Abstract: An electrochemical sensor apparatus and electrochemical sensing method are described, using one or more working electrodes (110) of boron doped diamond (BDD). A cathodic reduction process provides a cathodic measurement and, substantially simultaneously, an anodic oxidation process provides an anodic measurement. A sum of a content of two equilibrium species within an aqueous system is obtained using both the cathodic measurement and the anodic measurement. One example measures total free chlorine by simultaneously measuring hypochlorous acid (HOCl) and hypochlorite ion (OCl-). The BDD working electrode (110) comprises at least one ablated region (115) which introduces non-diamond carbon sp2 material. The ablated region (115) may comprise one or more grooves (114) which are cut into the working surface (112), e.g. by a laser.

Abstract: An article of footwear has ventilation and shock absorption provided by a mechanism which may be constructed within or added to the footwear. A first chamber beneath the heel draws external air through a conduit which includes a one-way valve. As a wearer walks, the heel compresses the first chamber, forcing the air through a special second valve causing directional airflow to a second chamber in a controlled manner thereby absorbing the shock of the heel strike in the same manner a shock absorber functions in an automobile. As weight is transferred from the heel to the ball of the foot, further cushioning is provided by the second chamber. Specifically designed vents connected to the second chamber allow air to be forced into the region of the shoe around the foot. Expansion of the air from these vents affects cooling and drying of the foot through evaporation and convection.