Patents by Inventor Michel Armand

Michel Armand has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20250210707
    Abstract: A polymer electrolyte for a battery cell. The polymer electrolyte includes or substantially consists of a polymaleimide copolymer. The polymaleimide copolymer includes or substantially consists of first polymaleimide repeat units and second polymaleimide repeat units, wherein the first polymaleimide repeat units and the second polymaleimide repeat units are covalently bonded to one another.
    Type: Application
    Filed: November 13, 2024
    Publication date: June 26, 2025
    Applicant: Belenos Clean Power Holding AG
    Inventors: Maria MARTINEZ-IBANEZ, Michel ARMAND, Alexander SANTIAGO SANCHEZ, David FRAILE INSAGURBE, Eduardo SANCHEZ DIEZ, Itziar ALDALUR CEBERIO, Oihane ZUGAZUA GANADO, Luca PORCARELLI, Daniele PEREGO
  • Publication number: 20250210706
    Abstract: A polymer electrolyte for a battery cell comprising i) a first polymaleimide polymer comprising first polymaleimide repeat units, wherein the first polymaleimide repeat units are according to R3(Q)?, wherein R3, individually, is a polyether or C(H)h(CxH2x+1)i((CH2)?)j(CH2OC(O)(CH2)?)k, wherein i is between 0 and 2; j and k, individually, are between 0 and 4; h is 4-i-j-k; h+i is between 0 and 2; x is between 1 and 6; L) is between 1 and 10; ? is between 1 and 20; ?, individually, is at least 2; and Q, individually, is according to a particular formula.
    Type: Application
    Filed: October 22, 2024
    Publication date: June 26, 2025
    Applicant: Belenos Clean Power Holding AG
    Inventors: Maria MARTINEZ-IBANEZ, Michel ARMAND, Alexander SANTIAGO SANCHEZ, David FRAILE INSAGURBE, Eduardo SANCHEZ DIEZ, Itziar ALDALUR CEBERIO, Oihane ZUGAZUA GANADO, Asier FERNANDEZ DE ANASTRO, Luca PORCARELLI, Daniele PEREGO
  • Patent number: 12322801
    Abstract: Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds may be obtained by a direct synthesis embodying a hydrothermal method. The method may include preparing an aqueous mixture including a M-containing compound, a M?-containing compound and a M?-containing compound to obtain a M-M?-M? mixture; adding a P-containing compound to the mixture M-M?-M? mixture to obtain a M-M?-M?-P mixture; adding a Na-containing compound to the M-M?-M?-P mixture to obtain a Na-M-M?-M?-P mixture; and introducing the Na-M-M?-M?-P mixture into an autoclave to perform crystal growth and obtain the compound of general formula NahMiM?jM?kPO4.
    Type: Grant
    Filed: December 22, 2022
    Date of Patent: June 3, 2025
    Assignee: HYDRO-QUÉBEC
    Inventors: Montse Galceran Mestres, Montse Casas-Cabanas, Abdelbast Guerfi, Michel Armand, Teofilo Rojo, Karim Zaghib, Andrea Paolella
  • Publication number: 20250087747
    Abstract: Solid state electrolytes having ionic compounds derived from sulfonimides have extended delocalization of the anionic charge and high total ionic conductivity. A secondary electrochemical cell or a secondary battery has the solid electrolyte. A vehicle, an electronic device, or an electrical grid comprising has at least one of the secondary electrochemical cell or the secondary battery.
    Type: Application
    Filed: December 23, 2022
    Publication date: March 13, 2025
    Inventors: Michel ARMAND, Heng ZHANG, María MARTÍNEZ-IBÁÑEZ, Leire MEABE, Eduardo SÁNCHEZ DÍEZ, Javier CARRASCO RODRÍGUEZ, Alexander SANTIAGO
  • Publication number: 20250066294
    Abstract: A method for obtaining ionic compounds of formula I involves two-steps carried out in a one-pot manner and includes reaction of a N-(sulfinyl)sulfonamide of formula R1SO2N?S?O with a sulphonamide salt of formula R2SO2N(M)m, followed by oxidation of the resulting compound. The method has several advantages compared to previous methods to access sulfonimides, including a short sequence of steps, short reaction time, avoidance of environmentally-unfriendly reagents (including CF3SiMe3), improved atom-economy, milder conditions, as well as the ability to synthesize a broad range of salts.
    Type: Application
    Filed: December 23, 2022
    Publication date: February 27, 2025
    Inventors: Michel ARMAND, Heng ZHANG, Lorena GARCÍA, María MARTÍNEZ-IBÁÑEZ, Eduardo SÁNCHEZ DÍEZ
  • Patent number: 12136515
    Abstract: A metal ion capacitor with outstanding power capabilities having a negative electrode based on hard carbon (HC) and a positive electrode based on a combination of activated carbon (AC) and a sacrificial salt selected from the group consisting of squarate, oxalate, ketomalonate and di-ketosuccinate or a combination thereof. The sacrificial salt is added to AC in the positive electrode as a source of metal ions for pre-doping the HC and to efficiently compensate its high irreversible capacity by providing the metal ions necessary for the formation of solid electrolyte interphase (SEI) on the hard carbon, allowing for a 1:1 and superior mass balances between anode and cathode. Advantageously, the extraordinary performance of this approach has been successfully demonstrated not only in lithium ion capacitors (LICs) but also in other metal ion capacitors such as sodium and potassium ion capacitors.
    Type: Grant
    Filed: January 7, 2021
    Date of Patent: November 5, 2024
    Assignee: FUNDACION CENTRO DE INVESTIGACION COOPERATIVA DE ENERGIAS ALTERNATIVAS CIC ENERGIGUNE FUNDAZIOA
    Inventors: Jon Ajuria Arregi, Maria Arnaiz Gonzalez, Michel Armand, Daniel Carriazo Martin, Devaraj Shanmukaraj
  • Publication number: 20240253023
    Abstract: The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M+m in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula RF—SOx—N?Z, where RF is a perflourinated group, x is 1 or 3, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants and the catalysis of various chemical reactions.
    Type: Application
    Filed: October 5, 2007
    Publication date: August 1, 2024
    Inventors: Christophe Michot, Michel Armand, Michel Gauthier, Yves Choquette
  • Patent number: 11999811
    Abstract: The present technology relates to a polymer comprising at least one ester repeating unit and one ether repeating unit for use in an electrochemical cell, particularly in electrochemical accumulators such as lithium batteries, sodium batteries, potassium batteries and lithium-ion batteries. More specifically, the use of this polymer as a solid polymer electrolyte (SPE), as a matrix for forming gel electrolytes, or as a binder in an electrode material are also contemplated.
    Type: Grant
    Filed: February 5, 2019
    Date of Patent: June 4, 2024
    Assignee: HYDRO-QUÉBEC
    Inventors: Basile Commarieu, Jean-Christophe Daigle, Pierre-Michel Jalbert, Gilles Lajoie, Catherine Gagnon, Abdelbast Guerfi, Michel Armand, Karim Zaghib
  • Publication number: 20230323029
    Abstract: The present technology relates to an ionic polymer comprising at least one repeating unit comprising the reaction product between at least one compound comprising at least two functional groups and a metal bis(halosulfonyl)imide for use in electrochemical applications, particularly in electrochemical accumulators such as batteries, electrochromic devices and supercapacitors. The present technology also relates to a polymer composition, a solid polymer electrolyte composition, a solid polymer electrolyte, an electrode material comprising said ionic polymer. Their uses in electrochemical cells and electrochemical accumulators as well as their manufacturing processes are also described.
    Type: Application
    Filed: January 22, 2021
    Publication date: October 12, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Jean-Christophe DAIGLE, Annie-Pier LAROUCHE, Patrick CHAREST, Abdelbast GUERFI, Martin DONTIGNY, Michel ARMAND, Karim ZAGHIB, Andreas HINTENNACH
  • Patent number: 11699781
    Abstract: A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.
    Type: Grant
    Filed: December 10, 2020
    Date of Patent: July 11, 2023
    Assignee: HYDRO-QUÉBEC
    Inventors: Karim Zaghib, Michel Armand, Abdelbast Guerfi, Michel Perrier, Elisabeth Dupuis, Patrick Charest
  • Publication number: 20230207808
    Abstract: Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds may be obtained by a direct synthesis embodying a hydrothermal method. The method may include preparing an aqueous mixture including a M-containing compound, a M?-containing compound and a M?-containing compound to obtain a M-M?-M? mixture; adding a P-containing compound to the mixture M-M?-M? mixture to obtain a M-M?-M?-P mixture; adding a Na-containing compound to the M-M?-M?-P mixture to obtain a Na-M-M?-M?-P mixture; and introducing the Na-M-M?-M?-P mixture into an autoclave to perform crystal growth and obtain the compound of general formula NahMiM?jM?kPO4.
    Type: Application
    Filed: December 22, 2022
    Publication date: June 29, 2023
    Applicants: HYDRO-QUÉBEC, CIC ENERGIGUNE
    Inventors: Montse GALCERAN MESTRES, Montse CASAS-CABANAS, Abdelbast GUERFI, Michel ARMAND, Teofilo ROJO, Karim ZAGHIB, Andrea PAOLELLA
  • Publication number: 20230064888
    Abstract: The present technology relates to a sulfur-containing polymer or organic compound for use in a positive electrode material, especially in lithium batteries. More specifically, the use of this sulfur-containing polymer or compound as an active electrode material makes it possible to combine sulfur and an active organic cathode material. The present technology also relates to the use of the sulfur-containing polymer or organic compound as defined herein as a solid polymer electrolyte (SPE) or as an additive for electrolyte, especially in lithium batteries.
    Type: Application
    Filed: August 25, 2022
    Publication date: March 2, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Rachel LÉVESQUE-BÉLANGER, Andrea PAOLELLA, Jean-Christophe DAIGLE, Basile COMMARIEU, Michel ARMAND, Karim ZAGHIB
  • Publication number: 20230045183
    Abstract: A solid electrolyte includes a polymer and a lithium salt, a sodium salt or mixtures of these salts. The polymer has at least 50 mol % of recurring units of formula (I). A method is for the preparation of the electrolyte. Energy storage devices can include the electrolyte.
    Type: Application
    Filed: March 8, 2021
    Publication date: February 9, 2023
    Inventors: Michel ARMAND, Shanmukaraj DEVARAJ
  • Patent number: 11569506
    Abstract: This disclosure provides for Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds of the invention are obtained by a direct synthesis embodying a hydrothermal method.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: January 31, 2023
    Assignees: HYDRO-QUÉBEC, CIC ENERGIGUNE
    Inventors: Montse Galceran Mestres, Montse Casas-Cabanas, Abdelbast Guerfi, Michel Armand, Teofilo Rojo, Karim Zaghib, Andrea Paolella
  • Publication number: 20220406532
    Abstract: A metal ion capacitor with outstanding power capabilities having a negative electrode based on hard carbon (HC) and a positive electrode based on a combination of activated carbon (AC) and a sacrificial salt selected from the group consisting of squarate, oxalate, ketomalonate and di-ketosuccinate or a combination thereof. The sacrificial salt is added to AC in the positive electrode as a source of metal ions for pre-doping the HC and to efficiently compensate its high irreversible capacity by providing the metal ions necessary for the formation of solid electrolyte interphase (SEI) on the hard carbon, allowing for a 1:1 and superior mass balances between anode and cathode. Advantageously, the extraordinary performance of this approach has been successfully demonstrated not only in lithium ion capacitors (LICs) but also in other metal ion capacitors such as sodium and potassium ion capacitors.
    Type: Application
    Filed: January 7, 2021
    Publication date: December 22, 2022
    Inventors: Jon AJURIA ARREGI, Maria ARNAIZ GONZALEZ, Michel ARMAND, Daniel CARRIAZO MARTIN, Devaraj SHANMUKARAJ
  • Patent number: 11479626
    Abstract: A solid single-ion conductive polymer comprising a repeat unit of formula (Ia): wherein R1 is H, or C1 to C16 linear or branched alkyl, alkenyl, alkinyl; m is 1 to 5; each M+ is independently selected from Li+, Na+ or K+; and X is selected from CF3, CH3, or F; and the polymer has an average molecular weight of 350.000 to 1.200.000 Da.
    Type: Grant
    Filed: October 22, 2020
    Date of Patent: October 25, 2022
    Assignee: Belenos Clean Power Holding AG
    Inventors: Michel Armand, Maria Martinez-Ibanez, Eduardo Sanchez Diez, Alexander Santiago Sanchez, Heng Zhang, Uxue Oteo Olea
  • Patent number: 11469419
    Abstract: The present technology relates to a sulfur-containing polymer or organic compound for use in a positive electrode material, especially in lithium batteries. More specifically, the use of this sulfur-containing polymer or compound as an active electrode material makes it possible to combine sulfur and an active organic cathode material. The present technology also relates to the use of the sulfur-containing polymer or organic compound as defined herein as a solid polymer electrolyte (SPE) or as an additive for electrolyte, especially in lithium batteries.
    Type: Grant
    Filed: October 2, 2018
    Date of Patent: October 11, 2022
    Assignee: HYDRO-QUEBEC
    Inventors: Rachel Lévesque-Bélanger, Andrea Paolella, Jean-Christophe Daigle, Basile Commarieu, Michel Armand, Karim Zaghib
  • Patent number: 11462768
    Abstract: A copolymer for constituting a polymer electrolyte for a solid-electrolyte lithium or sodium cell. A polymer electrolyte that is usable in combination with high-voltage cathode active materials and makes it possible to provide solid-electrolyte lithium or sodium cells and/or batteries having a high energy density that is sufficient even for use in electricity-based vehicles, the copolymer encompasses at least two ion-conductive polymers, the copolymer encompassing at least one polymer polymerized by ring-opening polymerization of at least one lactone and/or of at least one lactide and/or of at least one cyclic carbonate and/or of at least one cyclic carbamate and/or of at least one lactam and/or of at least one epoxide, and/or at least one polymer polymerized by radical polymerization of acrylonitrile and/or of at least one acrylonitrile derivative; and encompasses at least one polyacrylate having at least one repeating unit.
    Type: Grant
    Filed: December 19, 2019
    Date of Patent: October 4, 2022
    Assignee: Robert Bosch GmbH
    Inventors: Michel Armand, Hany Basam Eitouni, Heng Zhang, Jose Castellanos, Lide Rodriguez, Mario Joost
  • Patent number: 11453835
    Abstract: Polymers used as rolling lubricating agents, to compositions including said polymers, and to alkali metal films including the polymers or compositions on the surface(s) thereof. The use of said polymers and compositions is also described for strip-rolling alkali metals or alloys thereof in order to obtain thin films. Methods for producing said thin films, which are suitable for use in electrochemical cells, are also described. An improved lubricant according to formula I, which, for example, achieves enhanced conductivity, and/or enables the production of electrochemical cells having an improved life span in cycles.
    Type: Grant
    Filed: June 4, 2020
    Date of Patent: September 27, 2022
    Assignee: HYDRO-QUEBEC
    Inventors: Karim Zaghib, Michel Armand, Patrick Bouchard, Serge Verreault, Julie Hamel-Pâquet, Gabriel Girard
  • Patent number: 11417878
    Abstract: The present technology described relates to lithium-based alloy electrode materials used for the production of anode in lithium accumulators and processes for obtaining same. The alloy comprises metallic lithium, a metallic component X1 selected from magnesium and aluminum and a metallic component X2 selected from alkali metals, alkaline earth metals, rare earths, zirconium, copper, silver, bismuth, cobalt, zinc, aluminum, silicon, tin, antimony, cadmium, mercury, lead, manganese, boron, indium, thallium, nickel, germanium, molybdenum and iron. Processes for preparing electrode materials thus obtained and their uses are also described.
    Type: Grant
    Filed: August 15, 2018
    Date of Patent: August 16, 2022
    Assignee: HYDRO-QUEBEC
    Inventors: Karim Zaghib, Michel Armand, Patrick Bouchard, Serge Verreault, Nancy Turcotte, Dominic Leblanc, Kamyab Amouzegar