Abstract: A crystalline, amorphous or mixed crystalline and amorphous phosphate compound of the type (M1aM2bM3cM4d)3(PO4)2.xH2O with 0<a<1, 0<b<1, 0<c<1, 0<d<1, a+b+c+d=1 and 0<x<8, wherein M1, M2 and M3 are metals selected from Mn, Fe, Co or Ni, and M4 is one or more metals selected from Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr or La and process for the production thereof.

Abstract: A process for producing a phosphate by: introducing oxidic metal(II)-, metal(III)- metal(IV) or compounds with mixed oxide stages selected from hydroxides, oxides, oxide-hydroxides, oxide-hydrates, carbonates and hydroxide carbonates, of at least one of the metals Mn, Fe, Co and Ni with the elemental forms or alloys of at least one of the metals Mn, Fe, Co and/or Ni into an aqueous medium containing phosphoric acid, and reacting the oxidic metal compounds with elemental forms or alloys of the metals to obtain divalent metal ions, removing solid substances, producing an alkali metal phosphate receiver solution with a pH-value of 5 to 8 and metering the aqueous solution into the receiver solution and at the same time metering a basic aqueous alkali hydroxide solution that the pH-value of the resulting reaction mixture is kept in the region of 5 to 8 to precipitate the desired phosphate.

Abstract: A nutrient composition improved over the state of the art and which releases the nutrients contained therein in a time-controlled manner in the rhizodermal and epidermal region of the plants. The nutrient composition for plants contains at least one mixed-metallic crystalline orthophosphate of the type [Ta(M1 M2 M3 . . . Mx)b(PO4)c.nH2O], wherein T is selected from NH4, K or CH4N2O, M1, M2, M3 . . . Mx are metals selected from Mg, Ca, Mn, Fe, Co, Ni, Cu and Zn, a=0 or 1, wherein b=3 when a=0 and b=1 when a=1 and wherein c=2 when a=0 and c=1 when a=1 and wherein 0<n<9, wherein the mixed-metallic crystalline orthophosphate contains at least two different metals M1, M2, M3 . . . Mx, with the proviso that at least one of said at least two different metals is selected from Mn, Mg and Ca, wherein the total proportion of Mn, Mg and/or Ca in total is in the region of 0.5 to 90 mol-% with respect to the total amount of all metals contained in the mixed-metallic crystalline orthophosphate.

Abstract: A method for producing an iron(III)orthophosphate-carbon composite which contains iron(III)orthophosphate of the general formula FePO4×nH2O (n?2.5), a carbon source being dispersed in a phosphoric aqueous Fe2+ ion-containing solution and orthophosphate-carbon composite being precipitated and removed from the aqueous solution when an oxidant is added to the dispersion.

Abstract: A nutrient composition for biological systems, such as humans, animals, plants or microorganisms includes at least one monometallic or mixed-metallic phosphate of the (M1 M2 M3 . . . Mx)3(PO4)2.aH2O type where 0?a?9, where (M1, M2, M3 . . . Mx) represent the one metal of the monometallic phosphate or the two or more metals of the mixed-metallic phosphate and are selected from Na, K, Mg, Ca, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn and B, with the proviso that at least one of the metals in the phosphate is selected from Mn, Fe, Co and Ni.

Abstract: A manganese(Mn)-bearing monometal phosphate of the type Mn3(PO4)2.3H2O or mixed-metal phosphate of the type (Mnx, Mety)3(PO4)2.3H2O, wherein x+y=1 and Met represents one or more metals selected from Fe, Co, Ni, Sc, Ti, V, Cr, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr, Hf, Re, Ru, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, characterized in that in the X-ray powder diffraction diagram the phosphate has peaks at 10.96±0.05, 12.78±0.17, 14.96±0.13, 17.34±0.15, 18.98±0.18, 21.75±0.21, 22.07±0.11, 22.97±0.10, 25.93±0.25, 26.95±0.30, 27.56±0.10, 29.19±0.12, 29.84±0.21, 30.27±0.12, 34.86±0.21, 35.00±0.20, 35.33±0.30, 35.58±0.10, 35.73±0.12, 42.79±0.45, 43.37±0.45, 44.70±0.15 and 44.93±0.20 degrees two-theta, based on CuK?-radiation.

Abstract: A manganese(Mn)-bearing monometal phosphate of the type Mn3(PO4)2.3H2O or mixed-metal phosphate of the type (Mnx, Mety)3(PO4)2.3H2O, wherein x+y=1 and Met represents one or more metals selected from Fe, Co, Ni, Sc, Ti, V, Cr, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr, Hf, Re, Ru, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, characterised in that in the X-ray powder diffraction diagram the phosphate has peaks at 10.96±0.05, 12.78±0.17, 14.96±0.13, 17.34±0.15, 18.98±0.18, 21.75±0.21, 22.07±0.11, 22.97±0.10, 25.93±0.25, 26.95±0.30, 27.56±0.10, 29.19±0.12, 29.84±0.21, 30.27±0.12, 34.86±0.21, 35.00±0.20, 35.33±0.30, 35.58±0.10, 35.73±0.12, 42.79±0.45, 43.37±0.45, 44.70±0.15 and 44.93±0.20 degrees two-theta, based on CuK?-radiation.

Abstract: A process for producing a phosphate by: introducing oxidic metal(II)-, metal(III)-metal(FV) or compounds with mixed oxide stages selected from hydroxides, oxides, oxide-hydroxides, oxide-hydrates, carbonates and hydroxide carbonates, of at least one of the metals Mn, Fe, Co and Ni with the elemental forms or alloys of at least one of the metals Mn, Fe, Co and/or Ni into an aqueous medium containing phosphoric acid, and reacting the oxidic metal compounds with elemental forms or alloys of the metals to obtain divalent metal ions, removing solid substances, producing an alkali metal phosphate receiver solution with a pH-value of 5 to 8 and metering the aqueous solution into the receiver solution and at the same time metering a basic aqueous alkali hydroxide solution that the pH-value of the resulting reaction mixture is kept in the region of 5 to 8 to precipitate the desired phosphate.

Abstract: A nutrient composition for biological systems, such as humans, animals, plants or microorganisms includes at least one monometallic or mixed-metallic phosphate of the (M1 M2 M3 . . . Mx)3(PO4)2.aH2O type where 0?a?9, where (M1, M2, M3 . . . Mx) represent the one metal of the monometallic phosphate or the two or more metals of the mixed-metallic phosphate and are selected from Na, K, Mg, Ca, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn and B, with the proviso that at least one of the metals in the phosphate is selected from Mn, Fe, Co and Ni.

Abstract: A method for producing an iron(III)orthophosphate-carbon composite which contains iron(III)orthophosphate of the general formula FePO4×nH2O (n?2.5), a carbon source being dispersed in a phosphoric aqueous Fe2+ ion-containing solution and orthophosphate-carbon composite being precipitated and removed from the aqueous solution when an oxidant is added to the dispersion.