Abstract: Radically post-crosslinked polymers are made by a process comprising the steps of: (1) forming a polyurethane (a*) by reacting a compound (a) with an aliphatic and/or an aromatic isocyanate and a compound (c) wherein compound (a) is the product of the reaction of an epoxidized fatty acid ester and/or an epoxidized triglyceride with acrylic acid and/or methacrylic acid and wherein compound (c) is a polyol ester having two or more C?C double bonds per molecule; (2) forming a crosslinked polyurethane by reacting the polyurethane (a*) with a radical initiator (b). The polymers are useful as components in composites comprised of natural and/or synthetic fibers.

Abstract: Radically post-crosslinked polymers are made by a process comprising the steps of: (1) forming a polyurethane (at) by reacting a compound (a) with an aliphatic and/or an aromatic isocyanate and a compound (c) wherein compound (a) is the product of the reaction of an epoxidized fatty acid ester and/or an epoxidized triglyceride with acrylic acid and/or methacrylic acid and wherein compound (c) is a diallyl phthalate; (2) forming a crosslinked polyurethane by reacting the polyurethane (a*) with a radical initiator (b). The polymers are useful as components in composites comprised of natural and/or synthetic fibers.

Abstract: Radically post-crosslinked polymers are made by a process comprising the steps of: (1) forming a polyurethane (a*) by reacting a compound (a) with an aliphatic and/or an aromatic isocyanate and a compound (c) wherein compound (a) is the product of the reaction of an epoxidized fatty acid ester and/or an epoxidized triglyceride with acrylic acid and/or methacrylic acid and wherein compound (c) is a diallyl phthalate; (2) forming a crosslinked polyurethane by reacting the polyurethane (a*) with a radical initiator (b). The polymers are useful as components in composites comprised of natural and/or synthetic fibers.

Abstract: A process for making a fiber composite involving: (a) providing a natural fiber; (b) providing a matrix material produced by a radical polymerization reaction of: (i) a monomer selected from the group consisting of ring opening products of epoxidized fatty compounds with olefinically unsaturated carboxylic acids, and (ii) a comonomer selected from the group consisting of olefinically unsaturated carboxylic acids; (c) providing a radical initiator; and (d) conducting the radical polymerization reaction of (i) and (ii) in the presence of the natural fiber so that the matrix material envelops the natural fiber, thus producing the fiber composite.

Abstract: Radically post-crosslinked polymers are made by a process comprising the steps of: (1) forming a polyurethane (a*) by reacting a compound (a) with an aliphatic and/or an aromatic isocyanate and a compound (c) wherein compound (a) is the product of the reaction of an epoxidized fatty acid ester and/or an epoxidized triglyceride with acrylic acid and/or methacrylic acid and wherein compound (c) is selected from the group consisting of acrolein, acrylamide, vinyl acetate and styrene; (2) forming a crosslinked polyurethane by reacting the polyurethane (a*) with a radical initiator (b). The polymers are useful as components in composites comprised of natural and/or synthetic fibers.

Abstract: The invention relates to a method for production of radically post-cured polymers. In a first stage, at least one, or several compounds (a), which are the reaction products of epoxidised fatty acid esters and/or epoxidised triglycerides with acrylic acid and/or methacrylic acid, are converted into the corresponding polyurethane (a*) and said polyurethane (a*) is subsequently radically post-cured, in a second stage, in the presence of at least one radical initiator (b), with the additional proviso that, in the second stage, a combination of compounds (a*) with one or several compounds (c) are used, where the compounds (c) are chosen from the group of the reactive anhydrides. The polymers thus obtained are excellent matrix agents for composite materials.

Abstract: Radically post-crosslinked polymers are made by a process comprising the steps of: (1) forming a polyurethane (a*) by reacting a compound (a) with an aliphatic and/or an aromatic isocyanate and a compound (c) wherein compound (a) is the product of the reaction of an epoxidized fatty acid ester and/or an epoxidized triglyceride with acrylic acid and/or methacrylic acid and wherein compound (c) is a polyol ester having two or more C═C double bonds per molecule; (2) forming a crosslinked polyurethane by reacting the polyurethane (a*) with a radical initiator (b). The polymers are useful as components in composites comprised of natural and/or synthetic fibers.