Patents by Inventor Michel Delmas
Michel Delmas has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 12084811Abstract: A process for production of lignins and synthetic gas including the steps of extracting lignins and hemicellulose by putting solid Lignocellulosic Raw Material in contact with a mixture of water and formic acid at atmospheric pressure and at a temperature between 80° C. and 110° C.; fractionating, the primary solid fraction and the primary liquid fraction; separating the lignins from the intermediate liquid fraction; and gasifying at least part of said primary solid fraction and/or at least part of said residual liquid fraction for producing synthetic gas.Type: GrantFiled: February 14, 2019Date of Patent: September 10, 2024Assignee: Société BioebInventor: Michel Delmas
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Patent number: 12077613Abstract: A method of production of lignin and hemicellulose from a plant lignocellulosic material includes (a) contacting a plant lignocellulosic material with an extraction solution during more than 2 hours at a temperature between 95° ° C. to 110° C., thereby obtaining a solid fraction and a liquid fraction, (b) separating the solid fraction and the liquid fraction, (c) concentrating the liquid fraction so as to obtain a concentrated liquid fraction, (d) mixing equal parts by weight of water with the concentrated liquid fraction so as to obtain a suspension comprising solid particles in suspension in a liquid medium, (e) separating the particles and the medium of the suspension, (f) recovering the particles of the suspension thereby obtaining a fraction comprising lignin called lignified fraction, (g) recovering the medium of the suspension thereby obtaining a fraction comprising hemicellulose called hemicellulosic fraction.Type: GrantFiled: February 19, 2019Date of Patent: September 3, 2024Assignee: Compagnie Industrielle de la Matiere Vegetale—CIMVInventors: Bouchra Benjelloun Mlayah, Michel Delmas
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Patent number: 12077442Abstract: A method and a power plant for on-demand producing electricity from Non-Fossil Power Sources and from a Renewable Lignocellulosic Biomass Feedstock, in a power plant using several electrical production facilities comprising a first facility for producing electricity from a Non-Fossil Power Source chosen from among wind power, hydro power, solar power, geothermal power and/or tidal power; and a second facility using synthetic gas produced during a gasification step of several fractions from renewable lignocellulosic biomass feedstock obtained by the implementation of an organosolv process using a mixture composed of at least water and formic acid.Type: GrantFiled: February 12, 2019Date of Patent: September 3, 2024Assignee: Société BioebInventor: Michel Delmas
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Patent number: 11952282Abstract: A low energy production method for producing pure and highly concentrated carbon dioxide from a renewable lignocellulosic biomass feedstock comprising the steps of i) extracting lignins and hemicelluloses by putting a solid lignocellulosic raw material in the presence of a mixture of at least water and formic acid, at atmospheric pressure under conditions of temperature between 80° C. and 110° C., ii) fractionating, the primary solid fraction and the primary liquid fraction obtained at the end of the extraction step i), iii) separating the lignins from the intermediate liquid fraction, iv) producing a synthetic gas by feeding a gasification equipment with at least part of said primary solid fraction and/or at least part of said residual liquid fraction, and v) producing carbon dioxide and water by introducing dioxygen, or dioxygen enriched air, or air in said gasification equipment.Type: GrantFiled: February 15, 2019Date of Patent: April 9, 2024Assignee: Société BioebInventor: Michel Delmas
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Patent number: 11624152Abstract: A low energy production process for producing paper pulp from lignocellulosic biomass, the process comprising the following successive steps: a) extracting lignins and hemicellulose from lignocellulosic biomass by putting at least one solid lignocellulosic raw material in the presence of a mixture, composed only of water and of formic acid, at atmospheric pressure and under controlled conditions of reaction temperature between ambient temperature and the reflux temperature of the mixture at atmospheric pressure, preferably between 80° C. and 100° C., with a weight ratio of the at least one solid lignocellulosic raw material/liquid mixture comprised between 1/1 and 1/15, and for a determined period of time of reaction; and b) separating, at atmospheric pressure and at the reaction temperature, a solid fraction, constituting raw paper pulp, from an organic phase containing in solution at least the starting formic acid and water mixture, solubilized monomeric and polymeric sugars, lignins.Type: GrantFiled: December 13, 2018Date of Patent: April 11, 2023Assignee: Société BioebInventor: Michel Delmas
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Publication number: 20220325187Abstract: The invention proposes a method comprising (i) using a lignocellulosic raw material based process for production of synthetic gas; (ii) introducing the syngas to a Fischer-Tropsch (FT) catalytic synthesis (FTS) process and generating Fischer-Tropsch products, wherein the synthetic gas production process comprises the steps a) extracting lignins and hemicelluloses by putting solid lignocellulosic raw material in contact with a mixture composed of at least water and formic acid, at atmospheric pressure under temperature between 80° C. and 110° C., b) fractionating the obtained primary solid fraction (PSF) and primary liquid fraction (PLF); c) recovering and obtaining an intermediate liquid fraction (ILF); d) separating the lignins; e) gasifying at least part of said primary solid fraction (PSF) for producing synthetic gas.Type: ApplicationFiled: July 29, 2020Publication date: October 13, 2022Inventor: Michel Delmas
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Patent number: 11274209Abstract: The invention relates to a process for the simultaneous extraction of lignin and silica from lignocellulosic plant material, characterized in that it comprises the steps of: a) fractionating the lignocellulosic plant material in the presence of an acid solution, so as to obtain a solid fraction comprising cellulose, residual lignin and silica; b) extracting simultaneously lignin and silica from the solid fraction obtained in step a) with a basic solution, at a pH between 10 and 13 and at a temperature between 70° C. and 90° C., so as to obtain a liquid phase comprising lignin and silica, and a solid phase; c) separating the liquid phase and of the solid phase obtained in step b), d) coprecipitating a mixture of lignin and silica comprised in the liquid phase, at a pH between 5 and 6.Type: GrantFiled: February 16, 2018Date of Patent: March 15, 2022Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE-CIMVInventors: Bouchra Benjelloun Mlayah, Michel Delmas, Nadja Cachet
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Patent number: 11261310Abstract: The present invention relates to a method for treating fragments of polyvinyl butyral (PVB) in which glass shards are encrusted in or on the surface of the PVB. The method involves placing PVB fragments in contact with an aqueous solution comprising a cationic surfactant and a weak base, to obtain a mixture. This mixture, subjected to ultrasound within a defined temperature range, leads to separation of the glass shards and the PVB. In particular, the inventors have discovered that the combined, simultaneous, and complementary action of a weak base, a cationic surfactant, and ultrasound, at an appropriate temperature, made it possible to detach and/or unembed the glass shards fixed to the collected PVB without degrading the polymer matrix.Type: GrantFiled: March 1, 2019Date of Patent: March 1, 2022Assignee: INSTITUT NATIONAL POLYTECHNIQUE DE TOULOUSEInventors: Ghislain Denis, Jean-Luc Trompette, Michel Delmas
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Patent number: 11247910Abstract: Disclosed is a process for the extraction of silica from lignocellulosic plant matter, including the steps of: a) fractionating the lignocellulosic plant matter in the presence of an acid solution, so as to obtain a solid fraction including cellulose; b) extracting the silica from the solid fraction obtained in step a) with a basic solution, at a pH between 10 and 13 and at a temperature between 70° C. and 90° C., so as to obtain a liquid phase including silica and a solid phase; c) separating the liquid phase and of the solid phase which are obtained in step b); and d) precipitating the silica which is included in the liquid phase, at a pH between 5 and 6.Type: GrantFiled: August 18, 2016Date of Patent: February 15, 2022Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE—CIMVInventors: Bouchra Benjelloun Mlayah, Michel Delmas, Laurence Llovera, Alvaro Tejado Etayo
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Patent number: 11021720Abstract: A process for producing ethanol includes steps of pre-treatment of the lignocellulosic vegetable raw material, including the steps consisting in destructuring the lignocellulosic vegetable raw material, then in separating, on the one hand, the cellulose (C6) capable of then being hydrolysed (and fermented for the production of ethanol) and, on the other hand, the hemicelluloses capable of then being hydrolysed and the lignins. The hydrolysis of the cellulose and of the hemicelluloses is then carried out in a sequenced manner according to the following steps consisting in: i) beginning the enzymatic hydrolysis of the cellulose by at least one enzyme for a first period with a view to obtaining an intermediate hydrolysate; ii) adding hemicelluloses to the intermediate hydrolysate; iii) continuing the enzymatic hydrolysis of the mixture until a final hydrolysate is obtained at the end of a total period of enzymatic hydrolysis.Type: GrantFiled: June 3, 2015Date of Patent: June 1, 2021Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALEInventors: Bouchra Benjelloun Mlayah, Michel Delmas
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Patent number: 10160823Abstract: A lignin-phenol-formaldehyde resin, which is obtained by polycondensation of formaldehyde, phenol and lignin in the presence of a basic or acidic catalyst, is characterized in that the lignin is a lignin that is not chemically modified at the available functional groups. This lignin has a low molecular mass and includes available functional groups chosen from the group including aliphatic hydroxyls and phenolic hydroxyls. The degree of substitution by weight of phenol with the lignin is between 50% and 60%. The weight proportion of the lignin and of phenol in the resin is equal to the weight proportion of phenol in a lignin-free phenol-formaldehyde (PF) resin.Type: GrantFiled: March 26, 2014Date of Patent: December 25, 2018Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE-CIMVInventors: Michel Delmas, Bouchra Benjelloun Mlayah
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Patent number: 9580588Abstract: A method for the mechanical reinforcement of elastomer polymers, of a chemically unmodified lignin with available functional groups which has a specific surface area of between 0.5 m2/g and 5 m2/g, and preferably between 1 m2/g and 2.5 m2/g. Also an elastomer thus reinforced, in particular without carbon black.Type: GrantFiled: July 16, 2013Date of Patent: February 28, 2017Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALEInventors: Bouchra Benjelloun Mlayah, Michel Delmas
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Patent number: 9518274Abstract: A process for producing bioethanol includes the steps of pretreatment (consisting in destructuring the lignocellulosic vegetable raw material by placing it in the presence of a mixture containing formic acid, acetic acid and water, then in separating cellulose), of enzymatic hydrolysis and of alcoholic fermentation, characterized in that it includes, prior to the enzymatic hydrolysis, a step of partial elimination of the lignins so as to obtain a residual overall level of lignins (T), expressed as percentage by weight, which is non-zero and which is included in a range determined by a lower limit, and an upper limit Bsup, respectively equal to 0.30% and 4%. In order to obtain conditions of acidification before the enzymatic hydrolysis step, the process includes a step for re-acidification of the mixture, which is carried out with an acid, or of a mixture of acids, of determined pKa, and preferably with weak organic.Type: GrantFiled: October 5, 2011Date of Patent: December 13, 2016Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE—CIMVInventors: Michel Delmas, Bouchra Benjelloun Mlayah
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Patent number: 9388207Abstract: A process for the separation of lignins and sugars from an extracted liquor, including, in the form of dry matter (DM), lignins and sugars, includes: a) concentrating the extracted liquor, in order to obtain a liquor having dry matter in a proportion of between 60 and 70%; b) mixing the concentrated liquor with water in equal parts by weight; c) stirring the mixture in order to disperse the lignins and to obtain a stable suspending of the lignins; d) filtering the solution, wherein the mixing is carried out by introducing the concentrated liquor into the water; and the temperature of the solution, during the suspending, is between 50° C. and 60° C.Type: GrantFiled: June 1, 2011Date of Patent: July 12, 2016Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETABLE—CIMVInventors: Michel Delmas, Bouchra Benjelloun Mlayah
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Publication number: 20150152255Abstract: A method for the mechanical reinforcement of elastomer polymers, of a chemically unmodified lignin with available functional groups which has a specific surface area of between 0.5 m2/g and 5 m2/g, and preferably between 1 m2/g and 2.5 m2/g. Also an elastomer thus reinforced, in particular without carbon black.Type: ApplicationFiled: July 16, 2013Publication date: June 4, 2015Inventors: Bouchra Benjelloun Mlayah, Michel Delmas
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Patent number: 8551747Abstract: A process for pretreating a lignocellulosic plant raw material in order to obtain a pretreated material that is capable of being hydrolyzed and fermented for the production of bioethanol, includes the following successive steps: (i) destructuring the lignocellulosic plant raw material by placing it in the presence of a mixture containing formic acid and water, at a reaction temperature between 95° C. and 110° C.; (ii) then, at atmospheric pressure and prior to any hydrolysis then fermentation action, separating: on the one hand, the solid phase, mainly composed of the cellulose, constituting a first co-substrate, capable of then being hydrolyzed and fermented for the production of bioethanol; and on the other hand, the liquid phase, containing, in particular in aqueous solution, the formic acid, the lignins, and the hemicelluloses, constituting a second co-substrate, capable of then being hydrolyzed and fermented for the production of bioethanol.Type: GrantFiled: January 22, 2009Date of Patent: October 8, 2013Assignee: Campagnie Industrielle de la Matiere Vegetale CIMVInventors: Michel Delmas, Bouchra Benjelloun Mlayah
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Publication number: 20130183733Abstract: A process for producing bioethanol includes the steps of pretreatment (consisting in destructuring the lignocellulosic vegetable raw material by placing it in the presence of a mixture containing formic acid, acetic acid and water, then in separating cellulose), of enzymatic hydrolysis and of alcoholic fermentation, characterized in that it includes, prior to the enzymatic hydrolysis, a step of partial elimination of the lignins so as to obtain a residual overall level of lignins (T), expressed as percentage by weight, which is non-zero and which is included in a range determined by a lower limit, and an upper limit Bsup, respectively equal to 0.30% and 4%. In order to obtain conditions of acidification before the enzymatic hydrolysis step, the process includes a step for re-acidification of the mixture, which is carried out with an acid, or of a mixture of acids, of determined pKa, and preferably with weak organic.Type: ApplicationFiled: October 5, 2011Publication date: July 18, 2013Applicant: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE-CIMVInventors: Michel Delmas, Bouchra Benjelloun Mlayah
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Publication number: 20130085269Abstract: A process for the separation of lignins and sugars from an extracted liquor, including, in the form of dry matter (DM), lignins and sugars, includes: a) concentrating the extracted liquor, in order to obtain a liquor having dry matter in a proportion of between 60 and 70%; b) mixing the concentrated liquor with water in equal parts by weight; c) stirring the mixture in order to disperse the lignins and to obtain a stable suspending of the lignins; d) filtering the solution, wherein the mixing is carried out by introducing the concentrated liquor into the water; and the temperature of the solution, during the suspending, is between 50° C. and 60° C.Type: ApplicationFiled: June 1, 2011Publication date: April 4, 2013Inventors: Michel Delmas, Bouchra Benjelloun Mlayah
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Patent number: 8157964Abstract: The invention proposes an installation (10) in which the impregnation and fractionation of the raw material (MP) are conducted at atmospheric pressure, characterized in that it comprises means (18, 20) for transferring the raw material (MP) successively to a first treatment station (PT1) and a second treatment station (PT2), each comprising means (G1, G2) for temporarily combining, at the first station (PT1), the raw material (MP) with a quantity of a first mixture of organic acids and, at the second station (PT2), for temporarily combining the raw material (MP) with a quantity of a second mixture; and means, after impregnation, for at least partially recovering the quantity of second mixture after impregnation and for recycling at least a portion of the second recovered mixture to form at least partially said first impregnation mixture used at the first station (PT1).Type: GrantFiled: April 20, 2006Date of Patent: April 17, 2012Assignee: Compagnie Industrielle de la Matiere VegetaleInventors: Bouchra Benjelloun Mlayah, Michel Delmas, Gérard Avignon
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Publication number: 20110105737Abstract: A method for pretreating plant starting material for the purpose of producing bioethanol and/or sugar via a common chamber (12), is characterized in that: —during one period, the plant material (MP), introduced into the common pretreatment chamber, is a lignocellulosic plant starting material, whose pretreatment is aimed at separating the cellulose, the hemicelluloses and the lignins so as to obtain a pretreated plant material that can be hydrolyzed and fermented for the production of bioethanol; —during another period, the plant material (MP), introduced into the common pretreatment chamber, is a sacchariferous plant starting material, whose pretreatment is aimed at extracting therefrom, by diffusion, a sugar juice for the production of sugar and/or of bioethanol.Type: ApplicationFiled: June 3, 2009Publication date: May 5, 2011Applicant: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE-CIMVInventors: Bouchra Benjelloun Mlayah, Michel Delmas, Gérard Levasseur, Thierry Scholastique