuel to be introduced to generate an exothermic reaction in the oxidation catalyst based on a pre-determined desired outlet temperature of the oxidation catalyst, the calculation using a steady state model of the oxidation catalyst, the steady state model utilizing the exhaust mass flow rate and the inlet temperature of the oxidation catalyst and instruction means to instruct the post quantity of fuel to be introduced to the engine.

Abstract: A method for controlling a selective catalytic reduction catalyst in an exhaust line of an internal combustion engine is disclosed, wherein the supply of a quantity of a gaseous ammonia reductant to the SCR catalyst uses a closed-loop SCR catalyst model coupled to a SCR-out NOx sensor that measures a SCR-out NOx emission value. The closed-loop SCR catalyst model uses a relationship linking the measured SCR-out NOx value to the NOx conversion efficiency and the ammonia slip. The actual NH3 emission value and/or an actual SCR-out NOx indicative value are computed based upon differentiation of said relationship.

Abstract: There is presented a method for monitoring an oxidation catalyst in an exhaust line of an internal combustion engine, wherein a catalyst diagnostic event comprises a test cycle during which a conversion capability of the oxidation catalyst is determined based on the exotherm generated by post-injection of fuel. The diagnostic event may only be initiated when the temperature of the oxidation catalyst lies within a predetermined temperature range.

Abstract: A selective catalytic reduction (SCR) catalyst control system and method for an engine is disclosed. Urea injection to an SCR catalyst is determined based on an SCR catalyst model, which determines a value of stored NH3 in the SCR catalyst based on the NOx engine emission value, the SCR catalyst temperature, the quantity of urea supplied to the SCR catalyst and a pre-determined efficiency of conversion of NOx gases. A target value of stored NH3 and the value of stored NH3 in the SCR catalyst is then used to determine a stored NH3 differential, which is then used to calculate urea injection.

Abstract: An oxidation catalyst temperature control system and method for an engine having an exhaust means including an oxidation catalyst is provided. A post fuel calculation means calculates a value representing a post quantity of fuel to be introduced to generate an exothermic reaction in the oxidation catalyst based on a pre-determined desired outlet temperature of the oxidation catalyst, the calculation using a steady state model of the oxidation catalyst, the steady state model utilising the exhaust mass flow rate and the inlet temperature of the oxidation catalyst and instruction means to instruct the post quantity of fuel to be introduced to the engine.