Patents by Inventor Michel Delmas

Michel Delmas has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11952282
    Abstract: A low energy production method for producing pure and highly concentrated carbon dioxide from a renewable lignocellulosic biomass feedstock comprising the steps of i) extracting lignins and hemicelluloses by putting a solid lignocellulosic raw material in the presence of a mixture of at least water and formic acid, at atmospheric pressure under conditions of temperature between 80° C. and 110° C., ii) fractionating, the primary solid fraction and the primary liquid fraction obtained at the end of the extraction step i), iii) separating the lignins from the intermediate liquid fraction, iv) producing a synthetic gas by feeding a gasification equipment with at least part of said primary solid fraction and/or at least part of said residual liquid fraction, and v) producing carbon dioxide and water by introducing dioxygen, or dioxygen enriched air, or air in said gasification equipment.
    Type: Grant
    Filed: February 15, 2019
    Date of Patent: April 9, 2024
    Assignee: Société Bioeb
    Inventor: Michel Delmas
  • Patent number: 11624152
    Abstract: A low energy production process for producing paper pulp from lignocellulosic biomass, the process comprising the following successive steps: a) extracting lignins and hemicellulose from lignocellulosic biomass by putting at least one solid lignocellulosic raw material in the presence of a mixture, composed only of water and of formic acid, at atmospheric pressure and under controlled conditions of reaction temperature between ambient temperature and the reflux temperature of the mixture at atmospheric pressure, preferably between 80° C. and 100° C., with a weight ratio of the at least one solid lignocellulosic raw material/liquid mixture comprised between 1/1 and 1/15, and for a determined period of time of reaction; and b) separating, at atmospheric pressure and at the reaction temperature, a solid fraction, constituting raw paper pulp, from an organic phase containing in solution at least the starting formic acid and water mixture, solubilized monomeric and polymeric sugars, lignins.
    Type: Grant
    Filed: December 13, 2018
    Date of Patent: April 11, 2023
    Assignee: Société Bioeb
    Inventor: Michel Delmas
  • Publication number: 20220325187
    Abstract: The invention proposes a method comprising (i) using a lignocellulosic raw material based process for production of synthetic gas; (ii) introducing the syngas to a Fischer-Tropsch (FT) catalytic synthesis (FTS) process and generating Fischer-Tropsch products, wherein the synthetic gas production process comprises the steps a) extracting lignins and hemicelluloses by putting solid lignocellulosic raw material in contact with a mixture composed of at least water and formic acid, at atmospheric pressure under temperature between 80° C. and 110° C., b) fractionating the obtained primary solid fraction (PSF) and primary liquid fraction (PLF); c) recovering and obtaining an intermediate liquid fraction (ILF); d) separating the lignins; e) gasifying at least part of said primary solid fraction (PSF) for producing synthetic gas.
    Type: Application
    Filed: July 29, 2020
    Publication date: October 13, 2022
    Inventor: Michel Delmas
  • Patent number: 11274209
    Abstract: The invention relates to a process for the simultaneous extraction of lignin and silica from lignocellulosic plant material, characterized in that it comprises the steps of: a) fractionating the lignocellulosic plant material in the presence of an acid solution, so as to obtain a solid fraction comprising cellulose, residual lignin and silica; b) extracting simultaneously lignin and silica from the solid fraction obtained in step a) with a basic solution, at a pH between 10 and 13 and at a temperature between 70° C. and 90° C., so as to obtain a liquid phase comprising lignin and silica, and a solid phase; c) separating the liquid phase and of the solid phase obtained in step b), d) coprecipitating a mixture of lignin and silica comprised in the liquid phase, at a pH between 5 and 6.
    Type: Grant
    Filed: February 16, 2018
    Date of Patent: March 15, 2022
    Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE-CIMV
    Inventors: Bouchra Benjelloun Mlayah, Michel Delmas, Nadja Cachet
  • Patent number: 11261310
    Abstract: The present invention relates to a method for treating fragments of polyvinyl butyral (PVB) in which glass shards are encrusted in or on the surface of the PVB. The method involves placing PVB fragments in contact with an aqueous solution comprising a cationic surfactant and a weak base, to obtain a mixture. This mixture, subjected to ultrasound within a defined temperature range, leads to separation of the glass shards and the PVB. In particular, the inventors have discovered that the combined, simultaneous, and complementary action of a weak base, a cationic surfactant, and ultrasound, at an appropriate temperature, made it possible to detach and/or unembed the glass shards fixed to the collected PVB without degrading the polymer matrix.
    Type: Grant
    Filed: March 1, 2019
    Date of Patent: March 1, 2022
    Assignee: INSTITUT NATIONAL POLYTECHNIQUE DE TOULOUSE
    Inventors: Ghislain Denis, Jean-Luc Trompette, Michel Delmas
  • Patent number: 11247910
    Abstract: Disclosed is a process for the extraction of silica from lignocellulosic plant matter, including the steps of: a) fractionating the lignocellulosic plant matter in the presence of an acid solution, so as to obtain a solid fraction including cellulose; b) extracting the silica from the solid fraction obtained in step a) with a basic solution, at a pH between 10 and 13 and at a temperature between 70° C. and 90° C., so as to obtain a liquid phase including silica and a solid phase; c) separating the liquid phase and of the solid phase which are obtained in step b); and d) precipitating the silica which is included in the liquid phase, at a pH between 5 and 6.
    Type: Grant
    Filed: August 18, 2016
    Date of Patent: February 15, 2022
    Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE—CIMV
    Inventors: Bouchra Benjelloun Mlayah, Michel Delmas, Laurence Llovera, Alvaro Tejado Etayo
  • Patent number: 11021720
    Abstract: A process for producing ethanol includes steps of pre-treatment of the lignocellulosic vegetable raw material, including the steps consisting in destructuring the lignocellulosic vegetable raw material, then in separating, on the one hand, the cellulose (C6) capable of then being hydrolysed (and fermented for the production of ethanol) and, on the other hand, the hemicelluloses capable of then being hydrolysed and the lignins. The hydrolysis of the cellulose and of the hemicelluloses is then carried out in a sequenced manner according to the following steps consisting in: i) beginning the enzymatic hydrolysis of the cellulose by at least one enzyme for a first period with a view to obtaining an intermediate hydrolysate; ii) adding hemicelluloses to the intermediate hydrolysate; iii) continuing the enzymatic hydrolysis of the mixture until a final hydrolysate is obtained at the end of a total period of enzymatic hydrolysis.
    Type: Grant
    Filed: June 3, 2015
    Date of Patent: June 1, 2021
    Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE
    Inventors: Bouchra Benjelloun Mlayah, Michel Delmas
  • Publication number: 20210079123
    Abstract: The present invention relates to a method of production of lignin and hemicellulose from a plant lignocellulosic material comprising the steps of: (a) contacting a plant lignocellulosic material with an extraction solution during more than 2 hours at a temperature between 95° C. to 110° C., thereby obtaining a solid fraction and a liquid fraction, (b) separating the solid fraction and the liquid fraction, (c) concentrating the liquid fraction so as to obtain a concentrated liquid fraction, (d) mixing equal parts by weight of water with the concentrated liquid fraction so as to obtain a suspension comprising solid particles in suspension in a liquid medium, (e) separating the particles and the medium of said suspension, (f) recovering the particles of said suspension thereby obtaining a fraction comprising lignin called lignified fraction, (g) recovering the medium of said suspension thereby obtaining a fraction comprising hemicellulose called hemicellulosic fraction.
    Type: Application
    Filed: February 19, 2019
    Publication date: March 18, 2021
    Inventors: Bouchra BENJELLOUN MLAYAH, Michel DELMAS
  • Publication number: 20210009908
    Abstract: A process for production of lignins and synthetic gas including the steps of extracting lignins and hemicellulose by putting solid Lignocellulosic Raw Material in contact with a mixture of water and formic acid at atmospheric pressure and at a temperature between 80° C. and 110° C.; fractionating, the primary solid fraction and the primary liquid fraction; separating the lignins from the intermediate liquid fraction; and gasifying at least part of said primary solid fraction and/or at least part of said residual liquid fraction for producing synthetic gas.
    Type: Application
    Filed: February 14, 2019
    Publication date: January 14, 2021
    Inventor: Michel DELMAS
  • Publication number: 20210003073
    Abstract: A method and a power plant for on-demand producing electricity from Non-Fossil Power Sources and from a Renewable Lignocellulosic Biomass Feedstock, in a power plant using several electrical production facilities comprising a first facility for producing electricity from a Non-Fossil Power Source chosen from among wind power, hydro power, solar power, geothermal power and/or tidal power; and a second facility using synthetic gas produced during a gasification step of several fractions from renewable lignocellulosic biomass feedstock obtained by the implementation of an organosolv process using a mixture composed of at least water and formic acid.
    Type: Application
    Filed: February 12, 2019
    Publication date: January 7, 2021
    Inventor: Michel DELMAS
  • Publication number: 20210002451
    Abstract: The present invention relates to a method for treating fragments of polyvinyl butyral (PVB) in which glass shards are encrusted in or on the surface of the PVB. The method involves placing PVB fragments in contact with an aqueous solution comprising a cationic surfactant and a weak base, to obtain a mixture. This mixture, subjected to ultrasound within a defined temperature range, leads to separation of the glass shards and the PVB. In particular, the inventors have discovered that the combined, simultaneous, and complementary action of a weak base, a cationic surfactant, and ultrasound, at an appropriate temperature, made it possible to detach and/or unembed the glass shards fixed to the collected PVB without degrading the polymer matrix.
    Type: Application
    Filed: March 1, 2019
    Publication date: January 7, 2021
    Inventors: Ghislain DENIS, Jean-Luc TROMPETTE, Michel DELMAS
  • Publication number: 20210002568
    Abstract: A low energy production method for producing pure and highly concentrated carbon dioxide from a renewable lignocellulosic biomass feedstock comprising the steps of i) extracting lignins and hemicelluloses by putting a solid lignocellulosic raw material in the presence of a mixture of at least water and formic acid, at atmospheric pressure under conditions of temperature between 80° C. and 110° C., ii) fractionating, the primary solid fraction and the primary liquid fraction obtained at the end of the extraction step i), iii) separating the lignins from the intermediate liquid fraction, iv) producing a synthetic gas by feeding a gasification equipment with at least part of said primary solid fraction and/or at least part of said residual liquid fraction, and v) producing carbon dioxide and water by introducing dioxygen, or dioxygen enriched air, or air in said gasification equipment.
    Type: Application
    Filed: February 15, 2019
    Publication date: January 7, 2021
    Inventor: Michel DELMAS
  • Publication number: 20210002824
    Abstract: A low energy production process for producing paper pulp from lignocellulosic biomass, the process comprising the following successive steps: a) extracting lignins and hemicellulose from lignocellulosic biomass by putting at least one solid lignocellulosic raw material in the presence of a mixture, composed only of water and of formic acid, at atmospheric pressure and under controlled conditions of reaction temperature between ambient temperature and the reflux temperature of the mixture at atmospheric pressure, preferably between 80° C. and 100° C., with a weight ratio of the at least one solid lignocellulosic raw material/liquid mixture comprised between 1/1 and 1/15, and for a determined period of time of reaction; and b) separating, at atmospheric pressure and at the reaction temperature, a solid fraction, constituting raw paper pulp, from an organic phase containing in solution at least the starting formic acid and water mixture, solubilized monomeric and polymeric sugars, lignins.
    Type: Application
    Filed: December 13, 2018
    Publication date: January 7, 2021
    Inventor: Michel DELMAS
  • Publication number: 20200157352
    Abstract: The invention relates to a process for the simultaneous extraction of lignin and silica from lignocellulosic plant material, characterized in that it comprises the steps of: a) fractionating the lignocellulosic plant material in the presence of an acid solution, so as to obtain a solid fraction comprising cellulose, residual lignin and silica; b) extracting simultaneously lignin and silica from the solid fraction obtained in step a) with a basic solution, at a pH between 10 and 13 and at a temperature between 70° C. and 90° C., so as to obtain a liquid phase comprising lignin and silica, and a solid phase; c) separating the liquid phase and of the solid phase obtained in step b), d) coprecipitating a mixture of lignin and silica comprised in the liquid phase, at a pH between 5 and 6.
    Type: Application
    Filed: February 16, 2018
    Publication date: May 21, 2020
    Inventors: Bouchra BENJELLOUN MLAYAH, Michel DELMAS
  • Patent number: 10160823
    Abstract: A lignin-phenol-formaldehyde resin, which is obtained by polycondensation of formaldehyde, phenol and lignin in the presence of a basic or acidic catalyst, is characterized in that the lignin is a lignin that is not chemically modified at the available functional groups. This lignin has a low molecular mass and includes available functional groups chosen from the group including aliphatic hydroxyls and phenolic hydroxyls. The degree of substitution by weight of phenol with the lignin is between 50% and 60%. The weight proportion of the lignin and of phenol in the resin is equal to the weight proportion of phenol in a lignin-free phenol-formaldehyde (PF) resin.
    Type: Grant
    Filed: March 26, 2014
    Date of Patent: December 25, 2018
    Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE-CIMV
    Inventors: Michel Delmas, Bouchra Benjelloun Mlayah
  • Publication number: 20180251379
    Abstract: Disclosed is a process for the extraction of silica from lignocellulosic plant matter, including the steps of: a) fractionating the lignocellulosic plant matter in the presence of an acid solution, so as to obtain a solid fraction including cellulose; b) extracting the silica from the solid fraction obtained in step a) with a basic solution, at a pH between 10 and 13 and at a temperature between 70° C. and 90° C., so as to obtain a liquid phase including silica and a solid phase; c) separating the liquid phase and of the solid phase which are obtained in step b); and d) precipitating the silica which is included in the liquid phase, at a pH between 5 and 6.
    Type: Application
    Filed: August 18, 2016
    Publication date: September 6, 2018
    Inventors: Bouchra BENJELLOUN MLAYAH, Michel DELMAS, Laurence LLOVERA, Alvaro TEJADO ETAYO
  • Publication number: 20170137847
    Abstract: A process for producing ethanol includes steps of pre-treatment of the lignocellulosic vegetable raw material, including the steps consisting in destructuring the lignocellulosic vegetable raw material, then in separating, on the one hand, the cellulose (C6) capable of then being hydrolysed (and fermented for the production of ethanol) and, on the other hand, the hemicelluloses capable of then being hydrolysed and the lignins. The hydrolysis of the cellulose and of the hemicelluloses is then carried out in a sequenced manner according to the following steps consisting in: i) beginning the enzymatic hydrolysis of the cellulose by at least one enzyme for a first period with a view to obtaining an intermediate hydrolysate; ii) adding hemicelluloses to the intermediate hydrolysate; iii) continuing the enzymatic hydrolysis of the mixture until a final hydrolysate is obtained at the end of a total period of enzymatic hydrolysis.
    Type: Application
    Filed: June 3, 2015
    Publication date: May 18, 2017
    Inventors: Bouchra BENJELLOUN MLAYAH, Michel DELMAS
  • Patent number: 9580588
    Abstract: A method for the mechanical reinforcement of elastomer polymers, of a chemically unmodified lignin with available functional groups which has a specific surface area of between 0.5 m2/g and 5 m2/g, and preferably between 1 m2/g and 2.5 m2/g. Also an elastomer thus reinforced, in particular without carbon black.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: February 28, 2017
    Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE
    Inventors: Bouchra Benjelloun Mlayah, Michel Delmas
  • Publication number: 20160369033
    Abstract: A lignin-phenol-formaldehyde resin, which is obtained by polycondensation of formaldehyde, phenol and lignin in the presence of a basic or acidic catalyst, is characterized in that the lignin is a lignin that is not chemically modified at the available functional groups. This lignin has a low molecular mass and includes available functional groups chosen from the group including aliphatic hydroxyls and phenolic hydroxyls. The degree of substitution by weight of phenol with the lignin is between 50% and 60%. The weight proportion of the lignin and of phenol in the resin is equal to the weight proportion of phenol in a lignin-free phenol-formaldehyde (PF) resin.
    Type: Application
    Filed: March 26, 2014
    Publication date: December 22, 2016
    Inventors: Michel DELMAS, Bouchra BENJELLOUN MLAYAH
  • Patent number: 9518274
    Abstract: A process for producing bioethanol includes the steps of pretreatment (consisting in destructuring the lignocellulosic vegetable raw material by placing it in the presence of a mixture containing formic acid, acetic acid and water, then in separating cellulose), of enzymatic hydrolysis and of alcoholic fermentation, characterized in that it includes, prior to the enzymatic hydrolysis, a step of partial elimination of the lignins so as to obtain a residual overall level of lignins (T), expressed as percentage by weight, which is non-zero and which is included in a range determined by a lower limit, and an upper limit Bsup, respectively equal to 0.30% and 4%. In order to obtain conditions of acidification before the enzymatic hydrolysis step, the process includes a step for re-acidification of the mixture, which is carried out with an acid, or of a mixture of acids, of determined pKa, and preferably with weak organic.
    Type: Grant
    Filed: October 5, 2011
    Date of Patent: December 13, 2016
    Assignee: COMPAGNIE INDUSTRIELLE DE LA MATIERE VEGETALE—CIMV
    Inventors: Michel Delmas, Bouchra Benjelloun Mlayah