Abstract: A two-component solvent-based coating composition comprising a component A comprising an autoxidizable resin comprising unsaturated fatty acids and a metal-ligand complex as drying catalyst, wherein the metal is manganese, vanadium or iron; and a component B comprising a (meth)acrylate compound and a thiol compound, wherein the (meth)acrylate compound is a poly (meth)acryloyl functional ester of (meth)acrylic acid and a polyhydric alcohol or a poly (meth)acryloyl functional dimer of such ester, wherein component B is free of drying catalyst, wherein component A is free of a compound comprising a thiol group and of a compound comprising a (meth)acryloyl functional group, and wherein the coating composition is free of cobalt.

Abstract: A coating composition comprising an alkyd-comprising resin and a drier comprising a dinudear ligand-manganese complex comprising manganese and a 1,4,7-trisubstituted-1,4,7-triazacyclononane ligand, wherein the alkyd-comprising resin is an alkyd-stabilized non-aqueous dispersion of particles of addition polymer in a non-aqueous liquid phase comprising alkyd.

Abstract: A drier for air-drying an auto-oxidizable resin composition, said drier comprising: 1,4,7-trialkyl-1,4,7-triazacyclononane (L); a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, Cl?, Br?, I?, NO3, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20) aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of Mn:L is at least 1.25:1 and preferably at least 1.5:1.

Abstract: A mixture for use as a drier for air-drying an auto-oxidizable resin composition, said mixture comprising : 1,4,7-trialkyl-1,4,7-triazacyclononane (L); and, a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, CI?, Br?, I?, NO3?, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of L:Mn is at least 1.25:1 and more preferably at least 1.5:1.

Abstract: The invention relates to a drier for an air drying auto-oxidisable resin composition comprising a polymer comprising unsaturated fatty acid residues, the drier comprising a manganese triaza complex comprising the following structure: wherein R1=C1-C20alkyl optionally substituted with heteroatoms, or C6-C20aryl optionally substituted with heteroatoms; X and Y are independently selected from O and OC(R2)O, in which a=4 when X=O, and a=3 when X=OC(R2)O, and in which b=4 when Y=O, and b=3 when Y=OC(R2)O; Wherein R2=C1-C20alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue, and one or more anions, being chosen PF6-, SbF6—, AsF6-, BF4—, B(C6F5)4—, Cl—, Br—, I—, NO3—, or R3COO— or SO42?, and wherein R3 is C1-C20alkyl optionally substituted with heteroatoms, C6-C20aryl 1optionally substituted with heteroatoms, or a polymeric residue, and wherein the drier comprises an additional amount of, 4,7-trialkyl-1,4,7-triazacyclononane; wherein the 1,4,7-tr

Abstract: A drier for air-drying an auto-oxidizable resin composition, said drier comprising: 1,4,7-trialkyl-1,4,7-triazacyclononane (L); a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, CI?, Br?, I?, NO3, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20) aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of Mn:L is at least 1.25:1 and preferably at least 1.5:1.

Abstract: A mixture for use as a drier for air-drying an auto-oxidizable resin composition, said mixture comprising : 1,4,7-trialkyl-1,4,7-triazacyclononane (L); and, a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, Cl?, Br?, I?, NO3?, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of L:Mn is at least 1.25:1 and more preferably at least 1.5:1.

Abstract: Coating composition comprising an oxidatively drying binder and a reactive diluent. The diluent is an ester of a polyunsaturated alcohol, the ester being without chain-end double bonds. The alcohol can selected from the group comprising geraniol, nerol, citronellol, and farnesol. The ester can be a di-ester of a dicarboxylic acid, such as malonic acid or a polyester comprising at least one terminal malonate group.

Abstract: Coating composition comprising an oxidatively drying binder, such as an alkyd, and a reactive diluent. The diluent is an ester of malonic acid and an unsaturated mono-alcohol, e.g., geraniol, farnesol, citronellol and/or nerol.

Abstract: Coating composition comprising an oxidatively drying binder and a reactive diluent. The diluent is an ester of a polyunsaturated alcohol, the ester being without chain-end double bonds. The alcohol can selected from the group comprising geraniol, nerol, citronellol, and farnesol. The ester can be a di-ester of a dicarboxylic acid, such as malonic acid or a polyester comprising at least one terminal malonate group.

Abstract: Coating composition comprising an oxidatively drying binder, such as an alkyd, and a reactive diluent. The diluent is an ester of malonic acid and an unsaturated mono-alcohol, e.g., geraniol, farnesol, citronellol and/or nerol.