Abstract: A water- and oil-repellent agent including: a modified starch, the modified starch including a hydrophobized modified starch that exhibits a viscosity of 60 cps or less at 50° C. in a 20 mass % aqueous solution, the hydrophobized modified starch accounting for 60% by mass or more of the modified starch contained in the water- and oil-repellent agent, where the amount of the modified starch in the water- and oil-repellent agent is 15% by mass or more.

Abstract: A water- and oil-repellent agent including: a polysaccharide; and a sizing agent, wherein the polysaccharide exhibits a viscosity of 60 cps or less at 50° C. in a 20 mass % aqueous solution.

Abstract: Provided is an aqueous polymer dispersion exhibiting excellent liquid repellency, oil resistance, and low-temperature storage stability, and obtained from a hydrocarbon group-containing polymer composition including (1) a hydrocarbon group-containing polymer having a repeating unit formed from an acrylic monomer having a hydrocarbon group having 7-40 carbon atoms, (2) a diol compound, and (3) an aqueous medium.

Abstract: A paper oil-resistant agent composition containing a hydrocarbon group-containing polymer having a repeating unit formed from a monomer having a hydrocarbon group having 7 to 40 carbon atoms and an NH group-containing group in an amount of 80% by weight or more based on the polymer. Also disclosed is an oil-resistant paper to which the hydrocarbon group-containing polymer in the paper oil-resistant agent composition adheres, a method for producing paper which includes treating paper with the paper oil-resistant composition, and a method for producing molded pulp which includes filling a mold with the paper oil-resistant agent composition and a pulp slurry, and molding the pulp.

Abstract: Provided are a fluorine-free soil resistant agent and a soil resistant treatment method which give excellent water-repellency and excellent antifouling property to a substrate, especially a carpet. The soil resistant agent contains (1) a fluorine-free copolymer having (a) a repeating unit formed from an acrylic monomer having a hydrocarbon group containing 7 to 40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer having a hydrophilic group, and (2) water or a mixture of water and an organic solvent dispersing the fluorine-free copolymer (1). A method of treating the substrate, includes applying the soil resistant agent to the substrate.

Abstract: An oil-resistant agent for paper, which contains a non-fluorine copolymer that has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group with 7-40 carbon atoms and a repeating unit formed from (b) an acrylic monomer having a hydrophilic group. The oil-resistant agent for paper also contains a liquid medium that is composed of water and/or an organic solvent, preferably of water or a mixture (aqueous medium) of water and an organic solvent. The non-fluorine copolymer preferably has a repeating unit formed from (c) a monomer having an ion donor group in addition to the repeating units formed from the monomers (a) and (b). Also disclosed is an oil-resistant paper having an oil-resistant layer including the oil-resistant agent for paper, and starch or modified starch, on a surface of the paper as well as a method of treating paper.

Abstract: An oil-resistant agent and an oil-resistant composition, which are capable of imparting excellent oil-resistance to paper. The oil-resistant composition contains a polysaccharide (1) and an oil-resistant polymer (2). The polysaccharide (1) is preferably starch. The oil-resistant polymer (2) preferably has (a) a repeating unit formed from an acrylic monomer that has a long-chain hydrocarbon group having 7-40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer that has a hydrophilic group. A polyvinyl alcohol or glucose may be present as an additive.

Abstract: A method for producing a paper, which includes applying at least one of ionizing radiation and plasma to at least one of a paper base and a compound (A) selected from: a compound having a carbon-carbon unsaturated bond and containing no fluorine atom in a molecular structure, and a compound containing no fluorine atom in a molecular structure in which radicals are generated by irradiation of an electron beam to the compound, to introduce a layer formed from the compound (A) on a surface of the paper base.

Abstract: A non-fluorinated copolymer composition containing (1) a fluorine-free copolymer and (2) acetylene alcohol. The non-fluorinated copolymer (1) has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group having 7 to 40 carbon atoms; and a repeating unit formed from (c) an acrylic monomer having an olefinic carbon-carbon double bond and an ion donating group. Also disclosed is an oil-resistant agent containing a fluorine-free composition including (1) a fluorine-free copolymer, and (2) an acetylene alcohol, wherein the fluorine-free copolymer (1) has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group having 7 to 40 carbon atoms; an oil-resistant agent kit; a method for producing the fluorine-free copolymer; an oil-resistant paper; and a method for eliminating foam during treatment of paper with the fluorine-free copolymer composition.

Abstract: A molded pulp product including: a pulp, a water- and oil-resistant agent, and a water soluble polymer that does not dissolve in an aqueous medium at 40° C. or lower, wherein a content of the water soluble polymer is 1 to 50% by mass, based on the pulp.

Abstract: A paper oil-resistant agent which is added to the interior of paper and includes (1) a non-fluorine polymer and (2) at least one type of particles selected from inorganic particles or organic particles, the amount of the particles (2) being 1-99.9 wt % of the total weight of the non-fluorine polymer (1) and the particles (2). Also disclosed is an oil-resistant paper including the paper oil-resistant agent and a method for producing the oil-resistant paper.

Abstract: An oil-resistant agent for paper, which contains a non-fluorine copolymer that has a repeating unit formed from (a) an acrylic monomer having a long-chain hydrocarbon group with 7-40 carbon atoms and a repeating unit formed from (b) an acrylic monomer having a hydrophilic group. The oil-resistant agent for paper also contains a liquid medium that is composed of water and/or an organic solvent, preferably of water or a mixture (aqueous medium) of water and an organic solvent. The non-fluorine copolymer preferably has a repeating unit formed from (c) a monomer having an ion donor group in addition to the repeating units formed from the monomers (a) and (b). Also disclosed is an oil-resistant paper having an oil-resistant layer including the oil-resistant agent for paper, and starch or modified starch, on a surface of the paper as well as a method of treating paper.

Abstract: A method for producing a paper, which includes applying at least one of ionizing radiation and plasma to at least one of a paper base and a compound (A) selected from: a compound having a carbon-carbon unsaturated bond and containing no fluorine atom in a molecular structure, and a compound containing no fluorine atom in a molecular structure in which radicals are generated by irradiation of an electron beam to the compound, to introduce a layer formed from the compound (A) on a surface of the paper base.

Abstract: Provided are a fluorine-free soil resistant agent and a soil resistant treatment method which give excellent water-repellency and excellent antifouling property to a substrate, especially a carpet. The soil resistant agent contains (1) a fluorine-free copolymer having (a) a repeating unit formed from an acrylic monomer having a hydrocarbon group containing 7 to 40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer having a hydrophilic group, and (2) water or a mixture of water and an organic solvent dispersing the fluorine-free copolymer (1). A method of treating the substrate, includes applying the soil resistant agent to the substrate.

Abstract: A molded pulp product including: a pulp, a water- and oil-resistant agent, and a water soluble polymer that does not dissolve in an aqueous medium at 40° C. or lower, wherein a content of the water soluble polymer is 1 to 50% by mass, based on the pulp.

Abstract: Disclosed is a treatment agent for paper comprising a fluorine-containing copolymer having a repeat unit (a) derived from a fluorine-containing monomer represented by general formula (I): CH2?C(—X)—C(?O)—Y—[—CH2)m—Z—]p—(CH2)n—Rf; a repeat unit (b) derived from at least one amino monomer represented by general formula (II-1): or a derivative thereof; and a repeat unit (c) derived from a pyrrolidone monomer represented by general formula (III): The treatment agent for paper provides paper having high oil resistance and high water resistance.

Abstract: A water-resistant/oil-resistant agent for paper containing (I) a fluorine-containing copolymer including repeating units derived from: (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1): CH2?C(—X)—C(?O)—Y—Z—Rf (where X is a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or the like; Y is —O— or —NH—; Z is an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-10 carbon atoms, a cycloaliphatic group, or the like; and Rf is a linear or branched fluoroalkyl group having 1-6 carbon atoms), and (b) a (meth)acrylate monomer containing no fluorine atoms; and (II) a polypropylene glycol compound. Also disclosed is a method for treating paper, a treated paper and a composition for treating paper containing the water-resistant/oil resistant agent.

Abstract: Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1-6 carbon atoms, hydrophilic monomer, and monomer having an anion-donating group, which agent affords a superior water and oil resistance to a paper. The invention also discloses a process for treating a paper by the water and oil resistant agent and a treated paper thereby.

Abstract: A water-resistant/oil-resistant agent for paper containing (I) a fluorine-containing copolymer including repeating units derived from: (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1): CH2?C(—X)—C(?O)—Y—Z—Rf (where X is a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or the like; Y is —O— or —NH—; Z is an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-10 carbon atoms, a cycloaliphatic group, or the like; and Rf is a linear or branched fluoroalkyl group having 1-6 carbon atoms), and (b) a (meth)acrylate monomer containing no fluorine atoms; and (II) a polypropylene glycol compound. Also disclosed is a method for treating paper, a treated paper and a composition for treating paper containing the water-resistant/oil resistant agent.

Abstract: Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1 to 6 carbon atoms, the agent being able to afford a superior water and oil resistance to a paper. The invention also discloses a composition comprising the water and oil resistant agent, a process for treating a paper thereby and a treated paper thereby.