Abstract: Molded articles which include at least one layer of a fluoropolymer and at least one layer of a thermoplastic polymer. More particularly, molded bottles having a layer of a fluoropolymer attached to a layer of a polyethylene via an intermediate adhesive tie layer. The molded articles are preferably formed such that the fluoropolymer layer is either the innermost layer or central layer of the multilayered structure. The adhesives that are employed are useful in adhering layers of dissimilar polymeric materials that are otherwise incompatible and achieve a significantly improved interlayer bond strength between a fluoropolymer layer and a thermoplastic polymer layer.

Abstract: Multilayer sheets and films are provided that include a layer of a fluoropolymer material and a layer of a thermoplastic polymer material. More particularly, an adhesive material and multilayered structures formed therewith are provided in which a layer of a fluoropolymer material is attached to a layer of a cyclic olefin copolymer material. The adhesive material is useful to adhere layers of dissimilar polymeric materials that are otherwise incompatible, and achieves a significantly improved interlayer bond strength between fluoropolymer and thermoplastic polymer layers as compared to the art.