Abstract: Described herein is a method of making a polymer electrolyte membrane, the method comprising: disposing a liquid composition on a substrate, wherein the liquid composition comprises an ionic fluorinated polymer, wherein the ionic fluorinated polymer comprises a plurality of side chains having a protogenic group in a salt form, and wherein the ionic fluorinated polymer has a T(a) of less than 200° C. Such polymer electrolyte membranes may be used in electrochemical cells, such as a flow cell battery.

Abstract: Fluorinated ionomers (i.e., ion conducting polymers) that include a fluorinated polymer backbone with covalently bound pendent groups that include heteropolyacid (HP A) groups, or salts thereof, and perfluorosulfonic acid (PF SA) groups, or salts thereof, as well as polymer electrolyte membranes, fuel cells, and methods.

Abstract: The copolymer includes divalent units represented by formula —[CF2—CF2]—, at least one divalent unit represented by formula (I): and at least one divalent unit independently represented by formula (II): A is —N(RFa)2 or a is non-aromatic, 5- to 8-membered, perfluorinated ring comprising one or two nitrogen atoms in the ring and optionally comprising at least one oxygen atom in the ring, each RFa is independently linear or branched perfluoroalkyl having 1 to 8 carbon atoms and optionally interrupted by at least one catenated O or N atom, each Y is independently —H or —F, with the proviso that one Y may be —CF3, h is 0, 1, or 2, each i is independently 2 to 8, and j is 0, 1, or 2. A catalyst ink and polymer electrolyte membrane including the copolymer are also provided.

Abstract: A fluoropolymer is described comprising pendent groups having the formula: —(CF2)a—(OCbF2b)c—(OCeF2e)—SO2—[NX2—SO2(CF2)f—SO2]d—NX1—SO2—Rf wherein Rf is a perfluoroether and X1 and X2 are independently cationic counterions. Also described are various articles including catalyst ink, polymer electrolyte membranes, and membrane electrode assemblies comprising the fluoropolymer described herein; as well as a method of making a fluoropolymer.

Abstract: Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.

Abstract: Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.

Abstract: The copolymer includes divalent units represented by formula —[CF2—CF2]—, at least one divalent unit represented by formula (I): and at least one divalent unit independently represented by formula (II): A is —N(RFa)2 or a is non-aromatic, 5- to 8-membered, perfluorinated ring comprising one or two nitrogen atoms in the ring and optionally comprising at least one oxygen atom in the ring, each RFa is independently linear or branched perfluoroalkyl having 1 to 8 carbon atoms and optionally interrupted by at least one catenated O or N atom, each Y is independently —H or —F, with the proviso that one Y may be —CF3, h is 0, 1, or 2, each i is independently 2 to 8, and j is 0, 1, or 2. A catalyst ink and polymer electrolyte membrane including the copolymer are also provided.

Abstract: Presently described is a monomer having the formula: wherein n ranges from 2 to 8; Y is F or CmF2m+1; a is 0, or averages 1 to 2; m is independently 1, 2, 3, or 4; and X is F or OH. Also described is a method of making such monomer, various compounds prepared during while making the monomer, fluoropolymers comprising polymerized units of such monomer, fuel cell membranes, membrane electrode assemblies, and methods of making fluoropolymers.

Abstract: Described herein are nitrogen-containing multi-block copolymers, as well as methods for making such multi-block copolymers, and articles comprising such multi-block copolymers. The nitrogen-containing multi-block copolymers contains at least one A block comprising polyisoprene; and at least one B block comprising amino-functionalized polybutadiene, the amino-functionalized polybutadiene comprising nitrogen-containing pendant groups.

Abstract: Described herein is a coating composition comprising: (a) a metal catalyst, wherein the metal catalyst comprises at least one of platinum, ruthenium, iridium, and alloys and combinations thereof; (b) an at least highly fluorinated ionomer comprising a polymer backbone and a plurality of first side chains pendant therefrom, wherein the first side chain comprises at least one protogenic group, wherein the protogenic group is selected from a sulfonic acid, a bis(sulfonyl)imide, a sulfonamide, a sulfonyl methide, and salts and combinations thereof, and wherein the polymer backbone comprises an average of at least 14 carbon atoms between adjacent first side chains along the polymer backbone; and (c) a solvent. Such coating compositions may be used to make electrodes for electrochemical cells and have been shown to have reduced poisoning of the catalyst.

Abstract: Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.

Abstract: Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.

Abstract: Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.

Abstract: Described herein are cationic polymers having a plurality of quaternary amino groups, methods of making such polymers, and uses of such polymers as ion exchange membranes in electrochemical devices.

Abstract: Described herein are nitrogen-containing multi-block copolymers, as well as methods for making such multi-block copolymers, and articles comprising such multi-block copolymers. The nitrogen-containing multi-block copolymers contains at least one A block comprising polyisoprene; and at least one B block comprising amino-functionalized polybutadiene, the amino-functionalized polybutadiene comprising nitrogen-containing pendant groups.

Abstract: A separation membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., a first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g., second liquid), wherein the separation membrane includes a polymeric ionomer that has a highly fluorinated backbone and recurring pendant groups according to the following formula (Formula I): —O—Rf—[—SO2—N?(Z+)—SO2—R—]m—[SO2]n-Q wherein: Rf is a perfluorinated organic linking group; R is an organic linking group; Z+ is H+, a monovalent cation, or a multivalent cation; Q is H, F, —NH, —O-2 Y+, or —CxF2x+1; Y+ is H+, a monovalent cation, or a multivalent cation; x=1 to 4; m=0 to 6; and n=0 or 1; with the proviso that at least one of m or n must be non-zero.

Abstract: A separation membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., a first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g., second liquid), wherein the separation membrane includes a polymeric ionomer that has a highly fluorinated backbone and recurring pendant groups according to the following formula (Formula I): —O—Rf—[—SO2—N?(Z+)—SO2—R—]m—[SO2]n-Q wherein: Rf is a perfluorinated organic linking group; R is an organic linking group; Z+ is H+, a monovalent cation, or a multivalent cation; Q is H, F, —NH2, —NH2, —O?Y+, or —CxF2x+1; Y+ is H+, a monovalent cation, or a multivalent cation; x=1 to 4; m=0 to 6; and n=0 or 1; with the proviso that at least one of morn must be non-zero.

Abstract: The method includes providing a component of an assembly having an interior portion and a peripheral portion and adhering separate strips of an adhesive tape to the peripheral portion of the component to surround the interior portion. The short side of a first strip is positioned adjacent a second strip. The adhesive tape includes an adhesive disposed on a backing, and the adhesive includes an amorphous fluoropolymer. The method further includes applying at least one of heat or pressure to the separate strips such that the adhesive flows seals any gap between the first and second strips and crosslinks. The method can be useful, for example, when the assembly is an electrochemical cell assembly and when the component includes at least one of an electrolyte membrane or a current collector.

Abstract: An automated roll to roll method of making a fuel cell roll good subassembly is described wherein an elongated first subgasket web having a plurality of apertures is moved relative to a plurality of individual electrolyte membranes, each individual electrolyte membrane having a center region. The individual electrolyte membranes are aligned with the first subgasket web so that a center region of each electrolyte membrane is aligned with an aperture of the first subgasket web and the individual electrolyte membranes are attached to the first subgasket web.

Abstract: A separation membrane for selectively separating (e.g., pervaporating) a first fluid (e.g., a first liquid) from a mixture comprising the first fluid (e.g., first liquid) and a second fluid (e.g.